Nitrogen uptake,ammonium oxidation and nitrous oxide (N2O) levels in the coastal waters of western Cook Strait,New Zealand

Vertical measurements of $\text{NH}{}_4{}^{\mathrm{+}}$, $\text{NO}{}_3{}^{\mathrm{?}}$ and N₂O concentrations, $\text{NO}{}_3{}^{\mathrm{?}}$ and $\text{NH}{}_4{}^{\mathrm{+}}$ uptake, and $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom $\text{NO}{}_3{}^{\mathrm{?}}\text{N l}{}^{\mathrm{?1}}$ at the most strongly stratified station whereas $\text{NH}{}_4{}^{\mathrm{+}}$ was relatively constant with depth at all stations (～0.1 μg-atom $\text{NH}{}_4{}^{\mathrm{+}}\text{N l}{}^{\mathrm{?1}}$). The highest rates of $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation generally occurred in the near surface waters and decreased with depth. N₂O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation by nitrifying bacteria may account for about 30% of the total $\text{NH}{}_4{}^{\mathrm{+}}$ utilization (i.e. bacterial+agal) and, assuming oxidation through to $\text{NO}{}_3{}^{\mathrm{?}}$, may supply about 40% of the algal requirements of $\text{NO}{}_3{}^{\mathrm{?}}$ in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton.     

Line broadening on HF ocean surface radar backscatter spectra

Experimental results from an array of moored current meters and an HF ocean surface radar support the idea that line broadening on the radar spectra is caused by the velocity distribution within the radar target cell. The experiment was done in the wake of a small island where the velocity variations were severe. An estimate is made of the line broadening which can be expected. In a turbulent flow with dissipation rate of the orderepsilon sim 10^{-10}m^{2}s^{-3}and target cell size 1 3000 m, the line broadening isDeltaf sim 10^{-3}Hz. This would be resolved with a radar time series ofsim 20min and indicates that the HF ocean surface radar technique has potential in the observation of surface velocity distributions.     

Growth, interaction and seismogenic potential of coupled active normal faults (Isernia Basin, central-southern Italy)

The inception and growth of the active Carpino-Le Piane Basin Fault System (CLPBFS; central-southern Apennines, Italy) was analysed with respect to the neighbouring Isernia and Surrounding (ISFS) and Boiano Basin (BBFS) extensional Fault Systems. ³⁹Ar–⁴⁰Ar dating showed that the BBFS was already active 649 ± 21 ka bp and that the ISFS was active at least 476 ±10 ka bp , whereas the activity of the CLPBFS started certainly later than 253 ± 22 ka bp , and very probably as recently as <28 ka bp . These ages, combined with structural data (geometry and kinematics of the fault systems), indicate that the inception and development of the CLPBFS could be strictly related to the stress changes caused by earthquakes occurring on the BBFS.     

Pb, Sr and Nd isotope study of two co-existing magmas in the Nízke Tatry Mountains, Western Carpathians (Slovakia)

Summary Two co-existing plutonic rocks (diorite and granodiorite) were studied from an intrusion of Variscan age in the Raztocna Valley – Nízke Tatry Mountains, Western Carpathians. Geochemical analyses of major and trace elements constrain a volcanic arc as emplacement environment and give the first hints of a mixture of two magmatic end-members: the so-called Prasivá granodiorite and the Raztocna diorite. The ⁸⁷Sr/⁸⁶Sr₍₀₎ ratios vary between 0.7075 and 0.7118, the ε Nd₍₀₎ values range from −1.4 to −5.0. Common Pb isotopes reveal a dominant crustal source with minor influences from a mantle and a lower crustal source. Modelling based on Sr and Nd isotope data and using three component mixing calculations indicates that mixing of 2/3 of upper mantle material with 1/3 upper crustal material can produce the isotopic composition of the Raztocna diorite. Very minor amounts of lower crust were incorporated in the diorite. For the Prasivá granodiorite, the mixing ratio of upper mantle and upper crust is similar, but a lower crustal reservoir contributed about 5–10% of the source material.     

The Early Pleistocene Praetiglian and Ludhamian pollen stages in the North Sea Basin and their relationship to the marine isotope record

In this paper, the currently accepted correlation of the Early Pleistocene Ludhamian stage of England with the Tiglian‐A sub‐stage of the Netherlands is challenged. Recent investigations of Early Pleistocene marine North Sea deposits from a borehole near Noordwijk (the Netherlands) yielded evidence from molluscs, dinoflagellate cysts and sporomorphs for an alternation of warm‐temperate and arctic intervals within the Praetiglian and Tiglian stages. Marine equivalents of the terrestrial‐based pollen sub‐stages Tiglian A and B have been recognised in the upper part of the sequence. A Praetiglian age can be assigned to the lower part of the sequence on the basis of mollusc analysis. Within the Praetiglian, an alternation of warm and cold phases has been recognised from both the dinoflagellate cyst and molluscan records. Three cold phases within the Praetiglian are tentatively correlated with marine isotope stages (MIS) 96–100. The molluscan assemblages provide evidence for climate forcing of the sea level: highest sea levels are reached in the warm‐temperate intervals. Within the Praetiglian, an interval with an acme zone of the dinoflagellate cyst Impagidinium multiplexum, is correlated with the Ludhamian and tentatively linked to MIS 97 and/or MIS 96. The cold molluscan assemblages from the Noordwijk borehole include an acme zone of Megayoldia thraciaeformis, the first and only occurrence of this North Pacific bivalve in the North Sea Basin. Copyright © 2006 John Wiley & Sons, Ltd.     

A simulation tool for high data-rate acoustic communication in ashallow-water, time-varying channel

The paper discusses the development of a simulation tool to model high data-rate acoustic communication in shallow water. The simulation tool is able to generate synthetic time series of signals received at a transducer array after transmission across a shallow-water communication channel. The simulation tool is suitable for testing advanced signal processing techniques for message recovery. A channel model has been developed based on the physical aspects of the acoustic channel. Special emphasis has been given to fluctuations of the signal transmission caused by time-varying multipath effects. At shorter ranges, the temporal variations are dominated by acoustic scattering from the moving sea surface. Therefore, the channel model produces a coherence function which may be interpreted as a time-varying reflection coefficient for the surface scattered acoustical path. A static, range-independent ray model identifies the significant multipaths, and the surface path is modulated with the time-varying reflection coefficient. The advantages and limitations of the channel model are discussed and assumptions necessary to overcome the limitations are emphasised. Based on the assumptions, an algorithm has been developed and implemented to model how a binary message will be modulated when transmitted by a transducer, is distorted in the channel and finally is received by a transducer array     

Application of an improved self-starter to geoacoustic inversion

The self-starter is improved using the operator of the split-step Pade solution. In addition to providing greater stability and being applicable closer to the source, the improved self-starter is an efficient forward model for geoacoustic inversion. It is necessary to solve only O(10) tridiagonal systems of equations to obtain the acoustic field on a vertical array located O(10) wavelengths from a source. This experimental configuration is effective for geoacoustic inverse problems involving unknown parameters deep in the ocean bottom. For problems involving depth-dependent acoustic parameters, the improved self-starter can be used to solve nonlinear inverse problems involving O(10) unknown sediment parameters in less than a minute on the current generation of workstations     

Controls on the chemistry of runoff from an upland peat catchment

This study uses 2 years of data from a detailed weekly water sampling programme in a 11·4 km² upland peat catchment in the Northern Pennines, UK. The sampling comprised precipitation, soil‐water samples and a number of streams, including the basin outlet. Samples were analysed for: pH, conductivity, alkalinity, Na, K, Ca, Mg, Fe, Al, Total N, SO₄, Cl and colour. Principal component analysis (PCA) was used to identify end‐members and compositional trends in order to identify controls on the development of water composition. The study showed that the direct use of PCA had several advantages over the use of end‐member mixing analysis (EMMA) as it combines an analysis of mixing and evolving waters without the assumption of having to know the compositional sources of the water. In its application to an upland peat catchment, the study supports the view that shallow throughflow at the catotelm/acrotelm boundary is responsible for storm runoff generation and shows that baseflow is controlled by cation exchange in the catotelm and mixing with a base‐rich groundwater. Copyright © 2003 John Wiley & Sons, Ltd.     

Isobaric cooling and anti-clockwise P–T paths in the Variscan Odenwald Crystalline Complex, Germany

Mineral assemblages in Al₂O₃‐rich, SiO₂‐ and K₂O‐poor metapelitic rocks from the western Odenwald Crystalline Complex (Variscan Mid‐German Crystalline Rise, southern Germany) include corundum, spinel, cordierite, sillimanite, garnet and staurolite. Quartz is absent from almost all samples. Therefore, the applicability of conventional geothermobarometry is very limited or even impossible. Detailed petrographic investigation on selected samples permits inference of the sequence of appearance and disappearance of several mineral assemblages. The recognition of such partial re‐equilibration stages and their associated mineral assemblages, together with mineral stabilities predicted from KFMASH pseudosections, enables the determination of the pressure‐temperature (P–T) trajectories experienced by these rocks during the Variscan metamorphism. The rocks were metamorphosed under low‐P/high‐T conditions and underwent an anti‐clockwise P–T evolution. A pressure increase from about 2 kbar to 4 ± 0.5 kbar was accompanied by heating. Peak metamorphic conditions were reached at pressures of 4 ± 0.5 kbar and temperatures of at least 640 °C, probably even higher. The retrograde evolution is characterised by near‐isobaric cooling from ≥ 640 °C to approximately 550 °C. The rocks underwent the anti‐clockwise evolution in a subduction‐related magmatic arc setting. The close spatial association of the low‐P/high‐T rocks with recently discovered metabasic eclogites in the eastern part of the Odenwald Crystalline Complex may indicate a fossil paired metamorphic belt in the Central European Variscides.