SOLID-LIQUID INTERFACE PROCESS OF HEAVY METALS IN THE CHANGJIANG ESTUARYKINETICS OF ADSORPTION OF Pb, Cu AND Cd ON HFO

The adsorption kinetics of Pb, Cu and Cd on hydrous ferrk oxide (HFO) has been approached in tthe simulated environmental conditions of the Changjiang Estuary. The forward adsorption rate constants of different systems under different temperatures have been determined, and the activation energies of the adsorption for Pb and Cu evaluated (Pb=7 kcal/mol, Cu= 11 kcal/mol). The results show that Pb and Cu are strongly adsorbed by HFO; the order of their adsorption rate is found to be Pb≥Cu≥Cd, which follows thte order of their theonody-namic equilibrium constants. It has been demonstrated that the surface exchange-adsorption is the determining step of the solid-liquid interface process. The field investigation results are theoretically explained by the kinetic mechanism.     

虾蟹类亲体生殖营养需求研究的进展

本文综述了虾蟹类生殖营养的最新研究成果,并讨论了各营养素对虾蟹类亲体成熟、生殖和幼体质量的影响．此外,就今后在虾蟹类亲体生殖营养方面开展深入研究提出了一些建议。     

多目标粒子群算法与选址中的形状优化

选址问题是GIS最基本的任务之一.一般性的选址是基于点的位置优化,可利用有关GIS功能完成.实际的选址问题是很复杂的.在给定设施的数量和面积前提下,需要在空间上确定设施的最佳位置,并对形状进行优化,以获取最大的效用.采用一般的方法无法求解这种最优化问题.而且,当选址问题涉及多个目标和不同的约束性条件时,就会变得异常复杂.提出了利用多目标粒子群优化算法和区域形状变异算法相结合来解决复杂的空间选址问题.具有智能的搜索方法,大大提高了空间搜索能力,并保持了搜索区域的连通性,取得了较好的效果.     

基于蚁群智能的遥感影像分类新方法

智能式遥感分类是遥感研究的新热点.提出了一种基于蚁群智能规则挖掘(ant-miner)的遥感影像分类新方法.遥感数据各波段之间存在较强的相关性,这种相关性往往会导致分类产生误差.而ant-miner算法中的信息素是基于规则整体性能的,信息素的动态更新能有效地处理相关性较强的数据,所提供的正反馈信息能纠正启发式函数缺陷所造成的错误.因此,蚁群智能算法应用于遥感分类具有一定的优势.将该方法用于广州市地区的遥感影像,取得了较好的分类结果.并与See5.0决策树方法及最大似然方法(MLH)进行了对比研究,实验结果表明,蚁群智能算法分类精度比后两者的分类精度更高.     

三峡水库区兴山后坝滑坡成因分析

文章通过对三峡水库区兴山后坝滑坡的地质、结构及变形特征研究以及稳定性分析,阐明了该滑坡成因和影响因素。研究发现,滑坡活动主要受地形地貌、地层岩性、人类工程活动以及降雨等因素的影响。运用剩余推力法对比分析天然及暴雨条件下不同层位的滑坡稳定性系数,得出在暴雨作用下滑坡表层滑带稳定性系数最小,不同滑带的稳定性受降雨的影响也各不相同,呈表层〉浅层〉深层的规律;这主要受滑带土的粘土矿物组分的影响。     

山东省日照市蓝色经济区工程建设适宜性评价

本文以山东省日照市蓝色经济区为研究区, 通过野外地质调查和室内综合分析, 选取场地稳定性、工程地质条件、地下水条件, 地形排水条件、地质灾害及其他因素6个一级评价因子, 构造活动、场地土类型、建筑场地类别等13个二级评价因子, 利用专家-层次分析定权法进行区内工程建设适宜性评价, 得到了相应工程建设评价分区图。评价结果表明, 日照市场地工程建设适宜性总体较好, 大部分地区适宜进行高层建筑工程建设, 占84.50%; 地下空间开发利用条件优越, 全区多数地区属于城市地下空间建设适宜区, 适宜性差及不适宜区主要分布在付疃河两岸附近和海岸附近、大型高速公路和铁路沿线一带区域及城区; 轨道交通建设适宜性良好, 小部分不适宜区主要集中在付疃河下游夹仓和小古镇一带及其沿海地区。评价结果可有效地服务于该地区规划布局、建设发展和工程选址, 具有重要的理论和实践指导意义。     

On proton and electron acceleration by shock waves during large solar flares

The data on optical, X-ray and gamma emission from proton flares, as well as direct observations of flare-associated phenomena, show energetic proton acceleration in the corona rather than in the flare region. In the present paper, the acceleration of protons and accompanying relativistic electrons is accounted for by a shock wave arising during the development of a large flare. We deal with a regular acceleration mechanism due to multiple reflection of resonance protons and fast electrons from a collisionless shock wave front which serves as a moving mirror. The height of the most effective acceleration in the solar corona is determined. The accelerated particle energy and density are estimated. It is shown in particular that a transverse collisionless shock wave may produce the required flux of protons with energy of 10 MeV and of relativistic electrons of 1–10 MeV.The proposed scheme may also serve as an injection mechanism when the protons are accelerated up to relativistic energies by other methods.     

Mineralogical and chemical transformation of Oldoinyo Lengai natrocarbonatites, Tanzania

The minerals of Oldoinyo Lengai natrocarbonatite lavas are unstable under atmospheric conditions. Subsolidus mineral assemblages in natrocarbonatites were studied in 105 samples from contemporary eruptions ranging from present day to about 100 years old. The subsolidus minerals in natrocarbonatites were formed (i) along cracks on the lava surface from hot gases escaping during cooling, (ii) as atmospheric alteration by solution of water-soluble minerals, in particular halides and gregoryite, and by hydration of nyerereite under the influence of meteoric water and (iii) by reaction with fumarole gases. After solidification, the lavas were cut by a network of thin cracks, the edges of which are covered by polymineralic encrustations. Samples collected 2–24 h after eruption contain nahcolite, trona, sylvite, and halite with accessory kalicinite and villiaumite. Atmospheric humidity results immediately (≥ 2 h after eruption) in alteration of black lavas that is marked by the appearance of white powdery thermonatrite with nahcolite on the lava surface. Subsequent reaction (weeks, months, years) of natrocarbonatite with meteoric water and the atmosphere results in the formation of pirssonite, gaylussite, shortite, trona, thermonatrite, nahcolite and calcite. Generally, the first important step is the formation of pirssonite and the end-members are calcite carbonate rocks or loose aggregates. Fumarolic activity is common for the active northern crater of the volcano. Reaction of hot (54–141 °C) fumarolic gases with natrocarbonatite leads to the formation of sulphur, gypsum, calcite, anhydrite, monohydrocalcite, barite and celestine. Changes in mineralogy of the natrocarbonatite lead to substantial chemical transformation. The most obvious chemical changes in this process are the loss of Na, K, Cl and S, combined with an increase in H₂O, Ca, Sr, Ba, F and Mn. The oxygen and carbon isotopic composition of altered natrocarbonatites shows a significant shift from the primary “Lengai Box” to high values of δ¹⁸O and δ¹³C. Calcite exhibits δ¹³C values between − 2‰ and − 4‰ PDB and δ¹⁸O values of + 23‰ to + 26‰ SMOW. The observed assemblages of secondary minerals formed by reaction with atmosphere and meteoric water, the changes in chemical composition of the natrocarbonatite and field observations suggest that alteration of natrocarbonatite is an open-system low-temperature process. It takes place at temperatures between 8 and 43 °C with the addition of H₂O to the system and the removal of Na, K, Cl and S from the carbonatites. Low-temperature thermodynamic models developed for alkali carbonate systems can be used for the interpretation of Oldoinyo Lengai subsolidus mineralization.     

紫金牛生长土壤微生物和养分特性

研究了自然坡地坡上、坡中和坡下三种不同部位上紫金牛生长土壤的微生物特性和养分特性。结果表明，紫金牛只生长在坡下，紫金牛生长的坡下土壤中细菌比例最高、真菌比例最低，土壤全氮和有机质含量均高于对照的坡中和坡上。     

小岩头滑坡稳定性分析

小岩头滑坡位于贵州省威宁县二(连浩特)河(口)高速公路K255 010~K255 240里程右侧,属一个大型古滑坡,发育于二叠系上统峨嵋山组玄武岩(P2β)地层中。在高速公路施工中对路堑进行深挖削坡,可能导致古滑坡中部、线路右侧斜坡失稳破坏,发生滑坡。因此,滑坡稳定性评价是重大工程地质问题之一。根据大量勘察试验资料,系统地揭示了滑坡的特征,分析了滑坡形成的控制因素、成因和形成机制,建立了滑坡体稳定性计算模型,利用反演计算法进行稳定性分析与评价,认为两滑体均处于滑动失稳状态。建议对滑坡体进行处理,采用排水、支挡、减压等措施进行整治。