长江口海域有害重金属转移机理——Ⅱ.粘土矿物对重金属吸附作用的热力学和动力学的实验室模拟研究

关于控制水体中重金属含量的因素,六十年代以来文献陆续有所报导.在海水体系中粘土矿物对重金属的固定作用的研究,较早期的有Chester(1965)的伊利石吸附海水中钴和锌的研究.近五年来又见有Rermers[1]、Murray[2]、Meyers[3]、O'conner[4]、Weijden[5]以及Robin[6]等进一步分别探讨了粘土矿物对重金属吸附作用的影响因素、吸附能力及吸附动力学等问题,其中有的还提出了吸附作用的模式.     

三峡工程对长江口区无脊椎动物资源影响的预测

长江大量径流给其河口及邻近海域带来丰富的营养物质,维持了长江河口生态系统的巨大生产力,并使之成为多种重要经济鱼虾类的索饵和产卵场。长江口生态环境的变化,对我国最大、最重要的浙江舟山渔场和江苏吕四渔场的渔业资源有举足轻重的影响。三峡工程的兴建将使长江入海径流量及其季节分配有很大改变,也不可避免地影响到河口和近海的海洋环境、经济动物的组成及资源状况。为研究长江口无脊椎动物资源结构及其分布特征,以及预测三峡工程对自然生态环境的影响,于1985年9月至1986年8月进行了无脊椎动物资源底拖网试捕调查。本文系统整理调查所得资料,结合历史资料进行分析研究。     

西太平洋暖池区气象学特征分析

本文根据ＴＯＧＡ－ＣＯＡＲＥ强化观测资料及卫星资料分析讨论了西太平洋暖池区１１－２月间海面气象要素的平均特征。分析发现海面气压平均日变化似乎同中纬度区明显不同。文中还分析讨论了在西太暖池区西风爆发、赤道浅涡、信风逆温及ＩＴＣＥ和南太平洋辐合带ＳＰＣＺ的变化特征。     

Co–rich Mn crusts from the Magellan Seamount cluster: the long journey through time

The Magellan seamounts began forming as large submarine shield volcanoes south of the equator during the Cretaceous. These volcanoes formed as a cluster on the small Pacific plate in a period when tectonic stress was absent. Thermal subsidence of the seafloor led to sinking of these volcanoes and the formation of guyots as the seamounts crossed the equatorial South Pacific (10–0°S) sequentially and ocean surface temperatures became too high for calcareous organisms to survive. Guyot formation was completed between about 59 and 45 Ma and the guyots became phosphatized at about 39–34 and 27–21 Ma. Ferromanganese crusts began formation as proto-crusts on the seamounts and guyots of the Magellan Seamount cluster towards the end of the Cretaceous up to 55 Ma after the formation of the seamounts themselves. The chemical composition of these crusts evolved over time in a series of steps in response to changes in global climate and ocean circulation. The great thickness of these crusts (up to 15–20 cm) reflects their very long period of growth. The high Co contents of the outer parts of the crusts are a consequence of the increasing deep circulation of the ocean and the resulting deepening of the oxygen minimum zone with time. Growth of the Co-rich Mn crusts in the Magellan Seamount cluster can be considered to be the culmination of a long journey through time.     

Estimating the geostrophic velocity obtained by HF radar observations in the upstream area of the Kuroshio

A method to extract geostrophic current in the daily mean HF radar data in the Kuroshio upstream region is established by comparison with geostrophic velocity determined from the along-track altimetry data. The estimated Ekman current in the HF velocity is 1.2% (1.5%) and 48° (38°)-clockwise rotated with respect to the daily mean wind in (outside) the Kuroshio. Furthermore, additional temporal smoothing is found necessary to remove residual ageostrophic currents such as the inertial oscillation. After removal of the ageostrophic components, the HF geostrophic velocity agrees well with that from the altimetry data with rms difference 0.14 (0.12) m/s in (outside) the Kuroshio.     

A study on benthic community structure in west of the Taiwan Strait and near the Taiwan Shoals

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水平孔钻渣运移机理研究

有效地排除钻渣是钻井液的主要功能之一。本文结合实验及相关工程情况,从力学角度对水平孔中钻渣的运移机理及相关影响因素进行分析,采用牛顿力学定律对钻渣在钻井液中的运移速度进行了解析建模。     

Simulation experiment on hydrocarbon generating potential of various source rocks on the northern margin of the Qaidam Basin,Qinghai, China

The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation.     

A study on the polarimetric properties of various features using SIR-C data

Spaceborne Imaging Radar (SIR-C) data acquired over Gujarat, India in 1994 were processed and analysed using differnet techniques applicable to polarimetric SAR data such as polarization signatures, polarization index, decomposition of the signal and polarization phase difference and limited groundtruth data. It has been observed that multi-frequency polarimetric data enhances the potential of retrieving geo-physical parameters. The polarization signatures are found to vary with the nature of the target. Target decomposition of the returned signal will be useful for the classification of various features. Polarization Phase Difference (PPD) gives good information about the vegetation parameters.     

The Bayesian detection of discontinuities in a polynomial regression and its application to the cycle-slip problem

This paper deals with the problem of detecting and correcting cycle-slips in Global Navigation Satellite System (GNSS) phase data by exploiting the Bayesian theory. The method is here applied to undifferenced observations, because repairing cycle-slips already at this stage could be a useful pre-processing tool, especially for a network of permanent GNSS stations. If a dual frequency receiver is available, the cycle-slips can be easily detected by combining two phase observations or phase and range observations from a single satellite to a single receiver. These combinations, expressed in a distance unit form, are completely free from the geometry and depend only on the ionospheric effect, on the electronic biases and on the initial integer ambiguities; since these terms are expected to be smooth in time, at least in a short period, a cycle-slip in one or both the two carriers can be modelled as a discontinuity in a polynomial regression. The proposed method consists in applying the Bayesian theory to compute the marginal posterior distribution of the discontinuity epoch and to detect it as a maximum a posteriori (MAP) in a very accurate way. Concerning the cycle-slip correction, a couple of simultaneous integer slips in the two carriers is chosen by maximazing the conditional posterior distribution of the discontinuity amplitude given the detected epoch. Numerical experiments on simulated and real data show that the discontinuities with an amplitude 2 or 3 times larger than the noise standard deviation are successfully identified. This means that the Bayesian approach is able to detect and correct cycle-slips using undifferenced GNSS observations even if the slip occurs by one cycle. A comparison with the scientific software BERNESE 5.0 confirms the good performance of the proposed method, especially when data sampled at high frequency (e.g. every 1 s or every 5 s) are available.