Assessing groundwater storage changes in the Nubian aquifer using GRACE data

Gravity Recovery and Climate Experiment (GRACE) level two (L2) data is used in estimating the groundwater storage changes (GWSC) in the Nubian Sandstone Aquifer System (NSAS). This set of data consists of spherical harmonics coefficients with specific degree and order. The GRACE data is de-correlated using a sixth degree polynomial in order to reduce the effect of the noise error resulting from the correlation between the spherical harmonics coefficients with the same degree parity. The GRACE estimates of GWSC are smoothed using Gaussian filter with half width of 1000 km. This half width is chosen in order to maximize the correlation between the GRACE estimates of GWSC and previous modeling results of the NSAS. The loss in groundwater storage occurring in each of the four countries sharing the NSAS is calculated to assess the sustainability of using the NSAS as a water resource in each country. The overarching finding in this study is that NSAS is losing its groundwater storage at a very high rate. Also, it is found that Egypt is the fastest in losing its groundwater storage from the NSAS. This loss of groundwater storage in Egypt may not necessarily be resulting from in-country extractions because of the trans-boundary nature of this aquifer. The GRACE-based estimates are found to be close to available data and previous modeling results of the NSAS.     

Controlling factors of groundwater hydrochemistry in a small island’s aquifer

Factor analysis was applied to the hydrochemical data set of Manukan Island in order to extract the principal factors corresponding to the different sources of variation in the hydrochemistry. The application of varimax rotation was to ensure the clear definition of the main sources of variation in the hydrochemistry. The geochemical data of dissolved major, minor and trace constituents in the groundwater samples indicates the main processes responsible for the geochemistry evolution. By using Kaiser normalization, principal factors were extracted from the data for each location. The analysis reveals that there are four sources of solutes: (1) seawater intrusion; (2) leaching process of underlying rock mediated by pH; (3) minerals weathering process and (4) dissolution of carbonate minerals characterized by high loadings of Ca, Zn and Mg. Such processes are dominated by the significant role of anthropogenic impact from the over abstraction of fresh water from the aquifer. Those factors contributed to the changes of the groundwater geochemistry behavior explain the effect of rising extraction of freshwater from the aquifer.     

Environmental impact on groundwater of Maheshwaram Watershed,Ranga Reddy district,Andhra Pradesh

Maheshwaram watershed is situated in Ranga Reddy district of at a distance of about 30 km south of Hyderabad. The watershed has an area of 53 km² and has hard rock aquifers with semi-arid climate. The study area has been expanding at a fast pace and now has the distinction of being one of the fastest growing urban centers, facing the problem of groundwater depletion and quality deterioration due to the absence of perennial source of surface water and also due to over exploitation. Human activities involving industrial and agricultural development and the inadequate management of land and water resources have, directly or indirectly resulted in the degradation of environment viz. water and soil.     

Organisation hydrochimique,biologique et sédimentologique d’un lac intracontinental à peuplements lagunaires : la Birket Karoun (Fayoum,Egypte)

Résumé

La Birket Karoun a été étudiée d’un point de vue biogéologique sur une période de 12 mois. Les données ainsi obtenues, ajoutées à celles de la littérature disponible, permettent de présenter les caractéristiques biogéologiques essentielles de ce bassin original.

Le lac n’est alimenté actuellement que par des eaux continentales issues du système nilotique ce qui entraîne des propriétés hydrochimiques assez différentes des corps d’eau paraliques influencés par la mer. Cependant, les caractéristiques hydrologiques, biologiques et sédimen-taires de la Birket Karoun la classent parmi les écosystèmes de type lagunaire. Il est même possible d’y reconnaître une organisation biogéologique zonale très semblable à celle des lagunes, la partie la plus « marine » (ou la moins confinée) se situant à l’opposé de la zone des apports d’eau douce. Une connexion entre le lac et la mer, actuelle ou passée, étant à peu près exclues, il faut admettre que les eaux continentales concentrées peuvent présenter, dans certains cas, des caractéristiques chimiques et biochimiques presque marines vis-à-vis des êtres vivants.

Dans cette optique, la Birket Karoun apparaît comme un modèle actuel susceptible de fournir une alternative à l’hypothèse d’une « Mer Saharienne » pour rendre compte de l’existence des lacs sahariens pleistocènes à faunes fossiles lagunaires.     

Mid-Paleocene event at Gabal Nezzazat,Sinai, Egypt: planktonic foraminiferal biostratigraphy,mineralogy and geochemistry

The Qreiya Beds that record the ‘mid-Paleocene event’ at Gabal Nezzazat occur within the Igorina albeari (P3b) Zone and constitute part of a 14-m thick shale succession that ranges in age from Early to Late Paleocene. They are composed of four alternating dark grey and brown shale beds, which are thinly laminated, phosphatic, organic-rich and extremely sulphidic. They are characterized by distinct enrichment and high peak anomalies in chalcophiles (Zn, Co, Ni, Cu and Pb) and organic association elements (V and Cr), especially within the brown organic-rich beds. It is concluded that these elements are incorporated into the phosphatic debris, sulphides and organic matter. In contrast, the grey beds are enriched in clay minerals and quartz. Clay mineral assemblages indicate alternating periods of warm/humid climate (high kaolinite) and dry climate (low kaolinite) during the formation of the grey and brown beds, respectively. The sediments of the Qreiya Beds yield lithological, biotic, geochemical and mineralogical data indicative of suboxic/anoxic marine environments as a result of high productivity and/or upwelling. The top metre of the succession below the Qreiya Beds is characterized by a progressive change from faunas dominated by praemurcurids to faunas dominated by Morozovilids, and by a progressive upward decrease in δ¹³C_carb and δ¹⁸O_carb values. The foraminiferal faunal change may reflect shallowing and warming preceding deposition of the Qreiya Beds. The change in isotopic values is inferred to be the result of surface weathering, fluvial input and diagenesis with no evidence of any primary change that could support presence of a hyperthermal event.     

Les tholeiites a affinité alcaline du secteur ouest du Siroua (Anti-Atlas central, Maroc): temoins d'une distension au Néoproterozoïque

The Upper Proterozoic granitoids of the western part of the Siroua Massif (central Anti-Atlas, Morocco) are cut by doleritic dykes injected along submeridian and equatorial directions. These dykes were emplaced before deposition of late Neoproterozoic formations (PIII). According to and incompatible element ratios, these dolerites constitue two discrete chemical groups unrelated to orientation and thickness. They are both enriched in large ion lithophile elements, Zr, Th and light rare earth elements, and correspond to continental tholeiites displaying an alkaline affinity. This alkaline affinity is also confirmed by clinopyroxene and amphibole chemistry. Emplacement of these doleritic dykes occurred under an extensional regime active in the Anti-Atlas range during the Upper Proterozoic.     

Electrical Resistivity Imaging technique to delineate coal seam barrier thickness and demarcate water filled voids

Exploration and exploitation of coal seams is one of the major resources for the energy sector in any country but at the same time water filled voids/water logged areas in the old workings of these seams are very critical problems for the coal mining industry. In such situations, disasters like inundation, landslides, collapsing of the old seams may occur. In this regard, it is necessary to find out the water saturated/water filled voids and zones in the mining areas. Since no established technique is available to find such zones, an experimental study using Electrical Resistivity Imaging (ERI) has been carried out in one of the coal mining areas near Dhanbad, to find out the feasibility of finding the barrier thickness and the water logged area in underground coal mines. The area under study forms part of Jharia coalfield in Dhanbad district, Jharkhand state. The coal bearing rocks of Barakar Formation of Lower Permian age (Gondwana period) occur in the area under a thin cover (10 m to15 m) of soil and or alluvium. Coal bearing Barakar Formations consist mainly of sandstone of varying grain size, intercalation of shale and sandstone, grey and carbonaceous-shale and coal seams. Since the water saturation reduces the resistivity of a formation to a large extent, water filled voids and old coal workings are expected to have significant resistivity contrast with the surrounding host rock. Hence, ERI technique was applied in such an environment as this technique uses high-density data acquisition both laterally and vertically by using multiple number of electrodes. Along with ERI, mise-à-la-masse (also called charged body) technique was also employed at one of the promising sites to find out the connectivity of water logged areas and also detection of these old workings from the surface measurements was analyzed. The interpreted 2D resistivity sections have clearly indicated the water bearing zone(s) along the profile which was well confirmed with the existing water level in the nearby borewells. On the other hand, this technique did not identify the size of the coal pillar and gallery (air filled voids), which might be due to the small size of the voids (i.e. about 2 m × 2 m) below a depth of 15m and more but have indicated altogether as a high resistive zone ranging from 600–1000 Ohm-m.     

Modeling Biogeochemistry,the Key for Understanding Environmental Chemistry of a Semi－Arid Soil in Egypt

1IntroductionThecomponentsoftheenvironmentaredamagedbyagriculturalpractices.Soilslosstheirfer tilityandwaterdeterioratesduetopollution .Chemicalweatheringofmineralandsoiloccursattheinterfacesbetweentheliquidandsolidphases;consequentlythesurfaceareaandcompositionofthemineralsplayanimportantroleinthisprocess.GarrelsandMackenzie ( 1 96 7)suggestedthatincon gruentweatheringreactionswouldproducedissolvedspeciesandnewsolidsthataremorestableintheweatheringenvironmentthantheoriginalbedrockminerals.Ro…     

Present environment and historic changes from the record of lake sediments, Dhaka City, Bangladesh

Changes in the urban environment of Dhaka City have been evaluated from the geochemical compositions of bottom sediments from two lakes, Gulshan-1 and –2. Abundances of Pb, Zn, Fe₂O₃ and total sulfur in a Gulshan-1 core gradually increase toward the sediment–water interface. Three stages of condition change can be recognized in Gulshan-1, based on trace metal concentration patterns. The basal Stage I corresponds to background Dhaka sedimentation, whereas gradual increase in Stage II represents the beginning of pollution. Marked increases in Pb and Zn in Stage III reflect rapid urban development and increased emissions to the atmosphere. The condition of the Dhaka environment is compared to that of Japan based on Zn–Fe₂O₃ and Pb–Fe₂O₃ relations. Zn–Fe₂O₃ ratios in Stage I Dhaka sediments are similar to normal Japanese sediments, whereas Stage II data lie on the same trend as Japan urban sediments. Dhaka Stage III samples have greater Zn:Fe₂O₃ ratios than Japanese urban sediments, suggesting Zn pollution from poorly-controlled industrial sources. In contrast, the Dhaka Pb–Fe₂O₃ trend lies between normal and urban Japanese sediments. Although vehicle emissions in Dhaka are now significant, the data suggest that Pb pollution from this source remains in its early stages.