Mediterranean outflow through the Strait of Gibraltar since 18,000 Years B.P.: Mineralogical and geochemical arguments

Data obtained from mineralogical and geochemical analyses of piston and gravity cores, recovered from an area off Lisbon (Portugal) to the Alboran Sea (Mediterranean), serve as a basis for better understanding the past 18,000 years of hydrological exchanges at Gibraltar. Tracers used in this study are smectite, kaolinite, Ta, Th, La. One of the primary sources of particles both into and out of the Mediterranean is the Guadalquivir River. These particles are transported back into the Atlantic in the Mediterranean outflow water, and deposited along the Iberian slope. No evidence for reversal of this outflow current was found in those cores, since 18,000 years B.P.     

Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.     

P‐wave stacking‐velocity tomography for VTI media

A major complication caused by anisotropy in velocity analysis and imaging is the uncertainty in estimating the vertical velocity and depth scale of the model from surface data. For laterally homogeneous VTI (transversely isotropic with a vertical symmetry axis) media above the target reflector, P‐wave moveout has to be combined with other information (e.g. borehole data or converted waves) to build velocity models for depth imaging. The presence of lateral heterogeneity in the overburden creates the dependence of P‐wave reflection data on all three relevant parameters (the vertical velocity V_P0 and the Thomsen coefficients ε and δ) and, therefore, may help to determine the depth scale of the velocity field. Here, we propose a tomographic algorithm designed to invert NMO ellipses (obtained from azimuthally varying stacking velocities) and zero‐offset traveltimes of P‐waves for the parameters of homogeneous VTI layers separated by either plane dipping or curved interfaces. For plane non‐intersecting layer boundaries, the interval parameters cannot be recovered from P‐wave moveout in a unique way. Nonetheless, if the reflectors have sufficiently different azimuths, a priori knowledge of any single interval parameter makes it possible to reconstruct the whole model in depth. For example, the parameter estimation becomes unique if the subsurface layer is known to be isotropic. In the case of 2D inversion on the dip line of co‐orientated reflectors, it is necessary to specify one parameter (e.g. the vertical velocity) per layer. Despite the higher complexity of models with curved interfaces, the increased angle coverage of reflected rays helps to resolve the trade‐offs between the medium parameters. Singular value decomposition (SVD) shows that in the presence of sufficient interface curvature all parameters needed for anisotropic depth processing can be obtained solely from conventional‐spread P‐wave moveout. By performing tests on noise‐contaminated data we demonstrate that the tomographic inversion procedure reconstructs both the interfaces and the VTI parameters with high accuracy. Both SVD analysis and moveout inversion are implemented using an efficient modelling technique based on the theory of NMO‐velocity surfaces generalized for wave propagation through curved interfaces.     

Sliding fragility of block‐type non‐structural components. Part 1: Unrestrained components

Motivated by the development of performance‐based design guidelines with emphasis on both structural and non‐structural systems, this paper focuses on seismic vulnerability assessment of block‐type unrestrained non‐structural components under sliding response on the basis of seismic inputs specified by current seismic codes. Two sliding‐related failure modes are considered: excessive relative displacement and excessive absolute acceleration. It is shown that an upper bound for the absolute acceleration response can be assessed deterministically, for which a simple yet completely general equation is proposed. In contrast, fragility curves are proposed as an appropriate tool to evaluate the excessive relative displacement failure mode. Sample fragility curves developed through Monte‐Carlo simulations show that fragility estimates obtained without taking into account vertical base accelerations can be significantly unconservative, especially for relatively large values of the coefficient of friction. It is also found that reasonable estimates of relative displacement response at stories other than the ground in multistorey buildings cannot in general be obtained by simply scaling the ground acceleration to the peak acceleration at the corresponding storey. Failure modes considered in this study are found to be essentially independent of each other, a property that greatly simplifies assessment of conditional limit states. Copyright © 2002 John Wiley & Sons, Ltd.     

Effet du vieillissement des céramiques poreuses sur leur capacité à évaluer la concentration de pesticide en solution

The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).     

北喀斯喀特边缘IODP 311航次断面的地震结构、天然气水合物含量和滑塌构造

北喀斯喀特活动边缘的增生楔沉积物中含有分布广泛的天然气水合物一直延伸到海底下几百米的深度。为了评估天然气水合物的长期能源潜力和它在全球气候变化及边坡稳定性中的作用,2005年9月IODP311航次建立了一个详细的地质模型来解释水合物的形成与分解以及它与穿过大陆边缘流体流的伴生关系。在考察前,先在大陆坡上进行地震试验以提供支持钻井的地球物理信息。     

Why chromatic imaging matters

During the last two decades, the first generation of beam combiners at the Very Large Telescope Interferometer has proved the importance of optical interferometry for high-angular resolution astrophysical studies in the near- and mid-infrared. With the advent of 4-beam combiners at the VLTI, the u ? v coverage per pointing increases significantly, providing an opportunity to use reconstructed images as powerful scientific tools. Therefore, interferometric imaging is already a key feature of the new generation of VLTI instruments, as well as for other interferometric facilities like CHARA and JWST. It is thus imperative to account for the current image reconstruction capabilities and their expected evolutions in the coming years. Here, we present a general overview of the current situation of optical interferometric image reconstruction with a focus on new wavelength-dependent information, highlighting its main advantages and limitations. As an Appendix we include several cookbooks describing the usage and installation of several state-of-the art image reconstruction packages. To illustrate the current capabilities of the software available to the community, we recovered chromatic images, from simulated MATISSE data, using the MCMC software SQUEEZE. With these images, we aim at showing the importance of selecting good regularization functions and their impact on the reconstruction.     

Preliminary assessment of the ATHENA/WFI non-X-ray background

We present a preliminary assessment of the non-X-ray background for the WFI on board ATHENA conducted at IAAT in the context of the collaborative background and radiation damage working group activities. Our main result is that in the baseline configuration originally assumed for the camera the requirement on the level of non-X-ray background could not be met. In light of the results of Geant4 simulations we propose and discuss a possible optimization of the camera design and pinpoint some open issues to be addressed in the next phase of investigation. One of these concerns the possible contribution to the non-X-ray background from soft protons and ions funneled to the focal plane through the optics. This is not quantified at this stage, here we just briefly report on our ongoing activities aimed at validating the mechanisms of proton scattering at grazing incidence.     

Distribution and spatial variation of hydrothermal faunal assemblages at Lucky Strike (Mid-Atlantic Ridge) revealed by high-resolution video image analysis

Whilst the fauna inhabiting hydrothermal vent structures in the Atlantic Ocean is reasonably well known, less is understood about the spatial distributions of the fauna in relation to abiotic and biotic factors. In this study, a major active hydrothermal edifice (Eiffel Tower, at 1690 m depth) on the Lucky Strike vent field (Mid-Atlantic Ridge (MAR)) was investigated. Video transects were carried out by ROV Victor 6000 and complete image coverage was acquired. Four distinct assemblages, ranging from dense larger-sized Bathymodiolus mussel beds to smaller-sized mussel clumps and alvinocaridid shrimps, and two types of substrata were defined based on high definition photographs and video imagery. To evaluate spatial variation, faunal distribution was mapped in three dimensions. A high degree of patchiness characterizes this 11 m high sulfide structure. The differences observed in assemblage and substratum distribution were related to habitat characteristics (fluid exits, depth and structure orientation). Gradients in community structure were observed, which coincided with an increasing distance from the fluid exits. A biological zonation model for the Eiffel Tower edifice was created in which faunal composition and distribution can be visually explained by the presence/absence of fluid exits.     

Absorption and desorption of dichloromethane vapor by water drops in air. An experimental test of scavenging theory

An experimental study of the scavenging of dichloromethane vapor by water drops falling at terminal velocity, has been carried out in the UCLA precipitation shaft, in order to test the predictions of theoretical washout models. Whereas good agreement between theory and experiment was found for drops of radius 0.332 mm, computed gas uptake rates for 1.253 and 2.21 mm radius drops were much slower than those measured, just as reported previously for the washout of both sulfur dioxide and acetaldehyde. An analysis shows that theory can be reconciled with all of the experimental data by replacing the compound specific aqueous phase Fickian molecular diffusion coefficient used in the theory, by an effective diffusivity, having a constant value, (3×10^-4 cm² s^-1), independent of the physical and chemical nature of the absorbed species, for all drops of equivalent radii greater than 0.9 mm.