Mercury distribution in seawater in Minamata Bay and the origin of particulate mercury

Horizontal and vertical distributions of mercury were determined in seawater in Minamata Bay and Yatsushiro Sea. The concentrations of total and particulate mercury respectively ranged from 56–285 ng l^–1 and 2.1–506 ng l^–1. They were both highest in the inner most part of Minamata Bay where the sediment was most heavily polluted, and decreased with increasing distance from there. Vertically, an evident increase in concentration was observed near the bottom. A good agreement was found between the mercury content in suspended matter and that in fine sediment particles.These facts show that the particulate mercury is supplied mostly from the bottom sediment, and that it is spreading offshore with dispersing in seawater. This process would eventually result in the pollution of sediment in Yatsushiro Sea.     

Application of the Single-Bubble Airgun Technique for OBS-Data Acquisition Across the Jan Mayen Ridge,North Atlantic

A 140 km long wide-angle seismic profile has been acquired by use of 6 Ocean Bottom Seismographs across the Jan Mayen Ridge, North Atlantic. The profile was acquired twice; once with a traditionally tuned standard source and secondly with a somewhat smaller source tuned on the first bubble pulse. Analysis of the frequency content of the data reveals that the single-bubble source within the 10-15 Hz frequency range generates a signal with a level about 5 db above that of the standard source. These differences can partly be related to differences in airgun depth. The higher output level for these frequencies enables the single-bubble source to resolve intra-crustal structures with a higher degree of certainty, when compared to the data acquired by use of the standard source array. The standard source seems to generate slightly more energy for frequencies around 6 Hz, probably due to the use of a large 1200 in/sup3 gun in this array. These low frequencies a re of importance for mapping of lower crustal and upper mantle structures, and it is recommended that this is taken into account when seismic sources for mapping of deep crustal and upper mantle structures are designed.     

Satellite detection of red tide in Ariake Sound, 1998–2001

High resolution SeaWiFS data was used to detect red tide events that occurred in the Ariake Sound, Japan, a small embayment known as one of the most productive areas in Japan. SeaWiFS chlorophyll data clearly showed that a large red tide event, which damaged seaweed (Nori) cultures, started early in December 2000 in Isahaya Bay, expanded to the whole sound and persisted to the end of February 2001. The monthly average of SeaWiFS data from May 1998 to December 2001 indicated that the chlorophyll peaks appeared twice a year, in early summer and in fall, after the peaks of rain and river discharge. The SeaWiFS data showed that the red tide event during 2000–2001 winter was part of the fall bloom; however, it started later and continued significantly longer than other years. Satellite ocean color data is useful to detect the red tide; however the algorithms require improvement to accurately estimate chlorophyll in highly turbid water and in red tide areas.     

波流共存场中多向随机波浪传播变形数学模型

基于波作用量守恒方程建立了波流共存场中多向随机波浪传播变形数学模型,模型中考虑了波浪绕射的影响和水流引起的波浪弥散多普勒效应,应用包含水流和地形影响的激破波模式计算波浪破碎的能量耗散,采用一阶上迎风有限差分格式离散控制方程。分别计算了有无近岸流情况下单向和多向随机波浪的波高分布,考虑水流影响的数值计算结果与物理模型实验数据吻合良好,比较分析表明,所建立的数学模型能够复演由于离岸流引起的波高增大,可用于波流共存场多向随机波浪传播变形的模拟和预报。     

Application of AVO Analysis to Seismic Data for Detection of Gas below Methane Hydrate Stability Zone in Nankai Trough Area

Abstract. For the purpose of development of methane hydrate, occurring in the deep marine subsurface, as a resource, the most important issue is to understand the methane hydrate system (generation, migration and accumulation) as well as to delineate the methane hydrate reservoir properties. We have applied the Amplitude Versus Offset (AVO) analysis to the seismic data acquired in the Nankai Trough, offshore Japan, in order to confirm the occurrence of gas just below the methane hydrate-bearing zone, assuming that gas will show a so-called Class-3 AVO response. Knowledge of the amount and occurrence of gas in the sediment below methane hydrate-bearing zone is one of the keys to understand the methane hydrate system.
We have utilized the qualitative analysis of AVO methodology to delineate how gas is located below the BSR, which is thought to be the reflection event from the interface between the methane hydrate-bearing zone and the underlying gas-bearing zone. In the region of MITI Nankai Trough Well PSW-3, we observe two BSRs separated by 25 ms. After AVO modeling using well data, we applied AVO attribute analysis and attribute crossplot analysis to the seismic data. Finally we applied an offset-amplitude analysis to CMP gather data at specific locations to confirm the results of AVO attribute analysis. The AVO analysis shows that there is very little gas located in the underlying sediment below methane hydrate-bearing zone. This result supports the fact that we could not obtain any clear evidence of gas occurrence just below the methane hydrate-bearing zone in the Nankai Trough well drilling.     

A numerical study of tropospheric ozone in the springtime in East Asia

The Models-3 Community Multi-scale Air Quality modeling system (CMAQ)coupled with the Regional Atmospheric Modeling System (RAMS)is applied to East Asia to study the transport and photochemical transformation of tropospheric ozone in March 1998．The calculated mixing ratios of ozone and carbon monoxide are compared with ground 1evel observations at three remote sites in Japan and it is found that the model reproduces the observed features very well．Examination of several high episodes of ozone and carbon monoxide indicates that these elevated levels are found in association with continental outflow,demonstrating the critical role of the rapid transport of carbon monoxide and other ozone precursors from the continental boundary layer．In comparison with available ozonesonde data,it is found that the model-calculated ozone concentrations are generally in good agreement with the measurements,and the stratospheric contribution to surface ozone mixing ratios is quite limited．     

Hedonic approaches based on spatial econometrics and spatial statistics: application to evaluation of project benefits

This study discusses the theoretical foundation of the application of spatial hedonic approaches—the hedonic approach employing spatial econometrics or/and spatial statistics—to benefits evaluation. The study highlights the limitations of the spatial econometrics approach since it uses a spatial weight matrix that is not employed by the spatial statistics approach. Further, the study presents empirical analyses by applying the Spatial Autoregressive Error Model (SAEM), which is based on the spatial econometrics approach, and the Spatial Process Model (SPM), which is based on the spatial statistics approach. SPMs are conducted based on both isotropy and anisotropy and applied to different mesh sizes. The empirical analysis reveals that the estimated benefits are quite different, especially between isotropic and anisotropic SPM and between isotropic SPM and SAEM; the estimated benefits are similar for SAEM and anisotropic SPM. The study demonstrates that the mesh size does not affect the estimated amount of benefits. Finally, the study provides a confidence interval for the estimated benefits and raises an issue with regard to benefit evaluation.     

Silver in Tokyo Bay estuarine waters and Japanese rivers

Dissolved and particulate concentrations of silver in Tokyo Bay estuarine waters and Japanese rivers were determined in this study. The dissolved silver concentrations in the surface water of Tokyo Bay range from 5.9 to 15.1 pmol kg⁻¹, which is comparable to those in the surface water of the Japan Sea, but two or three times higher than those in the surface water of the open ocean. However, elevated concentrations of dissolved silver are not found in Tokyo Bay compared with those in other highly urbanized estuaries, such as San Francisco Bay (20∼243 pmol kg⁻¹). In the Tokyo Bay estuary, silver typically exhibits non-conservative mixing behavior, which is a common feature in the other estuaries reported previously. Dissolved silver concentrations decrease with salinity from the rivers to the mouth of Tokyo Bay. Silver is efficiently scavenged by suspended particulates, as evidenced by the high conditional distribution coefficients for silver throughout the estuary (log K_d > 5.0 ± 0.6). The silver fluxes into Tokyo Bay via inflowing rivers and atmospheric deposition were estimated as 83 kg y⁻¹ and 15 kg y⁻¹, respectively. A simple budget calculation shows that the silver supplied from rivers and atmosphere must be rapidly scavenged within the Tokyo Bay estuary.     

Long-term bottom water warming in the north Ross Sea

We measured potential temperature, salinity, and dissolved oxygen profiles from the surface to the bottom at two locations in the north Ross Sea (65.2°S, 174.2°E and 67.2°S, 172.7°W) in December 2004. Comparison of our data with previous results from the same region reveals an increase in potential temperature and decreases in salinity and dissolved oxygen concentration in the bottom layer (deeper than 3000 m) over the past four decades. The changes were significantly different from the analytical precisions. Detailed investigation of the temperature, salinity, dissolved oxygen and σ ₃ value distributions and the bottom water flow in the north Ross Sea suggests a long-term change in water mass mixing balance. That is to say, it is speculated that the influence of cool, saline, high-oxygen bottom water (high-salinity Ross Sea Bottom Water) formed in the southwestern Ross Sea has possibly been decreased, while the influences of relatively warmer and fresher bottom water (low-salinity Ross Sea Bottom Water) and the Adélie Land Bottom Water coming from the Australia-Antarctic Basin have increased. The possible impact of global warming on ocean circulation needs much more investigation.     

Process length variation of the cyst of the dinoflagellate Protoceratium reticulatum in the North Pacific and Baltic‐Skagerrak region: calibration as an annual density proxy and first evidence of pseudo‐cryptic speciation

Process length variation of cysts of the dinoflagellate Protoceratium reticulatum (Claparède et Lachmann) Bütschli in surface sediments from the North Pacific was investigated. The average process length showed a significant inverse relation to annual seawater density: σ_{t annual} = ?0.8674 × average process length + 1029.3 (R² = 0.84), with a standard error of 0.78 kg m^?3. A sediment trap study from Effingham Inlet in British Columbia revealed the same relationship between average process length and local seawater density variations. In the Baltic–Skagerrak region, the average process length variation was related significantly to annual seawater density: σ_{t annual} = 3.5457 × average process length ? 993.28 (R² = 0.86), with a standard error of 3.09 kg m^?3. These calibrations cannot be reconciled, which accentuates the regional character of the calibrations. This can be related to variations in molecular data (small subunit, long subunit and internal transcribed spacer sequences), which show the presence of several genotypes and the occurrence of pseudo‐cryptic speciation within this species. Copyright © 2012 John Wiley & Sons, Ltd.