Geomorphology of the eastern coast of the Dead Sea, Jordan

This paper aims to investigate the geomorphological characteristics of theeastern coast of the Dead Sea as influenced by structural instability andclimatic changes. Aerial photos and map analyses served to distinguish mainmorphological features and slope classes, whereas geomorphological changesalong the cost, mainly those developed by the declining of the Dead Sealevels were located and examined in the field. The eastern coast of the DeadSea was considered an ultimate outcome of stream work practiced undercontrols of sea-level lowerings. Climatic, hydrological and structuralinstabilities characterizing the study coast put watersheds and wadisdraining into the sea under accelerated erosion that produced huge volumes ofsediments to be deposited in the upper levels of the subsiding former lakesof the Dead Sea. Retrogradation exposed subaqueous deltaic-fluviatileformations, contributing to coastal geomorphological development. Also,present climatic seasonal fluctuations, rejuvenating stream work, continue tosubject past depositional environments to denudation as the stream distanceof transport is increased, and newer subaqueous deltas are being formed.Weathering and mass-wasting processes added to such a development byenhancing the formation of karst, tofoni and pedestal features as well as thehigh erodibility rate of deltaic sediments which endagers constructionalprojects along the study coast.     

Traces of ancient geysers preserved in the travertine of Siwaqa,Jordan: conditions of their formation

A Pleistocene travertine quarrying on a hill in Siwaqa area, central Jordan, excavated solid, well-stratified travertine beds of about 12 m in thickness. The fabric and composition of the travertine indicate original deposition from hot spring water. At present, the area and its surrounding are devoid of any perennial water, except for periodic flood flows that collect at Siwaqa dam 4–5 km to the west of the quarry area, joining the catchment of the River Mujib. The travertine overlies combusted oil shale. The exposed hot spring travertine consists predominantly of well-bedded limestone, interrupted by horizons of chaotic angular debris, indicating ejection from below such as those produced by geysers. The article discusses the origins of the mottled and angular rock fragments, their transportation due to explosive geyser, the conditions and possible causes that produced the pressures leading to steam outbreaks and are responsible for the observed redistribution of travertine layers.     

Structural control of groundwater flow regimes and groundwater chemistry along the lower reaches of the Zerka River,West Jordan,using remote sensing,GIS, and field methods

A hydrogeological study was completed within a sub-catchment of the Zerka River drainage basin, in western Jordan. The system is characterized by anticlinal bending with an axis trending SSW–NNE and plunging a few degrees in the SSW direction. The anticlinal structure diverts groundwater flow towards the SSW while the strike-slipe faults cause the groundwater to diverge where the fault is perpendicular to the groundwater flow lines, and to converge where the fault is parallel to the groundwater flow lines. A direct relationship was found between the location of springs and the type of groundwater flow with regard to the amount of discharge wherein large spring discharges are located in zones of converging groundwater flow lines. In areas where faults are not abundant, the groundwater retention time in the aquifers is long and a zonation of the electrical conductivity was detected due to mineral dissolution. By controlling groundwater flow, the anticlinal setting produces three genetic groups of groundwater flow systems: (1) alkaline–earth alkaline water which is predominately a bicarbonate-type composition, (2) alkaline–earth alkaline water which is predominately bicarbonate–sulfate, and (3) alkaline–earth alkaline water with a high alkaline component.     

The Interface Configuration of the Fresh‐/Dead Sea Water – Theory and Measurements

The high‐density Dead Sea water (1.235 g/cm³) forms a special interface configuration with the fresh groundwater resources of its surrounding aquifers. The fresh groundwater column beneath its surroundings is around one tenth of its length compared to oceanic water. This fact alone indicates the vulnerability of the fresh groundwater resources to the impacts of changes in the Dead Sea level and to saltwater migration. Ghyben‐Herzberg and Glover equations were used to calculate the volumes of water in coastal aquifers which were replaced by freshwater due to the interface seaward migration as a result of the drop in the level of the Dead Sea. For that purpose, the dynamic equation of Glover approach has been integrated to accommodate that type of interface readjustment. The calculated amounts of freshwater which substituted salt Dead Sea water due to the migration of interface are 3.21 · 10¹¹ m³, from a Dead Sea level of –392 m to τ411 m below sea level. The average porosity of coastal aquifers was calculated to range from 2.8 to 2.94%. Geoelectric sounding measurements showed that areas underlying the coastal aquifers formerly occupied by the Dead Sea water are gradually becoming flushed and occupied by freshwater. The latter is becoming salinized due to the residuals of Dead Sea water in the aquifer matrix, the present salinity of which is lower than that of the Dead Sea water. At the same time salt dissolution from the Lisan Marl formation is causing collapses along the shorelines in the form of sinkholes, tens of meters in diameter and depth.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part I: Isotopic (C,O) study of the Khushaym Matruk natural analogue (central Jordan)

The Khushaym Matruk site in central Jordan may represent a natural analogue depicting the interaction of alkaline solutions with a clayey sedimentary formation or with clay-rich confining barriers at the interface with concrete structures in waste disposal sites. In this locality, past spontaneous combustion of organic matter in a clayey biomicritic formation produced a ca. 60 m-thick layer of cement-marble containing some of the high-temperature phases usually found in industrial cements (e.g., spurrite, brucite, and Ca-aluminate). A vertical cross-section of the underlying sediments was used in order to study the interaction between cement-marbles and neighbouring clayey limestones under weathering conditions. A thermodynamic approach of the alteration parageneses (calcite–jennite–afwillite–brucite and CSH phases) in the cement-marbles constrains the interacting solutions to have had pH-values between 10.5 and 12. Over 3 m, the sediments located beneath the metamorphic unit were compacted and underwent carbonation. They display large C and O isotopic variations with respect to “pristine” sediments from the bottom of the section. Low δ¹³C-values down to −31.4‰/PDB show the contribution of CO₂ derived from the oxidization of organic matter and from the atmosphere to the intense carbonation process affecting that particular sedimentary level. The size of the C isotopic anomalies, their geometrical extent and their coincidence with the variations of other markers like the Zn content, the structure of organic matter, the mineralogical composition, all argue that the carbonation process was induced by the percolation of high pH solutions which derived from the alteration of cement-marbles. The temperature of the carbonation process remains conjectural and some post-formation O isotopic reequilibration likely affected the newly-formed carbonate. Carbonation induced a considerable porosity reduction, both in fractures and matrixes. The Khushaym Matruk site may have some bearing to the early life of a repository site, when water saturation of the geological formations hosting the concrete structures is incomplete, enabling simultaneous diffusion of alkaline waters and gaseous CO₂ in the near field.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part II: Organic matter evolution,magnetic susceptibility and metals (Ti,Cr, Fe) at the Khushaym Matruk natural analogue (Central Jordan)

Spontaneous combustion, less than 1 Ma ago, affected a 60-m thick sediment pile of biomicrite at the Khushaym Matruck site (Jordan). The present study shows that three retrograde alteration stages occurred: weathering, thermal stress and oxidative alkaline perturbation. μ-FT-i.r. spectra of isolated kerogens and oxygen index of whole rocks indicate that oxidation of organic matter occurred down to ∼10 m beneath the metamorphosed zone at Khushaym Matruck. The occurrence of the oxidative weathering bacterially mediated, as suggested by the mass chromatograms of saturated hydrocarbons, can explain high Rock-Eval T_max values and low petroliferous potential measured along the sedimentary pile. On the other hand, the thermal extent of combustion events was limited to the first 2 m from the contact. The mean reflectance of 0.20–0.24% and porosity of ca. 50% of the grey clayey biomicrites indicate that organic matter was very immature and sediments were unconsolidated at the time of the combustion event. Using mineralogy, microscopic analyses of vegetable debris and magnetic susceptibility, a suite of characteristic points corresponding to the thermal imprint can be assessed: (i) x = 0m, T ∼ 1000 °C, (ii) x = 1 m, T ∼ 350 °C, (iii) x = 2 m, T ∼ 150 °C and (iv) x > ∼ 8 m, T ∼ 30 °C. Paleocirculation of meteoric groundwater in the ‘cement-marbles’ generated high-pH fluids that have circulated via fractures and through the matrix porosity of the underlying biomicrites but have also induced alkaline hydrolysis and oxidative attack of the organic matter. The polysaccharide/lignin ratio derived from μ-FT-i.r. analyses shows that the delignification of vegetable debris and degradation of polysaccharides progressively decline in the indurated zone, which indicates a decrease in the pH of migrating solutions. The latter also severely oxidized organic matter at 2.10 and 3.05 m as revealed by the oxygen index and induced the generation of bitumen. The spatial correlation between the oxidation levels of organic matter and the metal contents (Fe, Ti and Cr) suggests that redox reactions were responsible for the immobilization of metals in the indurated biomicrites. The intensity of these reactions is attributed to changes in the fluid flow regime within the sedimentary column.     

Sources of groundwater salinity along the flow path,Disi–Dead Sea/Jordan

The groundwater along the eastern escarpment of the Dead Sea shows a variety of chemical compositions with EC values ranging between 500 and a few thousand μS/cm. In this article the different groundwaters were correlated to the aquifers from where they originate and the water–rock interactions were elaborated at. It was found that the start of intercalations of Permo-Triassic and Jurassic rocks in the area and the basaltic dykes and sills are the sources, which cause a drastic increase in the salinity of the water. These rocks contents of residual evaporites, contact metamorphism products, sills, dykes and secondary altered mineral assemblage of plagioclase-, pyroxenes- and Fe-, Mn- minerals cause also drastic changes in ionic ratios, saturation indices and groundwater types. Fresh groundwater flows entering the area become, gradually, after a few kilometres highly salinized and of earthalkali type with prevailing chloride and sulfate instead of being bicarbonate waters.     

AGAGE Observations of Methyl Bromide and Methyl Chloride at Mace Head, Ireland, and Cape Grim, Tasmania, 1998–2001

In situ AGAGE GC-MS measurements of methyl bromide (CH₃Br) and methyl chloride (CH₃Cl) at Mace Head, Ireland and Cape Grim, Tasmania (1998–2001) reveal a complex pattern of sources. At Mace Head both gases have well-defined seasonal cycles with similar average annual decreases of 3.0% yr⁻¹ (CH₃Br) and 2.6% yr⁻¹ (CH₃Cl), and mean northern hemisphere baseline mole fractions of 10.37 ± 0.05 ppt and 535.7 ± 2.2 ppt, respectively. We have used a Lagrangian dispersion model and local meteorological data to segregate the Mace Head observations into different source regions, and interpret the results in terms of the known sources and sinks of these two key halocarbons. At Cape Grim CH₃Br and CH₃Cl also show annual decreases in their baseline mixing ratios of 2.5% yr⁻¹ and 1.5% yr⁻¹, respectively. Mean baseline mole fractions were 7.94 ± 0.03 ppt (CH₃Br) and 541.3 ± 1.1 ppt (CH₃Cl). Although CH₃Cl has astrong seasonal cycle there is no well-defined seasonal cycle in the Cape Grim CH₃Br record. The fact that both gases are steadily decreasing in the atmosphere at both locations implies that a change has occurred which is affecting a common, major source of both gases (possibly biomass burning) and/or their major sink process (destruction by hydroxyl radical).     

Does the Actual Drop in Dead Sea Level Reflect the Development of Water Sources Within its Drainage Basin?

As a part of Jordan’s efforts to quantify the effect of the Dead Sea level decline on the precious groundwater resources of the surrounding aquifers, the authors analyzed the historic or predevelopment inflows and outflows of the Dead Sea basin and the resulting water balance which included precipitation, evaporation, surface‐ and groundwaters. The predevelopment situation was taken as the point of departure for the sake of this study. Furthermore, the present situation was analyzed in an attempt to quantify the groundwater inflows into the Dead Sea as a result of drop in the Dead Sea level. The groundwater component and the corresponding saltwater/freshwater interface were taken as the variables to balance the levels of the sea that would have been reached without the contribution of the uncontrolled groundwater inflows as a result of the salt/freshwater interface seaward migration. The present day water balance that includes all the water diversion projects from all riparians indicates serious declines in the Dead Sea level. The effects of the present day level declines on the fresh groundwater/saltwater interface indicate that considerable amounts of groundwater are driven into the Sea as a result of the seaward migration of the freshwater/saline water interface.