Mineral dissolution in the Cape Cod aquifer, Massachusetts, USA: I . Reaction stoichiometry and impact of accessory feldspar and glauconite on strontium isotopes, solute concentrations, and REY distribution

To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between ⁸⁷Sr/⁸⁶Sr and Sr concentration is observed. At all depths, the ⁸⁷Sr/⁸⁶Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-⁸⁷Sr/⁸⁶Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-⁸⁷Sr/⁸⁶Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic ⁸⁷Sr because of its young Pleistocene age. The low ⁸⁷Sr/⁸⁶Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater chemistry, even in relatively simple aquifers, may be complicated by solute contributions from “exotic” accessory minerals such as glauconite. To detect such peculiarities, groundwater studies should combine the study of elemental concentration and isotopic composition of several solutes that show different geochemical behavior.     

Recent landslide activity in Manaihan,East Belgium

Past landslides have been recognized in the Battice area in E-Belgium. In contrast to the other inactive landslides, the Manaihan landslide responded immediately to heavy rainfall events in the last two decades. This study aims to map its spatial extent and the dominant surface features; to measure surface displacement using GPS; to investigate subsurface structure with Cone penetration test (CPT) and corings; and to determine the depth of the shear surface by inclinometers. Results show a partial landslide reactivation. Surface velocities range between 20 and 40 cm/year and are strongly dependent on winter rainfall. CPT results give clear boundaries between the landslide mass and the undisturbed bedrock in the head scarp. Distinct shear surfaces have been determined with displacement rates up to 15.8 mm in 21 days. Further research should apply geophysical methods for two-dimensional information on the ground, investigate geotechnical properties of the landslide mass, model slope instability, and determine the influence of a sewage pipe crossing the central landslide mass as a potential cause for landslide activity.     

Weathering of ilmenite from Chavara deposit and its comparison with Manavalakurichi placer ilmenite,southwestern India

The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10^?6 m³ kg^?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb₂O₅ (0.28%), Cr₂O₃ (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO₂ (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe³⁺/Fe²⁺ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene.     

Spectrophotometric observations of variable stars

We present the results of our visual and near-infrared spectrophotometric observations for 77 variable stars obtained during 1971–1991 in Chile, Armenia, and Bolivia. The quasi-monochromatic, extraatmospheric fluxes from the stars are given in absolute energy units (W m^?2 m^?1) at all wavelengths of the spectral range at 2.5-nm intervals.     

Exact Boltzmann-Gas Filled Bianchi Type V Space-Times

Bianchi type V cosmological models are studied that contain a relativistic ideal Boltzmann gas. The effect of a cosmological constant upon the space-time geometry is also considered. In both high and low temperature limit the general solution of the Einstein gravitational field equations can be expressed in an exact closed parametric form. At final stages, depending on the presence or absence of the cosmological constant, cosmologies are driven to an isotropic inflationary open de Sitter type Universe or to an isotropic open Friedmann era.     

Evidence for the depletion of ammonia in the Uranus atmosphere

The theoretical disk brightness temperature spectra for Uranus are computed and compared with the observed microwave spectrum. It is shown that the emission observed at short centimeter wavelengths originates deep below the region where ammonia would ordinarily begin to condense. We demonstrate that this result is inconsistent with a wide range of atmospheric models in which the partial pressure of NH₃ is given by the vapor-pressure equation in the upper atmosphere. It is estimated that the ammonia mixing ratio must be less than 10^?6 in the 150 to 200°K temperature range. This is two orders of magnitude less than the expected mixing ratio based on solar abundances. The evidence for this depletion and a possible explanation are discussed.     

AN ANALYTICAL SCHEME FOR CHONDRITIC METEORITES

A chemical scheme is reported for the analysis of chondritic materials and results are presented for the Cocklebiddy meteorite. Analytical problems associated with chondrite inhomogeneity including phase leaching selectivity and the completeness of individual phase attack are considered. Data obtained by this method can be used to classify chondrites according to the accepted weight and molar ratio methods (Van Schmus and Wood, 1967: Wasson, 1974) The analytical scheme uses selective leaching techniques to determine, in each sample, the chemical composition of metallic, sulphide and silicate phases. Elemental concentrations are obtained by atomic absorption spectrometry, flame photometry, spectrophotometry or titration techniques, and the total sample average compositions are determined on fully oxidised specimens by XRF     

A high-sensitivity search for extraterrestrial intelligence at γ18 cm

We have conducted a targeted high-sensitivity search for narrow-band signals near γ18 cm using the 91-m radiotelescope of the National Radio Astronomy Observatory. The search included 201 nearby solar-type stars and achieved a frequency resolution of 5.5 Hz over a 1.4-MHz bandwidth. This high spectral Mark I VLBI recording terminal in conjunction with the CDC 7600 computational facility at the NASA-Ames Research Center. This is the first high-resolution search for narrow-band signals in this wavelength regime. To date it is the most sensitive search per unit observing time of any search strategy which does not postulate a unique magic frequency. Our data show no evidence for narrow-band signals due to extraterrestrial intelligence at a 12-σ upper limit on signal strength of 1.1 × 10^?23 W m^?2.     

深反射地震揭示喜马拉雅地区地壳上地幔的复杂结构

报告了中、美两国在喜马拉雅山区进行的第一次深反射地震试验的结果．试验剖面南起喜马拉雅山山脊南亚东县的帕里镇,向北穿过喜马拉雅山脊的荡拉,到达康马南的萨马达．剖面长约１００ｋｍ．共中心点（ＣＭＰ）叠加剖面上显示出：１．在地壳中部有一强反射带,向北缓倾斜下去,延长达１００ｋｍ以上．它可能代表了一个活动的逆冲断裂或是一条巨大的拆离带,印度地壳整体或下地壳沿此拆离层俯冲到藏南之下．２．上部地壳的反射很丰富,显示了上地壳存在着大规模的叠瓦状结构．３．下地壳的反射同相轴呈现短而有规律的分布,显示了塑性流变特征．４．在测线南部莫霍反射明显,深度达７２－７５ｋｍ．发现南部有双莫霍层的存在．５．试验中还取得莫霍层下面３２,３８,４８ｓ等双程走时的多条反射,向北倾斜,反射同相轴延续较长,信息丰富,反映了上地幔的成层结构和变形特征．这些结果对印度大陆地壳整体或其下地壳俯冲到藏南特提斯喜马拉雅地壳之下,并导致西藏南端地壳增厚的观点,给予了实质性的支持．