钨—水杨基荧光酮络合物的极谱催化波研究

在HCl、KCl介质中,W(Ⅵ)-水杨基荧光酮络合物有一灵敏的催化波,峰电位为-1.22V(υs.SCE),W(Ⅵ)浓度在4.4×10~(-11)—4.4 ×10~(-8)mol/L范围内与峰电流呈线性关系,检测限2.2×10~(-11)mol/L。实验表明该波为氢催化波,可用于痕量或超痕量W的测定。     

Two types of summertime heating over Asian large-scale orography and excitation of potential-vorticity forcing II. Sensible heating over Tibetan-Iranian Plateau

Based on analysis and simulation, the interaction of thermal forcing between the Tibetan Plateau (TP) and Iranian Plateau (IP) in summer is investigated. Associated influences on water vapor transport in the Asian subtropical monsoon region and the formation of a cold center in the lower stratosphere over Eurasia are also investigated. Results show that surface sensible heating (SH) over the two plateaus not only have mutual influences but also feedback to each other. SH over the IP can reduce the SH and increase the LH over the TP, whereas the SH over the TP can increase surface heating over the IP, thereby reaching quasi-equilibrium among the SH and LH over the TP, IP SH and atmosphere vertical motion. Therefore, the so-called Tibetan-Iranian Plateau coupling system (TIPS) is constructed, which influences atmosphere circulation. In the TIPS system, interaction between surface SH and LH over the TP plays a leading role. SH of the IP and TP influences on other regions not only have superimposed effects but also mutually offset. Accounting for contributions to the convergence of water vapor transport in the Asian subtropical monsoon region, TP SH contributes more than twice that of the IP. The combined influence of SH over TP and IP represents the major contribution to the convergence of water vapor transport in that region. In addition, the heating effect of TIPS increases the upper tropospheric temperature maximum and lifts the tropopause, cooling the lower stratosphere. Combined with large-scale thermal forcing of the Eurasian continent, the TIPS produces a strong anticyclonic circulation and the South Asian High that warms the upper troposphere and cools the lower stratosphere, thereby affecting regional and global weather and climate.     

Three-dimensional sedimentary architecture of Quaternary sand and gravel resources: a case study of economic sedimentology (SW Germany)

Quaternary sands and gravels form important, yet often highly heterogeneous economic deposits. Detailed 3-D analysis of the sedimentary structure and stratigraphy of these deposits allows for an accurate estimation of exploitable material. This paper presents a case study in SW Germany reconstructing the 3-D distribution of glacial sediments based on a high-resolution, process-orientated sedimentary facies classification and lithostratigraphy integrated within the geo-modelling package gOcad. Situated along the maximal ice-extent of the Rhine glacier during the last glaciation, the study area is characterised by a morphologically prominent terminal moraine and its associated sandur, which form the stratigraphically youngest sediments of a glacial basin, partially exposed in two gravel pits. These outcrops helped to reconstruct the complex sedimentary architecture of the northern part of the glacial basin. The regional analysis is based on core data, as well as geoelectric and geomagnetic surveys. All data were integrated into km-scale, high-resolution geological 3-D models, depicting the large-scale dynamics of multiple glacier advances and retreats during the Early to Late Pleistocene. These models allow quantifying the thickness and volume distribution of exploitable sandy gravel and help to evaluate the occurrence of non-exploitable interbedded diamicton horizons. The high quality and quantity of gravels particularly north of the terminal moraine classifies the investigated area as very prospective for raw materials exploitation in the future.     

Stable isotopes and trace elements in modern ostracod shells: implications for reconstructing past environments on the Tibetan Plateau,China

Stable isotopes and trace elements in ostracod shells have been used widely in paleolimnological investigations of past lake hydrochemistry and climate because they provide insights into past water balance and solute evolution of lakes. Regional differences in lake characteristics and species-specific element fractionation, however, do not permit generalization of results from other regions or ostracod species to the southern Tibetan Plateau, in part because most common taxa from the southern Tibetan Plateau are endemic to the area. This study evaluated relations between present-day environmental conditions and the geochemical composition of modern ostracod shells from the southern Tibetan Plateau, to assess the suitability of using shell chemistry to infer hydrological conditions. We studied nine lakes and their catchments, located along a west–east transect in the south-central part of the Tibetan Plateau. Stable oxygen and carbon isotope values and trace element concentrations in recent shells from the four most abundant ostracod species (Leucocytherella sinensis, ?Leucocythere dorsotuberosa, Limnocythere inopinata, Tonnacypris gyirongensis) were measured, together with hydrochemical properties of host waters at the time of sampling. Results revealed significant between-species differences in stable isotope fractionation and trace element incorporation into shell calcite. Stable oxygen and carbon isotope values of ostracod shells were correlated significantly with the stable isotope composition of the respective water body \( \left( {\updelta^{18} {\text{O}}_{{{\text{H}}_{ 2} {\text{O}}}} \,{\text{and }}\updelta^{13} {\text{C}}_{{{\text{H}}_{ 2} {\text{O}}}} } \right) \), reflecting salinity and productivity, respectively. Offsets between δ¹⁸O_shell and δ¹³C_shell and inorganic calcite, the latter representing isotopic equilibrium, suggest shell formation of T. gyirongensis during spring melt. L. sinensis reproduces throughout the monsoon season until September and shows several consecutive generations, and L. inopinata molts to the adult stage after the monsoon season in August/September. The influence of pore water δ¹³C was displayed by L. inopinata, suggesting shell calcification within the sediment. Mg/Ca_shell is primarily influenced by water Mg/Ca ratios and salinity and confirms the use of this shell ratio as a proxy for precipitation-evaporation balance and lake level. In addition, Sr/Ca and Ba/Ca can be used to infer changes in salinity, at least in closed-basin lakes with calcite saturation. Observed effects of water Sr/Ca and salinity on Sr/Ca incorporation are biased by the presence of aragonite precipitation in the lakes, which removes bioavailable Sr from the host water, resulting in low Sr/Ca_shell values. Changes in carbonate mineralogy affect the bioavailability of trace elements, a process that should be considered in paleoclimate reconstructions. Oxygen isotopes and Mg/Ca_shell ratios were unaffected by water temperature. Positive correlations among Fe/Ca, Mn/Ca and U/Ca in ostracod shells, and their negative correlation with δ¹³C, which reflects organic matter decay, show the potential to infer changes in redox conditions that can be used to reconstruct past oxygen supply to bottom waters and thus past water-circulation changes within lakes. The intensity of microbial activity, associated with organic matter decomposition, can be inferred from U/Ca ratios in ostracod shells. These findings highlight the value of fossil ostracod records in lake deposits for inferring paleoenvironmental conditions on the southern Tibetan Plateau.     

Geochemical study on oil-cracked gases and kerogen-cracked gases (II)—Discrimination methods between oil-cracked gases and kerogen-cracked gases

In the processes of discrimination between oil-cracked gases and kerogen-cracked gases, Behar and Pinzgofer et al.’s results were adopted in the former researches, in which the ratio of C₂/C₃ is basically a constant while the ratio of C₁/C₂ gradually increases in the course of primary cracking of kerogen. Otherwise in the course of secondary cracking of oil, the ratio of C₂/C₃ increases rapidly while C₁/C₂ keeps relatively stable. Our study on analogue experiment shows that, whether it is oil or kerogen, in its process of gas generating by cracking, the ratios of C₂/C₃, C₁/C₂ or C₁/C₃ will all be increased with the growth of thermal conditions. In comparison, the ratio of C₂/C₃, which is affected by genetic type to some comparatively less extent, mainly responds to the maturity of gases, while the value of C₂/C₃ is about 2, and that of C₂/iC₄ is about 10, and the corresponding value of R _o is about 1.5%–1.6%. The influence of gas source on C₂/C₃ is less than that of gas maturity, otherwise C₁/C₂ (or C₁/C₃) is obviously affected by cracking matrices. The ratios of C₁/C₂, C₁/C₃ of oil-cracked gases are less than that of kerogen-cracked gases, under the condition that the ratios of C₂/C₃ are similar in value, so are the value of dryness indexes. There exists wide diffidence between this view and the former discrimination method in theory. The analysis of the spot sample indicates that we can apply the above basic view to dealing efficiently with the problem of the discrimination between oil-cracked gas and kerogen-cracked gas.

     

Seasonal variations of stable isotope in precipitation and moisture transport at Yushu,eastern Tibetan Plateau

Precipitation δ 18O at Yushu, eastern Tibetan Plateau, shows strong fluctuation and lack of clear seasonality. The seasonal pattern of precipitation stable isotope at Yushu is apparently different from either that of the southwest monsoon region to the south or that of the inland region to the north. This different seasonal pattern probably reflects the shift of different moisture sources. In this paper, we present the spatial comparison of the seasonal patterns of precipitation δ 18O, and calculate the moisture transport flux by using the NCAR/NCEP reanalysis data. This allows us to discuss the relation between moisture transport flux and precipitation δ 18O. This study shows that both the southwest monsoon from south and inland air mass transport from north affected the seasonal precipitation δ 18O at Yushu, eastern Tibetan Plateau. Southwest monsoon brings the main part of the moisture, but southwest transport flux is weaker than in the southern part of the Tibetan Plateau. However, contribution of the inland moisture from north or local evaporation moisture is enhanced. The combined effect is the strong fluctuation of summer precipitation δ 18O at Yushu and comparatively poor seasonality.     

Effects of historical and projected land use/cover change on runoff and sediment yield in the Netravati river basin,Western Ghats,India

In this study, the effects of changes in historical and projected land use land cover (LULC) on monthly streamflow and sediment yield for the Netravati river basin in the Western Ghats of India are explored using land use maps from six time periods (1972, 1979, 1991, 2000, 2012, and 2030) and the soil and water assessment tool (SWAT). The LULC for 2030 is projected using the land change modeller with the assumption of normal growth. The sensitivity analysis, model calibration, and validation indicated that the SWAT model could reasonably simulate streamflow and sediment yield in the river basin. The results showed that the spatial extent of the LULC classes of urban (1.80–9.96%), agriculture (31.38–55.75%), and water bodies (1.48–2.66%) increased, whereas that of forest (53.04–27.03%), grassland (11.17–4.41%), and bare land (1.09–0.16%) decreased from 1972 to 2030. The streamflow increased steadily (7.88%) with changes in LULC, whereas the average annual sediment yield decreased (0.028%) between 1972 and 1991 and increased later (0.029%) until 2012. However, it may increase by 0.43% from 2012 to 2030. The results indicate that LULC changes in urbanization and agricultural intensification have contributed to the increase in runoff, amounting to 428.65 and 58.67 mm, respectively, and sediment yield, amounting to 348 and 43 ton/km², respectively, in the catchment area from 1972 to 2030. The proposed methodology can be applied to other river basins for which temporal digital LULC maps are available for better water resource management plans.     

The Holocene–Anthropocene transition in lakes of western Spitsbergen,Svalbard (Norwegian High Arctic): climate change and nitrogen deposition

Lake sediments from four small lakes on western Spitsbergen (Svalbard Archipelago, Norwegian High Arctic) preserve biostratigraphic and isotopic evidence for a complex suite of twentieth century environmental changes. At Lake Skardtjørna and Lake Tjørnskardet on Nordenskiöldkysten, there is a marked diatom floristic change coupled to increased diatom concentrations beginning around 1920. At Lake Istjørna and Lake Istjørnelva, 25 km southwest of Longyearbyen, both diatom total valve and chrysophyte stomatocyst concentrations have increased dramatically since the beginning of the 1900s. The early twentieth century changes are probably related to climate warming after the Little Ice Age. However, the most pronounced changes in diatom assemblages seem to have occurred in the last few decades. At the same time, nitrogen stable isotopes in sediment organic matter in two of the lakes became progressively depleted by ~2‰, which is consistent with diffuse atmospheric inputs from anthropogenic sources and attendant fertilization. These data suggest that climate change and nitrogen deposition may be acting together in driving these lakes towards new ecological states that are unique in the context of the Holocene.     

基于网络团购的虚拟旅游流空间差异及动力机制研究

以旅游产品网络团购为研究视角,以中国26个旅游地旅游产品网络团购虚拟旅游流为研究数据,通过空间分析方法,研究虚拟旅游流的空间分布差异及形成动力机制.网络团购虚拟旅游流整体上表现出微弱离散分布特征,局部表现出一定的聚集性,总的来说虚拟客流集中于南方沿海与中部旅游资源丰富省域,中偏西部、华北及东北地区团购虚拟旅游流量较小;团购虚拟旅游流的空间分布是内外部驱动力及环境驱动力共同作用的结果,其中外部驱动力包括产品团购价格、产品类型、网络营销空间结构3个主要动力因素,相关分析表明团购价格是最主要的外部驱动因素,其次为产品类型,最后为网络营销空间结构;以团购虚拟旅游流为研究视角具有一定的新颖性,弥补了旅游流在虚拟空间研究薄弱的缺陷.虚拟旅游流流向能够在一定程度上反映现实旅游流,甚至导引现实旅游流,虚拟旅游流的研究为景区人流管理、景区容量管理提供预知警告.