A study on A-type granites in Suzhou,China

The Suzhou granite suite is the anorogenic product, which is located on the inactive continental margin of east China. It was emplaced about 141 Ma ago, occurring as a stock with a polygonal outline on the surface, belonging to alkali potash-feldspar granites with K₂O > Na₂O, Reit’s alkali coefficient = 0.694, SiO₂ = 74.95, and Al₂O₃/(K₂O + Na₂O)mol= 1. Besides K and Na, Li and Rb are also rather high. Highlycharged metals such as Zr, Nb, REE, Y, Sn, Th, Ga and Zn are 10, or even 50 times higher than those in the ordinary granites. Halogen elements such as F and Cl are high in abundance with F = 2700 ppm and Cl = 170 ppm on average. The abundances of deep-source elements such as Ti, Al, Ca, Mg and P are relatively low, with A1₂O₃ = 12.65% and Ca + Mg < 1%. High Ga and low Al contents are typomorphically characteristic of A type granites. Biotite in the rocks is, for the most part, annite, usually filling in quartz and feldspar crystals, indicating that the crystallization of magma proceeded under relatively anhydrous condition. More than 40 kinds of accessory minerals have been identified, of which the mantle-derived mineral chrompicotite and moissanite is of great interest. Two different intrusions, the major and supplementary intrusions, can be distinguished in the granite suite. The rock-forming temperature is estimated to be 810°C, pressure 2.5 kbars, pH 8.1,¹⁸O/¹⁶O low(δ¹⁸O_WR = 6.19‰), and_fo₂= 10⁻¹⁶. The abundances of REE are high and Eu depletion is remarkable (δEu = 0.24). A variety of mineral deposits related to the Suzhou granite suite have been recognized.     

对饱和粘性土渗透规律的新认识及其应用

通过实验，对饱和粘性土的渗透规律进行研究，得到几点新认识。利用此认识建立了饱和粘性土越流补给量的计算公式，并在实际应用中得到验证。     

Revision of the Clam Shrimp Genus Magumbonia from the Upper Jurassic of the Luanping Basin,Hebei,Northern China

The diverse clam shrimp Nestoria-Keratestheria fauna is widely distributed in the Dabeigou Formation in northern Hebei and eastern Inner Mongolia of China.Its important component genus Magumbonia from the Dabeigou Formation in the Luanping Basin,northern Hebei,China,is revised on the basis of a scanning electron microscope (SEM) examination of the type species M.jingshangensis Wang,1984,which revealed morphological features not recognized previously.These include coarse reticulation on the umbo and promi...     

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 4: Plagioclase,orthopyroxene, clinopyroxene,glass geobarometer,and application to Mt. Ruapehu,New Zealand

A new phase equilibria geobarometer determines magmatic storage and crystallization conditions, including pressure, temperature, oxygen fugacity (\({f_{{{\text{o}}_2}}}\)), and the presence of a fluid phase for glass-bearing rocks containing the assemblage plagioclase?+?pyroxene(s). This newly developed geobarometer can better constrain crystallization conditions of shallow (<?500 MPa; <~?20 km), glass-bearing andesites to dacites. The geobarometer utilizes rhyolite-MELTS to determine crystallization conditions in natural pumice and scoria samples. The validity of the geobarometer is tested by comparing it to results from experiments. Uncertainties are assessed using Monte Carlo simulations. We apply the geobarometer to the plag?+?opx?+?cpx-bearing system of Mt. Ruapehu, in the southern Taupo Volcanic Zone, New Zealand. The samples from Mt. Ruapehu are tested from ~?5 to ~?400 MPa and from super-liquidus to 90% crystalline (~ 1200 to ~ 700 °C). Mt. Ruapehu serves as a methodological testing ground for the geobarometer, and results from our geobarometer agree with recent Mt. Ruapehu studies. Results show a distribution of crystallization pressures ranging from 50 to 150 MPa (~?2.0 to 5.9 km) for different eruptions, with modes of 110 MPa (~ 4.3 km) and 130 MPa (~ 5.1 km). These are consistent with field interpretations of different eruptive styles based on juvenile clast textures and previous knowledge of the magma plumbing system. Mt. Ruapehu magmas are fluid saturated, with \({f_{{{\text{o}}_2}}}\) of ΔQFM ~ + 1 (NNO).     

An experimental study of Fe–Ni exchange between sulfide melt and olivine at upper mantle conditions: implications for mantle sulfide compositions and phase equilibria

The behavior of nickel in the Earth’s mantle is controlled by sulfide melt–olivine reaction. Prior to this study, experiments were carried out at low pressures with narrow range of Ni/Fe in sulfide melt. As the mantle becomes more reduced with depth, experiments at comparable conditions provide an assessment of the effect of pressure at low-oxygen fugacity conditions. In this study, we constrain the Fe–Ni composition of molten sulfide in the Earth’s upper mantle via sulfide melt–olivine reaction experiments at 2 GPa, 1200 and 1400 °C, with sulfide melt \(X_{{{\text{Ni}}}}^{{{\text{Sulfide}}}}=\frac{{{\text{Ni}}}}{{{\text{Ni}}+{\text{Fe}}}}\) (atomic ratio) ranging from 0 to 0.94. To verify the approach to equilibrium and to explore the effect of \({f_{{{\text{O}}_{\text{2}}}}}\) on Fe–Ni exchange between phases, four different suites of experiments were conducted, varying in their experimental geometry and initial composition. Effects of Ni secondary fluorescence on olivine analyses were corrected using the PENELOPE algorithm (Baró et al., Nucl Instrum Methods Phys Res B 100:31–46, 1995), “zero time” experiments, and measurements before and after dissolution of surrounding sulfides. Oxygen fugacities in the experiments, estimated from the measured O contents of sulfide melts and from the compositions of coexisting olivines, were 3.0?±?1.0 log units more reduced than the fayalite–magnetite-quartz (FMQ) buffer (suite 1, 2 and 3), and FMQ ??1 or more oxidized (suite 4). For the reduced (suites 1–3) experiments, Fe–Ni distribution coefficients \(K_{{\text{D}}}^{{}}=\frac{{(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}/X_{{{\text{Fe}}}}^{{{\text{sulfide}}}})}}{{(X_{{{\text{Ni}}}}^{{{\text{olivine}}}}/X_{{{\text{Fe}}}}^{{{\text{olivine}}}})}}\) are small, averaging 10.0?±?5.7, with little variation as a function of total Ni content. More oxidized experiments (suite 4) give larger values of K_D (21.1–25.2). Compared to previous determinations at 100 kPa, values of K_D from this study are chiefly lower, in large part owing to the more reduced conditions of the experiments. The observed difference does not seem attributable to differences in temperature and pressure between experimental studies. It may be related in part to the effects of metal/sulfur ratio in sulfide melt. Application of these results to the composition of molten sulfide in peridotite indicates that compositions are intermediate in composition (\(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}\)?~?0.4–0.6) in the shallow mantle at 50 km, becomes more Ni rich with depth as the O content of the melt diminishes, reaching a maximum (0.6–0.7) at depths near 80–120 km, and then becomes more Fe rich in the deeper mantle where conditions are more reduced, approaching (\(X_{{{\text{Ni}}}}^{{{\text{sulfide}}}}\)?~?0.28)?>?140 km depth. Because Ni-rich sulfide in the shallow upper mantle melts at lower temperature than more Fe-rich compositions, mantle sulfide is likely molten in much of the deep continental lithosphere, including regions of diamond formation.     

Non-coaxiality of soft clay generated by principal stress rotation under high-speed train loading

Plenty of geomechanics tests and theories have confirmed the existence of non-coaxiality while soil is subjected to principal stress rotation. This paper investigated the influence of one particular principal stress path, which is a ‘heart-shape’ stress path that is normally induced by high-speed train loading, on the non-coaxiality of reconstituted soft clay. Hollow cylinder apparatus was employed to carry out series of undrained dynamic tests. The goals of this study were to (1) reveal the essential factors of complex cyclic loading paths that influence non-coaxiality in clayey soil and (2) quantify the influence of the factors on variation in non-coaxiality under the high-speed training loading. To analyze the non-coaxiality under high-speed train loading, (a) the pure rotation stress path was utilized as comparison for underling the different influence that ‘heart-shape’ stress path has from other conventional cyclic stress paths. (b) Two variables, dynamic stress ratio and tension–compression amplitude ratio, were introduced in analyzing the evolution of the non-coaxial angle. (c) Based on the test results, equations for describing the revolution of non-coaxiality were proposed which can help to describe the variation in non-coaxial angle under complex loadings quantitatively and understand the influence of the major factors of the stress path intensively.

     

Analysis of anisotropy of magnetic susceptibility in iron-oolitic beds: a potential tool for paleocurrent identification

A combined sedimentological, shape-preferred orientation and anisotropy of magnetic susceptibility (AMS) analysis has been performed at the Arroyofrío Bed (Callovian–Oxfordian boundary level) in the locality of Moneva (Iberian Range, NE Spain). The Arroyofrío bed is a widespread iron-ooid limestone interval forming a condensed sequence. The present study has focused on the analysis of the potential presence of a preferred ooid orientation at the Arroyofrío bed. The obtained data show that ooids were originally ellipsoidal and had an imbricate disposition with respect to the bedding/lamination surface. The main ooid orientation within the bedding plane shows a NNE–SSW trend. Results of AMS analyses show a magnetic foliation parallel or slightly imbricated with respect to bedding and magnetic lineation parallel to the main ooid orientation. Magnetic mineralogy of studied samples shows that AMS is mainly controlled by magnetite with minor contributions of hematite and paramagnetic minerals (that can reach contributions of 35 %). The analyzed ooids show axial ratios between 1.4 and 2.8 (intrinsic anisotropy), while the anisotropy of their distribution shows lower anisotropies (e.g., Rs = 1.15) or very low values of the anisotropic magnetic parameters (e.g., P′ < 1.01). Sedimentary texture, matrix features, bioturbation and fossil content influenced both ooid main orientation and the magnetic fabric. Magnetic lineation and main orientation of long ooid axes are transverse to the inferred coastline in the studied area and parallel to the expected paleocurrent direction with respect to the Ejulve-Maestrazgo paleogeographic high. The direct correlation between AMS magnetic lineation and the ooid analysis permits to demonstrate that the paleocurrent imprint can be recorded by means of AMS despite the highly ferromagnetic context fabric and at coarse deposits. Obtained results support the interest and reliability of AMS to unravel paleocurrent imprints for paleogeographic reconstructions.     

Sr,Nd and O Isotopic Studies on the Genesis of the Huashan Granite Complex1

Abstract Systematical Sr, Nd and O isotopic studies were made on the Huashan granite complex in Guangxi. In combination with the studies of geological, petrological and geochemical data, it is believed that the complex consists of granites of three stages, with different geneses and different source materials. They are not the products of differentiation and evolution of one single consanguineous magma. Granites of the 1st stage are of the Indosinian syntectic type or I type, also derived from a mixed mantle-crustal source. Those of the 2nd stage are of the early Yanshanian syntectic type or I type, also derived from a mixed mantle-crustal source, and those of the 3rd stage are of the late Yanshanian transformed type or S type, derived from a crustal source.     

Mode of occurrence of Cu and Zn in till over three mineralized areas in Finland

The variation of Cu and Zn contents with grain size was studied in the size fractions: 2000-500 μm, 500-64 μm, 64-2 μm and minus 2 μm. The fixation to different minerals was investigated in the 500-64 μm and minus 64 μm fractions with microscope, microprobe, electron microscope and X-ray diffraction after heavy-liquid separation.The distribution of Cu and Zn between the four size fractions is very similar in all target areas. The contents tend to be highest in the minus 2 μm fraction, and to decrease with increasing grain size except for an increase in the coarsest material. This feature is typical in mineralized areas with till having anomalously high Cu and Zn contents.The anomalous Cu and Zn in the till of Talvivaara are mainly fixed to chalcopyrite and sphalerite, respectively, which indicates that the main part of the material originates from fresh bedrock and that postglacial alterations are slight. In the till of Outokumpu and Maaselkä sulphides are rare. We assume that in Outokumpu the reason for this is the postglacial weathering of sulphides and that in Maaselkä a great deal of till derives from highly weathered, sulphide-poor, preglacial regolith. In both target areas Cu in till seems to fix to limonite and also to clay minerals, particularly in Maaselkä. Zinc seems mainly to be hosted by limonite in Outokumpu.