Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

小波分析理论在GPS技术中的应用

在GPS数据处理中 ,存在着误差影响、影响波的干扰、周跳和数据量大等问题。误差影响和影响波的干扰实质是在接收卫星信号时受到其它因素的影响 ;周跳是由于卫星信号的失锁而造成信号的不连续 ;数据量大是因为GPS观测需要采样间隔小又连续观测所致。由于小波理论具有时频分析、波形分解、特征提取和快速小波变换等特性 ,应用小波变换和波形分解可以解决误差影响和影响波的干扰的问题 ;应用特征提取可以解决周跳检测问题 ;应用快速小波变换可进行数据压缩     

海岩小说的几种叙述模式及弊端

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。     

Tidal effects on temperature front in the Yellow Sea

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).     

西藏结则茶卡湖岸沉积物中铀系年龄及意义

通过对藏北高原西北部结则茶卡湖泊及其沿岸地质地貌调查,发现其为一个富含硼、锂、钾、锶的封闭型盐湖,沿岸海拔4 850 m拔湖325 m有一条明显的高位湖岸线,该湖岸线到湖面之间有六级湖积阶地发育,六级以上阶地保存零星。沿湖岸不同高度上的湖积物U系年龄分别为(14.2±1.2)ka BP(T2)、(38.0±3.5)ka BP(T4)和(41.6±3.2)ka BP(T5)。湖面下降的幅度是藏北高原迄今所知最大。根据湖面平均下降速度推算高位湖岸线和高位湖积层的形成年龄在(120~90)ka BP,与东部的纳木错和西部的甜水海基本一致,说明藏北高原在晚更新世初期有一个明显的泛湖期。大约100 ka BP结则茶卡湖面开始下降,晚更新世以来湖泊演化是在封闭体系干旱环境下进行的,盐湖形成于14 ka BP左右,藏北高原在晚更新世以来气候变化可能为自西向东逐渐变为干寒。     

PALEOSOLS OF SANDY LANDS AND ENVIRONMENTAL CHANGES IN THE WESTERN PART OF NORTHEAST PLAIN OF CHINA WESTERN DURING HOLOCENE

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...     

从ROSAT数据中寻找河内X射线暂现源

从ＲＯＳＡＴ巡天和定点观测结果的对比出发，发现了几个低银纬的巡天源表中的Ｘ射线源在定点观测中没有出现．本文计算了在这些位置的定点观测中出现点源的流强上限，发现比巡天源表中这些源的流强值低很多，这表明它们的流强变化很大，可能是Ｘ射线双星系统中的一类———Ｘ射线暂现源．     

Remarks on dynamical ellipticity at the Earth's

In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series.     

巴颜喀拉山东段及其邻区大地电磁测深成果地质解释

本文主要依据青海省囊歉至大河坝大地电磁测深成果,并结合重力资料对巴颜喀拉及南北两侧地区的壳幔结构进行了地质解释。指出了该区壳幔存在4个明显的低阻层,并简述了它们的形态特征,推断了其地质含意。认为昆中断裂带与昆南断裂带间是一个巨大的构造混杂岩带,影响深度亦很大。推断该区可能存在太古代地层。划出了8条壳幔断裂带,认为昆中断裂应是塔里木—华北板块与华南板块的分界线。     

GPS中BOC调制的FPGA实现

GPS系统中提出了一种新的信号形式,二进制偏移载波(BOC)调制是这种新的信号形式产生的技术关键。首先介绍了BOC调制的定义及其频谱特性,然后阐述了基于FPGA(现场可编程门阵列)硬件平台的BOC调制实现方法,并给出了仿真波形。结果表明,该实现方法是值得提倡的。