包气带土壤组成对三氯乙烯的吸附影响研究

有机质和矿物质是包气带土壤中的主要吸附介质,其吸附特性直接影响有机污染物在环境中的迁移、转化等过程。分别采用分析纯石英砂和典型粘土矿物高岭石模拟土壤的原生矿物和粘土矿物,利用批实验的方法研究土壤中各组成部分对三氯乙烯(TCE)的吸附行为。土壤有机质的吸附行为通过全土样和矿物质的对比得出。结果表明,粘土矿物是吸附氯代烃的主要矿物质,原生矿物对氯代烃的吸附量很小;土壤有机质含量和土壤吸附量之间有很好的正相关性;土壤有机碳含量与土壤粘土矿物含量的比值是影响吸附行为的另一重要因素,比值越小,Koc值越大,土壤对TCE的亲和力就越强。由于自然界中的土壤有机质大都与矿物质形成有机质-粘土矿物结合体,据此推测有机质-矿物质结合体会影响有机质的组成和形态,从而对其吸附行为有重要作用。     

高应变法在判定大直径灌注桩缺陷中的应用

测试数据准确可靠的高应变法检测,能够定量分析基桩缺陷,准确判定缺陷位置。通过工程桩的低应变法和高应变法对桩身完整性判定分析的工程实例,结合钻芯法验证,总结高应变法在不同情况下对桩身完整性的评定。     

基于统计学方法福建滑坡灾害与其影响因子的相关性分析

滑坡为福建省主要地质灾害之一,受自然地理、地质条件的制约,以及人类工程活动及降雨的诱发影响,发生频率较高。应用统计学方法,对近几年来福建省所发生滑坡的地质灾害点进行相关性研究,提出了福建省内山体滑坡主要受地形、地质、气象及人类工程活动因素的综合影响。     

晋豫间黄河峡谷黄土状沙丘的光释光年代学探讨

通过对风陵渡-三门峡晋豫间黄河峡谷的地貌考察和1:50000 地形图(1970年)的分析,初步查明了黄河南岸黄土状沙丘的分布特征.选取河南省灵宝市豫灵镇阌底约75m高的黄土状沙丘剖面进行了观测和取样.根据该剖面的粒度分布特点,选取中颗粒(40～90μm)石英进行了光释光(OSL)测年研究.采用简化SAR法测量样品的等效剂量(De),其中5个样品与SAR法测量的De值对比,结果在误差范围内一致.对阌底剖面自上而下19个样品运用简化SAR法做了OSL年龄测定,其中8个还进行了4～11μm细颗粒石英简易多测片再生法(SMAR)OSL测年,两个粒级石英的OSL年龄测定值在测量误差范围内一致.初步结果表明,晋豫间黄河峡谷阌底黄土状沙丘发育不晚于距今约5.5万年前,并延续到全新世初期,风沙堆积速率在3.2万年前后曾出现显著变化.     

Geological Evolution of Longhushan World Geopark in Relation to Global Tectonics

The South China fold belt has experienced a complex series of tectonic events that span 1.0 billion years of earth history. Longhushan (龙虎山) World Geopark is located on the Proterozoic suture between the Yangtze craton and Cathyasia block and highlights the long history of this belt. Collision of the Cathyasia and Yangtze cratons 1.0 billion years ago was associated with the formation of the Rodinian supercontinent where most of the planet's landmasses were amalgamated into one block. Jurassic through Early...     

基于贝叶斯网络的地下水环境系统决策管理研究

应用贝叶斯网络解决地下水环境管理中具有不确定性的多目标决策问题,通过对决策变量氮肥施用量以及灌溉模式的调控,减少水中的硝酸盐含量,达到既能有效改善水环境又不至使农民经济利益受到损害的目标。通过分析具体的地下水环境管理系统中变量间的相互关系,构建描述变量间不确定性关系的贝叶斯网络模型,其中包括表示其依赖关系的有向无环图和表示其具体概率依赖程度的条件概率表。并在多个水环境管理目标均达到最优的前提下进行概率推理,得到决策变量氮肥施用量以及灌溉模式取不同值时目标变量的概率分布情况。最终确定出能使所有目标均达到最优的合理的水环境管理决策:(1)使用喷灌,将氮肥施用量控制在0.01~0.03 kg/m2;(2)使用漫灌,将氮肥施用量控制在0.01~0.02 kg/m2。     

新疆东准双泉地区与韧-脆性剪切带有关的金矿成矿

[摘要]区域成矿背景分析表明,东准噶尔卡拉麦里地区韧-脆性剪切带形成于陆-陆碰撞体制, 在330 ~265Ma 期间,受挤压伸展体制转换影响,先后经历了韧、脆性构造变形。对与韧-脆性剪切带有 关的金矿石英流体包裹体研究发现,包裹体以气液相为主,均一温度集中在160 ~ 240益,成矿流体盐度 为3. 55 ~4. 5wt%NaCl。成矿流体的氢、氧同位素组成表明成矿流体的水为变质成因水。金属硫化物硫 同位素啄34 S 值为3. 54 ~10. 68译,显然属于混染硫。黄铁矿包裹体氦氩同位素3 He/ 4 He 值为0. 18 ~2. 18 Ra,属幔壳混源。成矿年代学研究表明,双泉金矿成矿时代及控矿构造脆性变形时间为(269依9) Ma ~ (260依4)Ma,金初始富集时间在310Ma 前后,并得到含矿花岗斑岩U-Pb 同位素年龄的支持,该事件在 东准地区均有同位素年龄记录,是区域性的构造岩浆成矿流体热事件。上述资料表明,金矿成矿过程、 成矿流体性质等在时间、空间上严格受韧-脆性剪切构造变形带控制。     

A parallel global-implicit 2-D solver for reactive transport problems in porous media based on a reduction scheme and its application to the MoMaS benchmark problem

In this article, an approach for the efficient numerical solution of multi-species reactive transport problems in porous media is described. The objective of this approach is to reformulate the given system of partial and ordinary differential equations (PDEs, ODEs) and algebraic equations (AEs), describing local equilibrium, in such a way that the couplings and nonlinearities are concentrated in a rather small number of equations, leading to the decoupling of some linear partial differential equations from the nonlinear system. Thus, the system is handled in the spirit of a global implicit approach (one step method) avoiding operator splitting techniques, solved by Newton’s method as the basic algorithmic ingredient. The reduction of the problem size helps to limit the large computational costs of numerical simulations of such problems. If the model contains equilibrium precipitation-dissolution reactions of minerals, then these are considered as complementarity conditions and rewritten as semismooth equations, and the whole nonlinear system is solved by the semismooth Newton method.     

Integrated stratigraphy and 40Ar/39Ar chronology of the early to middle Miocene Upper Freshwater Molasse in western Bavaria (Germany)

A detailed integrated stratigraphic study (biostratigraphy and magnetostratigraphy) was carried out on five sections from the western part of the Bavarian Upper Freshwater Molasse of the North Alpine Foreland Basin (NAFB), greatly improving the chronostratigraphy of these sediments. The sections belong to the lithostratigraphic units Limnische Untere Serie (UL) and Fluviatile Untere Serie (UF) and contain 19 (mostly new) small-mammal bearing levels, significantly refining the local biostratigraphy. Radiometric ages obtained from glass shards from tuff horizons are used together with the biostratigraphic information for constructing and confirming the magnetostratigraphic correlation of the studied sections to the Astronomical Tuned Time Scale (ANTS04; Lourens et al. in Geologic Time Scale 2004, Cambridge University Press, 2004). This correlation implies that the UL lithostratigraphic unit corresponds to the latest Ottnangian and the Early Karpatian, whereas the UF corresponds to the Karpatian and the Early Badenian. This indicates that the Brackish- to Freshwater Molasse transition already occurred during the late Ottnangian. The pre-Riesian hiatus occurred in the latest Karpatian and lower Early Badenian in Eastern Bavaria and Bohemia and in the Late Karpatian and earliest Badenian in Western Bavaria. The geochemical and Ar–Ar data of volcanic ashes suggest that highly evolved silicic magmas from a single volcano or volcanic center, characterized by a uniform Nd isotopic composition, erupted repetitively over the course of at least 1.6 Myr. Three phases of eruptive activity were identified at 16.1 ± 0.2 Ma (Zahling-2), 15.6 ± 0.4 Ma (Krumbad), and 14.5 ± 0.2 Ma (Heilsberg, Hegau). The correlation of the local biostratigraphic zonation to the ANTS04 enables further the characterization of both the Ottnangian–Karpatian and Karpatian–Badenian boundaries in the NAFB by small-mammal biostratigraphy. According to these results the Ottnangian–Karpatian boundary is contemporaneous with the first appearance datum of Megacricetodon bavaricus (in the size of the type population) and the first common occurrence of Keramidomys thaleri, whereas Ligerimys florancei, Melissiodon dominans and Prodeinotherium aff. bavaricum have been already disappeared during the late Ottnangian. The Karpatian–Badenian boundary is characterized by a significant size increase of the large Megacricetodon lineage and possibly a (re-)immigration of Prodeinotherium bavaricum.