Multicomponent reactive transport modeling of uranium bioremediation field experiments

A reaction network integrating abiotic and microbially mediated reactions has been developed to simulate biostimulation field experiments at a former Uranium Mill Tailings Remedial Action (UMTRA) site in Rifle, Colorado. The reaction network was calibrated using data from the 2002 field experiment, after which it was applied without additional calibration to field experiments performed in 2003 and 2007. The robustness of the model specification is significant in that (1) the 2003 biostimulation field experiment was performed with 3 times higher acetate concentrations than the previous biostimulation in the same field plot (i.e., the 2002 experiment), and (2) the 2007 field experiment was performed in a new unperturbed plot on the same site. The biogeochemical reactive transport simulations accounted for four terminal electron-accepting processes (TEAPs), two distinct functional microbial populations, two pools of bioavailable Fe(III) minerals (iron oxides and phyllosilicate iron), uranium aqueous and surface complexation, mineral precipitation and dissolution. The conceptual model for bioavailable iron reflects recent laboratory studies with sediments from the UMTRA site that demonstrated that the bulk (∼90%) of initial Fe(III) bioreduction is associated with phyllosilicate rather than oxide forms of iron. The uranium reaction network includes a U(VI) surface complexation model based on laboratory studies with Rifle site sediments and aqueous complexation reactions that include ternary complexes (e.g., calcium-uranyl-carbonate). The bioreduced U(IV), Fe(II), and sulfide components produced during the experiments are strongly associated with the solid phases and may play an important role in long-term uranium immobilization.     

On the interpretation of the “inverse phase effect” for CO2 equivalent widths on Venus

Computations of the equivalent widths of absorption lines as a function of planetary phase angle are made for a homogeneous cloud with particles having the properties (shape, refractive index, and size distribution) deduced from polarimetry of Venus. The computed equivalent widths show an “inverse phase effect” comparable to that which is observed for CO₂ lines on Venus. This result verifies a recent suggestion of Regas et al. that the existence of an inverse phase effect does not by itself imply the presence of multiple layers of scattering particles in the atmosphere of Venus.     

Vitrification darkening of rock powders: implications for optical properties of the lunar surface

Laboratory experiments show that albedoes as low as those on the Moon can be produced by vacuum vitrification and associated chemical fractionation of ordinary terrestrial basaltic material. Vitrification is established as an unequivocal process that can account for the low albedo and apparent local darkening with age of the lunar surface. The spectral reflectance curves of glass powders are significantly different than those of the parent rock mineralogy; thus, the presence of ubiquitous glass in lunar surface material complicates compositional determinations by interpretation of spectral reflectance curves. Vitrification of rocks on the Moon may highly modify the chemical composition of the resulting glass; thus, glass fragments found in lunar fines cannot be assumed to represent bulk parent rock material. Progressive impact vitrification of lunar surface material throughout the Moon's history may have led to a fine-grain, opaque, refractory-rich material we call ultimate glass. This unidentified and, at this point, hypothetical component may exist in dark regolith material; if found, it may be a useful indicator of regolith maturity.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

Lunar structure and dynamics - results from the apollo passive seismic experiment

Analysis of seismic signals from man-made impacts, moonquakes, and meteoroid impacts has established the presence of a lunar crust, approximately 60 km thick in the region of the Apollo seismic network; an underlying zone of nearly constant seismic velocity extending to a depth of about 1000 km, referred to as the mantle; and a lunar core, beginning at a depth of about 1000 km, in which shear waves are highly attenuated suggesting the presence of appreciable melting. Seismic velocitites in the crust reach 7 km s^–1 beneath the lower-velocity surface zone. This velocity corresponds to that expected for the gabbroic anorthosites found to predominate in the highlands, suggesting that rock of this composition is the major constituent of the lunar crust. The upper mantle velocity of about 8 km s^–1 for compressional waves corresponds to those of terrestrial olivines, pyroxenites and peridotites. The deep zone of melting may simply represent the depth at which solidus temperatures are exceeded in the lower mantle. If a silicate interior is assumed, as seems most plausible, minimum temperatures of between 1450°C and 1600°C at a depth of 1000 km are implied. The generation of deep moonquakes, which appear to be concentrated in a zone between 600 km and 1000 km deep, may now be explained as a consequence of the presence of fluids which facilitate dislocation. The preliminary estimate of meteoroid flux, based upon the statistics of seismic signals recorded from lunar impacts, is between one and three orders of magnitude lower than previous estimates from Earth-based measurements.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.     

Flow patterns of lobate debris aprons and lineated valley fill north of Ismeniae Fossae, Mars: Evidence for extensive mid-latitude glaciation in the Late Amazonian

A variety of Late Amazonian landforms on Mars have been attributed to the dynamics of ice-related processes. Evidence for large-scale, mid-latitude glacial episodes existing within the last 100 million to 1 billion years on Mars has been presented from analyses of lobate debris aprons (LDA) and lineated valley fill (LVF) in the northern and southern mid-latitudes. We test the glacial hypothesis for LDA and LVF along the dichotomy boundary in the northern mid-latitudes by examining the morphological characteristics of LDA and LVF surrounding two large plateaus, proximal massifs, and the dichotomy boundary escarpment north of Ismeniae Fossae (centered at 45.3°N and 39.2°E). Lineations and flow directions within LDA and LVF were mapped using images from the Context (CTX) camera, the Thermal Emission Imaging Spectrometer (THEMIS), and the High Resolution Stereo Camera (HRSC). Flow directions were then compared to topographic contours derived from the Mars Orbiter Laser Altimeter (MOLA) to determine the down-gradient components of LDA and LVF flow. Observations indicate that flow patterns emerge from numerous alcoves within the plateau walls, are integrated over distances of up to tens of kilometers, and have down-gradient flow directions. Smaller lobes confined within alcoves and superposed on the main LDA and LVF represent a later, less extensive glacial phase. Crater size-frequency distributions of LDA and LVF suggest a minimum (youngest) age of 100 Ma. The presence of ring-mold crater morphologies is suggestive that LDA and LVF are formed of near-surface ice-rich bodies. From these observations, we interpret LDA and LVF within our study region to result from formerly active debris-covered glacial flow, consistent with similar observations in the northern mid-latitudes of Mars. Glacial flow was likely initiated from the accumulation and compaction of snow and ice on plateaus and in alcoves within the plateau walls as volatiles were mobilized to the mid-latitudes during higher obliquity excursions. Together with similar analyses elsewhere along the dichotomy boundary, these observations suggest that multiple glacial episodes occurred in the Late Amazonian and that LDA and LVF represent significant reservoirs of non-polar ice sequestered below a surface lag for hundreds of millions of years.     

Formation of an eroded lava channel within an Elysium Planitia impact crater: Distinguishing between a mechanical and thermal origin

A lava channel identified on the wall of an Elysium Planitia impact crater is investigated to identify the dominant erosion mechanism, mechanical vs. thermal, acting during channel formation. Observations of channel morphology are used to supplement analytical models of lava channel formation in order to calculate the duration of channel formation, the velocity of the lava flowing through the channel, and the erosion rate in each erosion regime considered. Results demonstrate that the channel observed in the Elysium Planitia impact crater formed primarily due to mechanical erosion. In a more general sense, results of this study suggest that lava channels can form primarily due to thermal erosion in the presence of more gradual slopes and more consolidated substrates whereas lava channels can form primarily due to mechanical erosion in the presence of more energetic flows on steeper slopes and more poorly consolidated substrates. Therefore, both erosion regimes must be considered when analyzing origins of eroded lava channels that cut through strata of different strengths.     

Kinematics from spectroscopy with a wide slit: detecting black holes in galaxy centres

We consider long-slit emission-line spectra of galactic nuclei when the slit is wider than the instrumental point spread function, and the target has large velocity gradients. The finite width of the slit generates complex distributions of brightness at a given spatial point in the measured spectrum, which can be misinterpreted as coming from additional physically distinct nuclear components. We illustrate this phenomenon for the case of a thin disc in circular motion around a nuclear black hole (BH). We develop a new method for estimating the mass of the BH that exploits a feature in the spectrum at the outer edge of the BH's sphere of influence, and therefore gives higher sensitivity to BH detection than traditional methods. Moreover, with this method we can determine the BH mass and the inclination of the surrounding disc separately, whereas the traditional approach to BH estimation requires two long-slit spectra to be taken. We show that, with a given spectrograph, the detectability of a BH depends on the sense of rotation of the nuclear disc. We apply our method to estimate the BH mass in M84 from a publicly available spectrum, and recover a value four times lower than that published previously from the same data.     

Orientale multi-ringed basin interior and implications for the petrogenesis of lunar highland samples

The lunar Orientale basin and its associated facies formed as a result of impact into lunar highland crustal rocks. The crater rim is shown to be closely represented by the position of the outer Rook Mountain ring, approximately 620 km in diam. The inner Rook Mountains form a central peak ring within the crater. The 900 km diam Cordillera ring is a fault scarp which formed in the terminal stages of the cratering event as a large portion of the crust collapsed inward toward the recently excavated crater, forming a mega-terrace. This collapse pushed the wall of the Orientale crater inward, distorting it and slightly decreasing its radius.A domical facies is almost exclusively developed between the Cordillera and outer Rook rings. The domical facies is interpreted to be radially textured ejecta which was disrupted and modified to a jumbled domical texture by seismic shaking associated with the formation of the mega-terrace. The plains and corrugated facies pre-date the mare fill and lie within the Orientale crater. These facies are interpreted to have been deposited contemporaneously with the cratering event as partial and total impact melts which collected on the floor of the crater during the terminal stages of the event. The plains facies, with an estimated thickness of 1 km and a volume of 75000 km³, represent the most thoroughly impact melted materials which collected and ponded in the central portion of the crater floor. The corrugated facies, with an estimated thickness of 1 km and a volume of 180000 km³, represent impact partial melts mixed with debris. A relatively small volume of mare material was subsequently deposited in the basin (probably less than 25000 km³ in Mare Orientale).There is little evidence that the basin has undergone major structural modifications subsequent to the terminal stages of the cratering event. The striking implication for the Orientale gravity anomaly is that mascon formation may be primarily related to crustal excavation and upwarping of a moho plug, rather than attributable to post-impact mare filling.The plains units on the floor of Orientale are similar to Cayley-like plains in other multi-ringed basins and on smaller crater floors. Impact melt deposits may therefore be a significant source of Cayley-like plains units.The volumes of impact melt associated with the Orientale basin and their mode of deposition have important implications for petrogenetic models. Multi-ringed basin formation provides a mechanism for instantaneously melting large volumes of shallow to intermediate depth lunar crustal material which is emplaced such that the differentiation and crystallization of a variety of igneous rock types and textures may occur.     

A Mariner 9 atlas of the moons of Mars

This paper contains a complete set of the best enhancements of Mariner 9 high resolution television pictures of Phobos and Deimos, consisting of 27 different views of Phobos, and 9 of Deimos. Pertinent data about the pictures are arranged in convenient tabular and graphical form.