Transport of dissolved methoxy-nonafluorobutane through a saturated column

Solute transport experiments were conducted in a one-dimensional saturated column using dissolved methoxy-nonafluorobutane (HFE-7100), a Novec engineered fluid developed by the 3M Corporation, as the solute. Novec engineered fluids are considered dense non-aqueous phase liquids (DNAPLs) because they are immiscible with water and have a specific gravity greater than one. The HFE-7100 fluid is safer and environmentally friendlier than common DNAPL contaminants such as tetrachloroethylene (PCE) or trichloroethylene (TCE); thus, it is an ideal substitute DNAPL for laboratory groundwater contamination research. Three sets of solute transport experiments were conducted. The first set of experiments was conducted in a glass-bead-packed column using dissolved HFE-7100 as the solute. The second set of experiments was conducted in a sand-packed column using dissolved HFE-7100 as the solute. The third set of experiments was conducted in a sand-packed column using dissolved PCE as the solute. The dissolved HFE-7100 column breakthrough concentrations were compared with dissolved PCE breakthrough concentrations. Results show that the one-dimensional solute transport equation was successful in describing the transport behavior of dissolved HFE-7100. This study demonstrates that the HFE-7100 fluid can be used as a safer substitute DNAPL for groundwater contaminant dissolution and transport research.     

Satellite-based assessment of large-scale land cover change in Asian arid regions in the period of 2001–2009

Arid regions in Asia are commonly characterized by rapidly growing populations with limited land resources and varying rainfall frequencies under climatic change. Despite being one of the most important environmental challenges in Asia, the changing aridity in this region, particularly due to large-scale land cover change, has not been well documented. In this study, we used rainfall data and a new land heterogeneity index to identify recent trend in land cover changes in the Asian arid regions. The result indicates a significant decreasing trend of barren lands and an increasing trend of vegetated lands. Although the potential land cover change is commonly believed to be strongly sensitive to rainfall change, such sensitivity has not been observed during the nine-year period (2001–2009) analyzed. Through the analyses of two separate periods (2001–2005 and 2005–2009), the sensitivity of rainfall to land cover change in arid regions is found to be dependent on the initial spatial heterogeneity of vegetated land cover. The approach used and the findings in this study represent an important step toward better understanding of large-scale land cover change in the Asian arid regions, and have the potential to predict future land cover change under various climate change scenarios.     

Comparison of the Ordovician-Carboniferous Boundary Between Korea and NE China: Implications for Correlation and Tectonic Evolution

There is a great hiatus between Ordovician and Carboniferous strata in the Northeast China and Korean Peninsula. In order to understand geology and tectonic evolution, and to find out the similarities and differences in both regions, two sections in the Western Hill near Beijing in NE China and several sections in the Korean Peninsula were selected to examine their geologic boundaries between Lower and Upper Paleozoic strata to compare their characteristic features. At four sites in the two sections in the Western Hill near Beijing were examined their contact relations. The Hui Yu section is the same horizon where one site is top of a quarry hill and the other of down hill. Mid-Carboniferous Qingshuijian Formation rests on the Ordovician Majiagou Formation. Limestone beds are more commonly intercalated with shale and sandstone at site 2 of the Hui Yu section, while at site 1, conglomerate beds are dominant. Site 1 of the Se Shu Fen section shows eroded and concealed karst topography and conglomerate beds are intercalated within shale beds. Silurian and Devonian strata are absent in these areas. In the Korean Peninsula, most O-C contacts occur between Ordovician limestone formation and Carboniferous strata, although Silurian strata occur beneath the Carboniferous strata in the Jeongseon area and Pyeongnam Basin. Most contact relations are parallel unconformity and angular unconformity is rarely seen. The O-C relations in both regions are similar to each other, and these indicate that the Korean Peninsula was located near or belonged to the Sino-Korean paraplatform during Paleozoic time.     

Finite Element Solvers for Biot’s Poroelasticity Equations in Porous Media

We study and compare five different combinations of finite element spaces for approximating the coupled flow and solid deformation system, so-called Biot’s equations. The permeability and porosity fields are heterogeneous and depend on solid displacement and fluid pressure. We provide detailed comparisons among the continuous Galerkin, discontinuous Galerkin, enriched Galerkin, and two types of mixed finite element methods. Several advantages and disadvantages for each of the above techniques are investigated by comparing local mass conservation properties, the accuracy of the flux approximation, number of degrees of freedom (DOF), and wall and CPU times. Three-field formulation methods with fluid velocity as an additional primary variable generally require a larger number of DOF, longer wall and CPU times, and a greater number of iterations in the linear solver in order to converge. The two-field formulation, a combination of continuous and enriched Galerkin function space, requires the fewest DOF among the methods that conserve local mass. Moreover, our results illustrate that three out of the five methods conserve local mass and produce similar flux approximations when conductivity alteration is included. These comparisons of the key performance indicators of different combinations of finite element methods can be utilized to choose the preferred method based on the required accuracy and the available computational resources.

     

Investigation of CO2 behavior and study on design of optimal injection into Gorae-V aquifer

This study presents the Bottom-hole pressure (BHP) behavior with different wettabilities and the optimal design scheme to effectively inject CO₂ into the Gorae-V aquifer. As a result, the injection rate and injectivity were increased as the wettability condition became more water-wet. However, the more wettability condition becomes water-wet, the more the ultimate CO₂ injection volume decreases. When the injectivity was 346 ton/day/Mpa at the Gorae-V aquifer, the aquifer can sustain CO₂ injection at a rate of 2,425 tons per day over this time period. A design for a complete CCS system was developed based on the existing off-shore pipeline in combination with new on-shore CO₂ transport infrastructure, and a pressure of 12.8 MPa is required at the CO₂ source to maintain this injection rate.     

Spatio-temporal dynamics of heavy metals in sediments of the river estuarine system: Mahanadi basin (India)

Dynamics of heavy metals in the surface sediments of Mahanadi river estuarine system were studied for three different seasons. This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial pattern of heavy metals supported by enrichment ratio data, suggests their anthropogenic sources possibly from various industrial wastes and municipal wastes as well as agricultural runoff. The metal concentrations in estuarine sediments are relatively higher than in the river due to adsorption/accumulation of metals on sediments during saline mixing, while there is a decreasing trend of heavy metal concentrations towards the marine side. The temporal variations for metals, such as Fe, Mn, Zn, Ni and Pb exhibit higher values during monsoon season, which are related to agricultural runoff. Higher elemental concentrations are observed during pre-monsoon season for these above metals (except Ni) at the polluted stations and for metals, such as Cr, Co and Cd at all sites, which demonstrate the intensity of anthropogenic contribution. R-mode factor analysis reveals that “Fe–Mn oxy hydroxide”, “organic matter”, “CaCO₃”, and “textural variables” factors are the major controlling geochemical factors for the enrichment of heavy metals in river estuarine sediment and their seasonal variations, though their intensities were different for different seasons. The relationships among the stations are highlighted by cluster analysis, represented in dendrograms to categorize different contributing sites for the enrichment of heavy metals in the river estuarine system.     

He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.     

Spatiotemporal Patterns of Subtidal Benthic Microalgal Biomass and Community Composition in Galveston Bay,Texas, USA

Many Gulf of Mexico estuaries have low ratios of water volume to bottom surface area, and benthic processes in these systems likely have a major influence on system structure and function. The purpose of this study was to determine the spatiotemporal distribution of biomass and community composition of subtidal benthic microalgal (BMA) communities in Galveston Bay, TX, USA, compare BMA community composition and biomass to phytoplankton in overlying waters, and estimate the potential contribution of BMA to the trophodynamics in this shallow, turbid, subtropical estuary. The estimates of BMA biomass (mean = 4.21 mg Chl a m⁻²) for Galveston Bay were within the range of the reported values for similar Gulf of Mexico estuaries. BMA biomass in the central part of the bay was essentially homogeneous, whereas biomass at the seaward and upper bay ends of the transect were significantly lower. Peridinin, fucoxanthin, and alloxanthin were the three carotenoids with the highest concentrations, with fucoxanthin having the highest mean concentration (1.82 mg m⁻²). The seaward and landward ends of the transect differed from the central region of the bay with respect to the relative abundances of chlorophytes, cyanobacteria, and photosynthetic bacteria. Benthic microalgal community composition also showed a gradual shift over time due to changes in the relative abundances of photosynthetic bacteria, cryptophytes, dinoflagellates, and cyanobacteria. Major changes in community composition occurred in the spring months (March to April). On an areal basis, BMA biomass in Galveston Bay occurred at minor concentrations (16.5%) relative to phytoplankton. Furthermore, the concentrations of carotenoid pigments for phytoplankton and BMA (fucoxanthin, alloxanthin, and zeaxanthin) were correlated (r = 0.48 to 0.61), suggesting a close linkage between microalgae in the water column and sediments. The contribution of BMA to the primary productivity of the deeper waters (>2 m) of Galveston Bay is probably very small in comparison to shallower waters along the bay margins. The significant similarities in the community composition of phytoplankton and BMA illustrate the potential importance of deposition and resuspension processes in this turbid, shallow estuary.     

Structural relaxation in the MnCO3–CaCO3 solid solution: a Mn K-edge EXAFS study

Mn K-edge EXAFS spectroscopy of solid-solution samples encompassing the complete MnCO₃–CaCO₃ series shows that first-shell Mn–O distances deviate little from the 2.19-Å distance observed in pure MnCO₃. Very slight lengthening is observed only in the limiting case of dilute Mn(II) calcite solid solutions, where the Mn–O distance is 2.21 Å. The observed nearly complete structural relaxation and the composition independence of the Mn–O distance are consistent with the Pauling model behavior of solid solutions, and agree with previous studies showing a high degree of relaxation around hetero-sized substituents in the calcite structure. Strain occurs through bond bending, which is facilitated by the exclusively corner-sharing topology of calcite. Observed distances from Mn to more distant neighbors show significant variation across the solid-solution series that resembles Vegard's law-type behavior but reflects averaging. The high degree of relaxation suggests modest enthalpies of mixing in the solution, consistent with calorimetric studies.