Trace element and major ion concentrations and dynamics in glacier snow and melt: Eliot Glacier,Oregon Cascades

We present concentrations of environmentally available (unfiltered acidified 2% v/v HNO₃) As, Cu, Cd, Pb, V, Sr, and major ions including Ca²⁺, Cl^?, and SO₄^2? in a July 2005 and a March 2006 shallow snow profile from the lower Eliot Glacier, Mount Hood, Oregon, and its proglacial stream, Eliot Creek. Low enrichment factors (EF) with respect to crustal averages suggests that in fresh March 2006 snow environmentally available elements are derived primarily from lithogenic sources. Soluble salts occurred in lower and less variable concentrations in July 2005 snow than March 2006. Conversely, environmentally available trace elements occurred in greater and more variable concentrations in July 2005 than March 2006 snow. Unlike major solutes, particulate‐associated trace elements are not readily eluted during the melt season. Additionally, elevated surface concentrations suggest that they are likely added throughout the year via dry deposition. In a 1‐h stream sampling, ratios of dissolved (<0·45 µm) V:Cl^?, Sr:Cl^?, and Cu:Cl^? are enriched in the Eliot Stream with respect to their environmentally available trace element to Cl^? ratios in Eliot Glacier snow, suggesting chemical weathering additions in the stream waters. Dissolved Pb:Cl^? is depleted in the Eliot Stream with respect to the ratio of environmentally available Pb to Cl^? in snow, corresponding to greater adsorption onto particles at greater pH values. Copyright © 2009 John Wiley & Sons, Ltd.     

Seawater rare-earth element patterns preserved in apatite of Pennsylvanian conodonts?

Past workers have used rare-earth element patterns recorded in biogenic apatite as proxies for original seawater chemistry. To explore the potency of this approach, we analyzed Pennsylvanian conodonts from limestones, gray shales, and black shales of the Fort Scott and Pawnee formations (Desmoinesian) and Swope and Dennis formations (Missourian) in Kansas, Missouri, and Iowa, U.S.A. Analysis of individual platform conodonts from seven taxa using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) revealed a consistent enrichment in the middle rare-earth elements (MREE). Analogous MREE enrichment has been observed in authigenic apatite and bulk samples of phosphate-rich black shales from the same formations. Importantly, however, phosphate-depleted shales intimately associated with the P-rich intervals are relatively depleted in MREE. These antithetic patterns argue convincingly for secondary migration from the bulk sediment into the phosphate, and the extent of MREE enrichment in the conodonts is correlated positively with the total REE content. MREE enrichment in conodonts does not vary systematically as a function of lithology, stratigraphic level, conodont genus, geographic location, or with independent estimates of paleoredox conditions in the bottom waters. Collectively, these results argue for postmortem (diagenetic) REE uptake resulting in a pronounced (and progressive) MREE enrichment. Any cerium anomalies, if initially present, were masked by diagenetic uptake of REE. Paleoenvironmental interpretations of conodont REE, particularly for samples exhibiting MREE enrichment, should therefore be viewed with caution.     

Accurate estimators of power spectra in N-body simulations

A method to rapidly estimate the Fourier power spectrum of a point distribution is presented. This method relies on a Taylor expansion of the trigonometric functions. It yields the Fourier modes from a number of fast Fourier transforms (FFTs), which is controlled by the order N of the expansion and by the dimension D of the system. In three dimensions, for the practical value   N = 3  , the number of FFTs required is 20.
We apply the method to the measurement of the power spectrum of a periodic point distribution that is a local Poisson realization of an underlying stationary field. We derive an explicit analytic expression for the spectrum, which allows us to quantify – and correct for – the biases induced by discreteness and by the truncation of the Taylor expansion, and to bound the unknown effects of aliasing of the power spectrum. We show that these aliasing effects decrease rapidly with the order N . For   N = 3  , they are expected to be, respectively, smaller than  ∼10⁻⁴  and 0.02 at half the Nyquist frequency and at the Nyquist frequency of the grid used to perform the FFTs. The only remaining significant source of errors is reduced to the unavoidable cosmic/sample variance due to the finite size of the sample.
The analytical calculations are successfully checked against a cosmological N -body experiment. We also consider the initial conditions of this simulation, which correspond to a perturbed grid. This allows us to test a case where the local Poisson assumption is incorrect. Even in that extreme situation, the third-order Fourier–Taylor estimator behaves well, with aliasing effects restrained to at most the per cent level at half the Nyquist frequency.
We also show how to reach arbitrarily large dynamic range in Fourier space (i.e. high wavenumber), while keeping statistical errors in control, by appropriately 'folding' the particle distribution.     

Further evidences of deep convective vertical transport of water vapor through the tropopause

A few years ago, we identified a deep convective transport mechanism, of water vapor through the tropopause, namely, storm top gravity wave breaking, such that tropospheric water substance can be injected into the lower stratosphere via this pathway. The main evidence presented previously was taken from the lower resolution AVHRR images of the storm anvil top cirrus plumes obtained by polar orbiting satellites. Recent observations have provided further supporting evidence for this important cross-tropopause transport mechanism. There are now many higher resolution satellite images, mainly from MODIS instrument, that show more definitely the existence of these plumes, many of which would probably be unseen by lower resolution images.Furthermore, a thunderstorm movie taken in Denver (USA) area during STEPS2000 field campaign and another thunderstorm movie taken by a building top webcam in Zurich also demonstrate that the jumping cirrus phenomenon, first identified by T. Fujita in 1980s, may be quite common in active thunderstorm cells, quite contrary to previous belief that it is rare. We have used a cloud model to demonstrate that the jumping cirrus is exactly the gravity wave breaking phenomenon that transports water vapor through the tropopause.These additional evidences provide increasing support that deep convection contributes substantially to the troposphere-to-stratosphere transport of water substance. This corroborates well with recent studies of the stratospheric HDO/H₂O ratio which is much highly than it would be if the transport is via slow ascent. The only explanation that can be used to interpret this observation at present is that water substance is transported through the tropopause via rapid vertical motion, i.e., deep convection.     

Granta MIST

The magnetosphere, ionosphere and solar–terrestrial physics community gathered at Selwyn College, University of Cambridge, for three days between Tuesday 5 April and Thursday 7 April 2005. Neil Arnold and Andrew Lyons report.     

Seasonal metal remobilization in the sediments of Great Bay,New Hampshire

Concentrations of dissolved iron, manganese, molybdenum, copper, and organic carbon (DOC) were measured in the pore waters from surficial sediments of a temperate estuary to delineate seasonal metal remobilization from 1978 through 1980. Iron and DOC data were collected for 31 months and covaried inversely and exponentially. Iron dissolution occurred during the spring and during periods of active bioturbation with concentrations as high as 18 mg 1^?1. Iron values were low during winter due to oxidation to ferric oxides. The lack of active bioturbation during the summer of 1978 allowed for the nearly complete removal of iron as a monosulfide precipitate. However, bioturbation resumed during the summer of 1979 and 1980 and dissolved iron concentrations as high as 10 mg 1^?1 were observed at those times. The iron and DOC data were a qualitative measure of bioturbation activity. Dissolved manganese, molybdenum, and copper data were collected for 18 months during 1978 and 1979. All three metals displayed spring maxima covariate with iron, suggesting that they behaved chemically like iron and/or were associated with iron- or manganese-rich phases during this time of the year. In general, manganese and molybdenum varied temporally with iron while copper concentrations mimicked iron variations only during the spring.     

Infrared constraints on the dark mass concentration observed in the cluster Abell 1942

We present a deep H -band image of the region in the vicinity of the cluster Abell 1942 containing the puzzling dark matter concentration detected in an optical weak lensing study by Erben et al. We demonstrate that our limiting magnitude, H =22 , would be sufficient to detect clusters of appropriate mass out to redshifts comparable with the mean redshift of the background sources. Despite this, our infrared image reveals no obvious overdensity of sources at the location of the lensing mass peak, nor an excess of sources in the I − H versus H colour–magnitude diagram. We use this to constrain further the luminosity and mass-to-light ratio of the putative dark clump as a function of its redshift. We find that for spatially flat cosmologies, background lensing clusters with reasonable mass-to-light ratios lying in the redshift range 0< z <1 are strongly excluded, leaving open the possibility that the mass concentration is a new type of truly dark object.     

Surface influences on the Australian West Coast Trough

Summary  Three dimensional numerical simulations of the Australian West Coast Trough were conducted using a mesoscale model. These simulations represent the process of formation, development and disappearance of the trough and highlight the role of surface features in trough behaviour. Strong land surface heating strengthens the trough whereas topography and sea surface temperatures are of marginal importance. Diurnal variations in surface heating between the land and ocean lead to the trough line oscillating around the coast whereas its more general eastward movement is synoptically controlled. The sea breeze circulation influences local trough orientation through maritime cooling. Received December 23, 1999 Revised November 7, 2000