U-Th-Pb geochronology of the Massabesic Gneiss and the granite near Milford,South-Central New Hampshire: New evidence for avalonian basement and taconic and alleghenian disturbances in Eastern New England

U-Th-Pb systematics for zircon and monazite from Massabesic Gneiss (paragneiss and orthogneiss) and the granite near Milford, New Hampshire, were determined. Zircon morphology suggests that the paragneiss may be volcaniclastic (igneous) in origin, and thus the age data probably record the date (minimum of 646 m.y.) at which the rock was extruded. A two-stage lead-loss model is proposed to explain the present array of data points on a concordia diagram. Orthogneiss ages range only narrowly and are clustered around 475 m.y. Data for the granite of Milford, New Hampshire, are scattered, but may be interpreted in terms of inheritance and modern lead loss, yielding a crystallization age of 275 m.y. This is the only known occurrence of Avalonian-type basement in New Hampshire and as such provides evidence for the location of the paleo-Africa-paleo- North America suture. The geochronology also further documents the occurrence of disturbances during the Ordovician and Permian.     

Geomicrobiology of Blood Falls: An Iron-Rich Saline Discharge at the Terminus of the Taylor Glacier, Antarctica

Blood Falls, a saline subglacial discharge from the Taylor Glacier, Antarctica provides an example of the diverse physical and chemical niches available for life in the polar desert of the McMurdo Dry Valleys. Geochemical analysis of Blood Falls outflow resembles concentrated seawater remnant from the Pliocene intrusion of marine waters combined with products of weathering. The result is an iron-rich, salty seep at the terminus of Taylor Glacier, which is subject to episodic releases into permanently ice-covered Lake Bonney. Blood Falls influences thegeochemistry of Lake Bonney, and provides organic carbon and viable microbes to the lakesystem. Here we present the first data on the geobiology of Blood Falls and relate it totheevolutionary history of this unique environment. The novel geological evolution of thissubglacial environment makes Blood Falls an important site for the study of metabolic strategiesin subglacial environments and the impact of subglacial efflux on associated lake ecosystems.     

A Hybrid Multi-Agent/Spatial Interaction Model System for Petrol Price Setting

This paper examines the use of multi‐agent simulations (MAS) to model the petrol market. The development of a purely agent based model for petrol prices is presented. Failings within this model are discussed and an alternative strategy for controlling the price of each petrol station based on population of customers is considered. Individual level modelling of customers is too computationally intensive; therefore a spatial interaction model was used to estimate the sales and linked to the agent system to create a hybrid model. To evaluate how effective this hybrid model was, a comparison was made with an existing data set of real petrol prices collected over a two month period. This was achieved both statistically and visually with the use of a Geographical Information System (GIS). Experimentation revealed that the hybrid model outperformed the agent model. Investigation into the behaviour and sensitivity of the system (for example, how prices diffuse spatially) was undertaken by means of idealised simulations.     

Halogen geochemistry of the McMurdo dry valleys lakes, Antarctica: Clues to the origin of solutes and lake evolution

We have determined the halogen and boron concentrations in the ice-covered lakes of Taylor Valley, Antarctica, to better establish the sources of salts and evolutionary histories of these unusual water bodies. In addition, we report on a series of ¹²⁹I measurements that were compared with previous ³⁶Cl data that also help constrain the source of solutes and histories of the lakes. The new data, when put into context of previous work on these systems over the past forty years, allow us to make the following conclusions. The primary source of solutes to Lake Hoare, the youngest of the lakes, is the dissolution of marine aerosols and aeolian salts and the chemical weathering of dust on the glaciers. The geochemistry of Lake Fryxell, the brackish water lake, is primarily dominated by the diffusion from a halite-saturated brine at the sediment-water interface and the recent infilling of the lake by glacier meltwater. These waters have chemical weathering and marine aerosols components. Lake Bonney has two distinct lobes whose hypersaline hypolimnia have different chemistries. Both of the lobes are remnants of ancient marine waters that have been modified by the input of weathering products. This lake has also been modified by periods of cryogenic concentration when solutes have been lost via mineral precipitation. Thus the geochemistry of Lake Bonney owes its unusual geochemistry, in part, to variations in the climate in the Taylor Valley over at least the past 300kyr. The ¹²⁹I data from the Taylor Valley are similar to those from fracture fluids in crystalline rocks from the Northern Hemisphere.     

Radiometric ages of the Fire Clay tonstein [Pennsylvanian (Upper Carboniferous), Westphalian, Duckmantian]: A comparison of U–Pb zircon single-crystal ages and Ar/Ar sanidine single-crystal plateau ages

The Fire Clay tonstein [Pennsylvanian (Upper Carboniferous), Westphalian Series, Duckmantian Stage]–a kaolinized, volcanic-ash deposit occurring in Kentucky, West Virginia, Tennessee, and Virginia–is the most widespread bed in the Middle Pennsylvanian of the central Appalachian basin, USA. A concordant single-crystal U–Pb zircon datum for this tonstein gives a ²⁰⁶Pb/²³⁸U age of 314.6 ± 0.9 Ma (2σ). This age is in approximate agreement with a mean sanidine plateau age of 311.5 ± 1.3 Ma (1σ, n = 11) for the Fire Clay tonstein. The difference between the two ages may be due to bias between the ⁴⁰K and ²³⁸U decay constants and other factors. The age of the Fire Clay tonstein has important implications for Duckmantian Stage (Westphalian Series) sedimentation rates, correlations with the Westphalian Series of Europe, Middle Pennsylvanian volcanic events, and the late Paleozoic time scale.     

Searching for large-scale structure in deep radio surveys

We calculate the expected amplitude of the dipole and higher spherical harmonics in the angular distribution of radio galaxies. The median redshift of radio sources in existing catalogues is z  ∼ 1, which allows us to study large-scale structure on scales between those accessible to present optical and infrared surveys, and that of the cosmic microwave background (CMB). The dipole is a result of two effects which turn out to be of comparable magnitude: (i) our motion with respect to the CMB, and (ii) large-scale structure, parametrized here by a family of cold dark matter power-spectra. We make specific predictions for the Green Bank 1987 (87GB) and Parkes–MIT–NRAO (PMN) catalogues, which in our combined catalogue include ∼ 40 000 sources brighter than 50 mJy at 4.85 GHz, over about 70 per cent of the sky. For these relatively sparse catalogues both the motion and large-scale structure dipole effects are expected to be smaller than the Poisson shot noise. However, we detect dipole and higher harmonics in the combined 87GB–PMN_raw catalogue which are far larger than expected. We attribute this to a 2 per cent flux mismatch between the two catalogues. Ad hoc corrections made in an effort to match the catalogues may suggest a marginal detection of a dipole. To detect a dipole and higher harmonics unambiguously, a catalogue with full sky coverage and ∼ 10⁶ sources is required. We also investigate the existence and extent of the supergalactic plane in the above catalogues. In a strip of ± 10° of the standard supergalactic equator, we find a 3 σ detection in PMN_raw, but only 1 σ in 87 GB_raw. We briefly discuss the implications of ongoing surveys such as FIRST and NVSS and follow-up redshift surveys.     

Soil moisture prediction over the Australian continent

Summary This paper describes an attempt to model soil moisture over the Australian continent with an integrated system of dynamic models and a Geographic Information System (GIS) data base. A land surface scheme with improved treatment of soil hydrological processes is described. The non-linear relationships between soil hydraulic conductivity, matric potential and soil moisture are derived from the Broadbridge and White soil model. For a single location, the prediction of the scheme is in good agreement with the measurements of the Hydrological and Atmospheric Pilot Experiment (HAPEX). High resolution atmospheric and geographic data are used in soil moisture prediction over the Australian continent. The importance of reliable land surface parameters is emphasized and details are given for deriving the parameters from a GIS. Predicted soil moisture patterns over the Australian continent in summer, with a 50 km spatial resolution, are found to be closely related to the distribution of soil types, apart from isolated areas and times under the influence of precipitation. This is consistent with the notion that the Australian continent in summer is generally under water stress. In contrast, predicted soil temperatures are more closely related to radiation patterns and changes in atmospheric circulation. The simulation can provide details of soil moisture evolution both in space and time, that are very useful for studies of land use sustainability, such as plant growth modelling and soil erosion prediction.With 12 Figures     

Paleolimnology of the McMurdo Dry Valleys,Antarctica

The McMurdo Dry Valleys presently contain more than 20 permanent lakes and ponds, which vary markedly in character. All, with the exception of a hypersaline pond, have a perennial ice-cover. The dry valley lakes, and lakes in other ice-free regions of continental Antarctica, are unique on this planet in that they consistently maintain a thick year-round ice cover (2.8–6.0 m) over liquid water. The persistent ice covers minimize wind-generated currents and reduce light penetration, as well as restricting sediment deposition into a lake and the exchange of atmospheric gases between the water column and the atmosphere. From a paleolimnological perspective, the dry valley lakes offer an important record of catchment and environmental changes. These lakes are also modern-day equivalents of periglacial lakes that were common during glacial periods at temperature latitudes. The present lakes are mostly remnants of larger glacial lakes that occupied the valleys in the past, perhaps up to 4.6 Ma ago. Two of the valleys contain evidence of being filled with large glacial lakes within the last 10000 years. Repeated drying and filling events since then have left a characteristic impression on the salt profiles of some lakes creating a unique paleo-indicator within the water column. These events are also marked in the sediments by the concentration and dilution of certain chemical constituents, particularly salts, and are also corroborated by carbonate speciation and oxygen isotope analysis. Stratigraphic analysis of dry valley lake sediments is made difficult by the occurrence of an old carbon reservoir creating spurious radiocarbon dates, and by the high degree of spatial variability in lake sedimentation. From a biological perspective, the lakes are relatively simple, containing various taxa of planktonic and benthic microorganisms, but no higher forms of life, which is an advantage to paleolimnologists because there is no bioturbation in the sediments. Useful biological paleo-indicators found in the sediments include cyanobacterial filament sheaths, diatom frustules and other eukaryotic algal cells, protozoan cysts, photosynthetic pigments, and minerals (e.g. carbonates) associated with microbial activity. Future work will benefit from fully characterizing the connection between the ice covers, environmental conditions, and paleo-indicators, thereby allowing refinement of inferences made concerning the paleoenvironment. New dating techniques need to be tested in this environment to overcome the problems associated with radiocarbon dating. The establishment of a detailed and focused paleolimnological campaign is proposed.     

Strontium Isotopic Signatures of the Streams and Lakes of Taylor Valley, Southern Victoria Land, Antarctica: Chemical Weathering in a Polar Climate

We have collected and analyzed a series of water samples from three closed-basin lakes (Lakes Bonney, Fryxell, and Hoare) in Taylor Valley, Antarctica, and the streams that flow into them. In all three lakes, the hypolimnetic waters have different ⁸⁷Sr/⁸⁶Sr ratios than the surface waters, with the deep water of Lakes Fryxell and Hoare being less radiogenic than the surface waters. The opposite occurs in Lake Bonney. The Lake Fryxell isotopic ratios are lower than modern-day ocean water and most of the whole-rock ratios of the surrounding geologic materials. A conceivable source of Sr to the system could be either the Cenozoic volcanic rocks that make up a small portion of the till deposited in the valley during the Last Glacial Maximum or from marble derived from the local basement rocks. The more radiogenic ratios from Lake Bonney originate from ancient salt deposits that flow into the lake from Taylor Glacier and the weathering of minerals with more radiogenic Sr isotopic ratios within the tills. The Sr isotopic data from the streams and lakes of Taylor Valley strongly support the notion documented by previous investigators that chemical weathering has been, and is currently, a major process in determining the overall aquatic chemistry of these lakes in this polar desert environment.