基于旋翼无人机的大气边界层环境气象垂直观测及订正方法的研究

基于旋翼无人机开展大气边界层观测可为气象要素和大气污染物垂直结构的研究提供具有高时空解析能力的新方法,有助于深入理解低层大气物理化学变化机制。本文详述了旋翼无人机在开展大气边界层环境气象垂直观测实验的应用及优势。基于自主研发的旋翼无人机环境气象观测平台,通过开展传感器在无人机上不同的搭载位置,以及旋翼无人机与探空气球、高塔的对比观测实验,明确了旋翼无人机对气象环境观测的影响及合理的搭载方式。研究进一步在湖北重污染天气条件下开展了0—1000 m的大气边界层垂直观测,并研发了基于旋翼无人机姿态数据的大气边界层气象要素及污染物垂直观测的订正方法。结果表明:实验获取了2—10 m垂直分辨率的高质量大气廓线数据,可精细捕捉大气边界层及其逆温层高度和污染物浓度等要素的垂直变化特征。本文旨在为无人机观测的科研应用提供一种技术可行且数据可靠的观测手段。     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

中国大陆西部强震前超低频磁场时空变化特征

对2015年至2019年期间中国大陆西部的磁通门磁力仪秒采样观测资料开展了5—100 s频段的地磁垂直强度极化分析,并运用一些数学方法对分析结果进行了处理.结果显示,极化高值在经向和纬向均无明显的形态和幅值变化,且极化高值与地磁外源场扰动无关.在此基础上筛选出18次极化高值异常事件,利用插值方法得到了极化高值异常的空间...     

GEN_MAT: A MATLAB‐based map generalization algorithm toolbox

Assistive tools are important for improving teaching and learning quality in courses that involve practical work. This article presents an overview of GEN_MAT, the first MATLAB‐based map generalization algorithm toolbox. The toolbox provides 42 map generalization algorithms for aggregation, selective omission, simplification, smoothing, collapse, agglomeration, merging, dissolving, displacement, and typification. A beta test of the application of GEN_MAT in teaching and learning was conducted. Evaluations showed that GEN_MAT has positive effects on teaching and learning. Comparing tool‐based and non‐tool‐based courses indicated that the experimental group performed better than the control group, and the two groups exhibited significant discrepancy (p < 0.05) in confidence, awareness, skills and attitudes or behaviors.     

三峡水库枯水期补水调度对洞庭湖越冬白鹤(Grus leucogeranus)摄食栖息地的影响

摄食栖息地面积是反映越冬水鸟生存空间的直接指标,三峡水库运行后洞庭湖枯水期水文节律出现新的变化,给越冬水鸟摄食栖息地造成的影响尚不明确.为定量描述三峡水库枯水期不同出库流量对洞庭湖越冬水鸟摄食栖息地的影响,以洞庭湖典型的珍稀越冬水鸟——白鹤(Grus leucogeranus)为指示性候鸟,以白鹤摄食对栖息地水深需求作为关键生态因子,建立白鹤摄食对水深需求的栖息地适宜度模型.构建涵盖长江干流、三口河系、洞庭湖及其四水尾闾河段的江湖一体化耦合水动力模型,实现栖息地水动力分布特征的精确模拟.在此基础上耦合栖息地适宜度模型和水动力模型,建立了面向白鹤摄食对三峡水库出库流量需求的物理栖息地模型,量化不同出库流量对应的白鹤摄食栖息地加权可利用面积,定量分析水库运行对白鹤摄食栖息地面积的影响.结果表明:1月中旬三峡水库不同出库流量下洞庭湖白鹤潜在摄食栖息地面积保持稳定并随出库流量的增加呈增大趋势,维持在101.40~121.84 km²之间,其中东洞庭湖摄食栖息地面积在7.49~9.86 km²之间,南洞庭湖(含横岭湖)摄食栖息地面积在47.37~60.34 km²之间,西洞庭湖摄食栖息地面积在46.54~51.64 km²之间.不同湖区摄食栖息地面积随着三峡水库出库流量的增加均呈增大的趋势,说明三峡水库枯水期补水调度对于维持栖息地面积具有重要作用.较三峡水库运行前相比,白鹤摄食栖息地面积最大增加20.44 km²,对应的增幅为20.16%.成果明晰了三峡水库运行对洞庭湖白鹤摄食栖息地面积的影响规律,可为通过三峡水库补水调度改善洞庭湖越冬水鸟摄食栖息地生境提供理论基础.     

2011年3月24日缅甸孟帕亚M7.2级地震地震构造浅析

本文简要论述了2011年3月24日缅甸孟帕亚M7.2级地震的发震构造,孟帕亚断裂的活动特征、活动时代,以及断裂与历史地震活动的关系.     

云南腾冲青海湖泊沉积物物化参数的特点、环境意义及末次冰消期以来气候环境变化

根据对云南腾冲青海湖泊沉积钻孔样品的粒度特征、总有机碳、碳酸盐、磁化率及年代学分析测试, 探讨了各指标的变化特点及其环境指示意义, 指出了云南高原湖泊沉积物化指标的特殊性及其变化特点。在此基础上, 重建了云南腾冲地区末次冰消期(15830a B.P.)以来沉积环境与气候干湿变化历史。通过青海沉积物年代序列的重建和综合各物化参数分析得出, 云南腾冲地区自15830a B.P.以来总体呈现冷湿-温湿-暖干-温和偏干的气候演变过程, 并可分为4个阶段, 即15830~12790a B.P.气候温凉偏湿; 12790~4680a B.P.为温暖湿润期, 湖泊水位高, 气候湿暖, 降水多; 4680~312a B.P.气候特征呈现出从温湿到暖干气候逐渐演化, 降水减少, 湖泊水位下降; 312a B.P.以来气候特征为前期温和湿润, 后期具有暖干化特征, 反映了近几十年来全球气候变暖导致的气候变化趋势并叠加了研究区人类活动对区域环境的影响。     

Modelling combined open channel flow by artificial neural networks

Combined open channel flow is encountered in many hydraulic engineering structures and processes, such as irrigation ditches and wastewater treatment facilities. Extensive experimental studies have conducted to investigate combined flow characteristics. Nevertheless, there is no simple relationship that can fully describe the velocity profiles in a turbulent flow. The artificial neural network (ANN) has great computational capability for solving various complex problems, such as function approximation. The main objective of this study is to evaluate the applicability of the ANN for simulating velocity profiles, velocity contours and estimating the discharges accordingly. The velocity profiles measured by an acoustic doppler velocimeter in the open channel of the Chihtan purification plant, Taipei, with different discharges at fixed measuring section and different depths are presented. The total number of data sets is 640 and the data sets are split into two subsets, i.e. training and validation sets. The backpropagation algorithm is used to construct the neural network. The results demonstrate that the velocity profiles can be modelled by the ANN, and the ANN constructed can nicely fit the velocity profiles and can precisely predict the discharges for the conditions investigated. Copyright © 2005 John Wiley & Sons, Ltd.     

Sheath formation inOscillatoria agardhii Gomont

Sheath formation was observed in laboratory culturedO. agardhii. The sheath serves as a protective cover against bacteria. Some comments on sheath formation by this alga are given.

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Zusammenfassung Scheidenbildung beiOscillatoria agardhii Gomont Im Kulturmaterial vonOscillatoria agardhii Gomont wurde die Bildung von Scheiden beobachtet. Diese dienen als Schutz gegen Bakterien. Es werden weitere überlegungen über die Scheidenbildung bei dieser Alge angestellt.

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Résumé Formation de gaines chezOscillatoria agardhii Gomont La formation d’une gaine chezOscillatoria agardhii Gomont fut observée dans une culture. Ces gaines protègent les algues contre les bactéries. Des considérations ultérieures sont faites sur le phénomène des gaines chez cette algue.

     

兴蒙造山带及邻区地壳速度结构特征

兴蒙造山带位于中亚造山带东段, 作为古亚洲构造域的重要组成部分, 由西伯利亚板块与华北板块碰撞拼合而成, 其经历了大陆裂解、洋盆扩张、洋壳俯冲消减和碰撞拼合造山等复杂的构造演化过程.为了利用壳幔结构约束造山带演化的深部过程, 跨越华北地块北缘、松辽—锡林浩特地块、兴安地块以及索伦—西拉木伦缝合带和二连—贺根山缝合带, 实施了一条520 km长的深地震测深剖面, 获得了高质量的人工源大当量的宽角反射和折射地震资料, 并采用地震动力学射线方法获得地壳速度结构.结果显示: (1)研究区地壳平均速度为6.15~6.3 km·s^-1, Pn波速度为7.8~8.2 km·s^-1; (2)地壳厚度约为36.1~42.2 km, 最厚位置(~42.2 km)对应地表大兴安岭主峰, 说明大兴安岭在此位置存在山根; (3)地壳速度在1.5~6.8 km·s^-1范围内, 认为在该区地壳内不存在洋壳物质; (4)主要断裂带或缝合带位于速度等值线变化剧烈的梯度带上; (5)速度结构显示研究区具有明显的横向分区和纵向分层的特点.地壳内速度剧烈变化特征表明兴蒙造山带的地壳物质组成不均匀, 尤其中下地壳, 速度等值线起伏剧烈.这种复杂的地壳速度结构应该与中生代以来多板块汇聚引发的多期区域性伸展和挤压作用有关.