The chemical changes of DOM from black waters to coastal marine waters by HPLC combined with ultrahigh resolution mass spectrometry

How dissolved organic matter (DOM) undergoes chemical changes during its transit from river to ocean remains a challenge due to its complex structure. In this study, DOM along a river transect from black waters to marine waters is characterized using an offline combination of reversed-phase high performance liquid chromatography (RP-HPLC) coupled to electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS), as well as tandem ESI-FTICR-MS. In addition, a water extract from degraded wood that mainly consists of lignins is used for comparison to the DOM from this transect. The HPLC chromatograms of all DOM samples and the wood extract show two major well-separated components; one is hydrophilic and the other is hydrophobic, based on their elution order from the C₁₈ column. From the FTICR-MS analysis of the HPLC fractions, the hydrophilic components mainly contain low molecular weight compounds (less than 400 Da), while the hydrophobic fractions contain the vast majority of compounds of the bulk C₁₈ extracted DOM. The wood extract and the DOM samples from the transect of black waters to coastal marine waters show strikingly similar HPLC chromatograms, and the FTICR-MS analysis further indicates that a large fraction of molecular formulas from these samples are the same, existing as lignin-like compounds. Tandem mass spectrometry experiments show that several representative molecules from the lignin-like compounds have similar functional group losses and fragmentation patterns, consistent with modified lignin structural entities in the wood extract and these DOM samples. Taken together, these data suggest that lignin-derived compounds may survive the transit from the river to the coastal ocean and can accumulate there because of their refractory nature.     

基于高空间分辨率的红树林卫星遥感监测技术进展

卫星遥感技术是红树林生态系统监测的重要手段。文章系统地总结了红树林的光谱特征,给出了目前应用于红树林生态监测的高空间分辨率卫星包括IRS-P6、SPOT-5、IKONOS、OrbView-3、QuickBird的主要技术参数以及它们在红树林遥感监测中的应用程度,叙述了目视解译法、波段组合法、图像分类法、专家分类法、模糊分类法和面向对象分类法等遥感监测技术方法在红树林的生态参数包括类外区分和类内区分、生物量和健康状况等的遥感提取的应用和精度对比情况。另外,对应用高分辨率卫星遥感资料监测红树林的技术发展趋势进行了讨论。     

Predicting size effect on diffusion-limited current density of oxygen reduction by copper wire

The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to satisfy application in a marine setting, an empirical equation correlating oxygen diffusion-limited current density to copper wire radius is proposed by fitting experimental data.     

近6 ka以来科尔沁沙地东部气候变化记录

 根据科尔沁沙地东部TL剖面磁化率、有机质、化学元素等气候代用指标的变化特征和14C测年结果,分析和讨论了科尔沁沙地6 ka BP以来的气候变化过程。实验数据显示,高频磁化率、低频磁化率、有机质、Al2O3含量变化趋势基本一致,且峰值段对应古土壤层,谷值段对应风成砂层。依据气候代用指标的变化将6 ka BP以来科尔沁沙地气候变化分为3个阶段：Ⅰ.6.0～4.2 ka BP,气候暖湿,夏季风逐渐增强,并占主导,冬季风较弱,与全新世大暖期对应,但存在百年尺度的气候波动,其中：6.0～5.6 ka BP,5.6～5.4 ka BP,4.9～4.2 ka BP气候暖湿;5.6～5.5 ka BP,5.4～4.9 ka BP气候相对冷干。Ⅱ.4.2～1.3 ka BP,气候相对暖湿,与上一阶段相比夏季风有所减弱,但仍强于冬季风,其间也存在次一级波动,3.7～3.6 ka BP,3.4～1.3 ka BP,气候相对暖湿,4.2～3.7 ka BP,3.6～3.4 ka BP气候相对干冷。Ⅲ.1.3～0.65 ka BP以来,气候波动频繁,后期有向暖湿发展的趋势。总体而言,区域气候变化与全球具有较好的一致性。     

Re–Os molybdenite ages and zircon Hf isotopes of the Gangjiang porphyry Cu–Mo deposit in the Tibetan Orogen

The Miocene porphyry Cu–(Mo) deposits in the Gangdese orogenic belt in southern Tibet were formed in a post-subduction collisional setting. They are closely related to the Miocene adakite-like porphyries which were probably derived from a thickened basaltic lower crust. Furthermore, mantle components have been considered to have played a crucial role in formation of these porphyry deposits (Hou et al. Ore Geol Rev 36: 25–51, 2009; Miner Deposita doi:10.1007/s00126-012-0415-6, 2012). In this study, we present zircon Hf isotopes and molybdenite Re–Os ages on the newly discovered Gangjiang porphyry Cu–Mo deposit in southern Tibet to constrain the magma source of the intrusions and the timing of mineralization. The Gangjiang porphyry Cu–Mo deposit is located in the Nimu ore field in the central Gangdese porphyry deposits belt, southern Tibet. The copper and molybdenum mineralization occur mainly as disseminations and veins in the overlapped part of the potassic and phyllic alteration zones, and are predominantly hosted in the quartz monzonite stock and in contact with the rhyodacite porphyry stock. SIMS zircon U–Pb dating of the pre-mineral quartz monzonite stock and late intra-mineral rhyodacite porphyry yielded ages of 14.73?±?0.13 Ma (2σ) and 12.01?±?0.29 Ma (2σ), respectively. These results indicate that the magmatism could have lasted as long as about 2.7 Ma for the Gangjiang deposit. The newly obtained Re–Os model ages vary from 12.51?±?0.19 Ma (2σ) to 12.85?±?0.18 Ma (2σ) for four molybdenite samples. These Re–Os ages are roughly coincident with the rhyodacite porphyry U–Pb zircon age, and indicate a relatively short-lived episode of ore deposition (ca. 0.3 Ma). In situ Hf isotopic analyses on zircons by using LA-MC-ICP-MS indicate that the ε _Hf(t) values of zircons from a quartz monzonite sample vary from +2.25 to +4.57 with an average of +3.33, while zircons from a rhyodacite porphyry sample vary from +5.53 to +7.81 with an average of +6.64. The Hf data indicate that mantle components could be partly involved in the deposit formation, and that mantle contributions might have increased over time from ca. 14.7 to 12.0 Ma. Combined with previous works, it is proposed that the Gangjiang deposit could have resulted from the convective thinning of the lithospheric root, and the input of upper mantle components into the magma could have played a key role in the formation of the porphyry deposits in the Miocene Gangdese porphyry copper belt in the Tibetan Orogen.     

阿尔金—祁连—昆仑造山带早古生代构造格架及结晶岩年代学研究进展

阿尔金—祁连—昆仑(阿祁昆)造山带早古生代加里东期的构造事件一直是国内外研究的热点,近年来发表了大量的研究成果。本文着重调研了各造山带内构造混杂带的重要组成部分——蛇绿岩、岩浆岩和高压—超高压变质岩的地球化学特征,尤其是同位素年代学资料。蛇绿岩的地球化学特征表明阿尔金—祁连—昆仑地区早古生代的蛇绿岩有MORB和OIB两种类型,其产出于成熟的洋盆、小洋盆或是与消减带有关的弧前或弧后盆地,还有很大的争议。根据大量的同位素年代学资料,阿尔金—祁连—昆仑地区洋盆在晚新元古代开启,寒武纪发育成熟,于中—晚奥陶世开始发生俯冲消减作用,晚志留世—早泥盆世进入碰撞后伸展阶段。再者,通过同位素年代学数据对比,证明北阿尔金与北祁连、南阿尔金与柴达木北缘、西昆仑与东昆仑在早古生代分别为同一条构造带,于新生代期间被活动的阿尔金左行走滑断裂错开了400多千米。     

印度与欧亚板块碰撞以来东喜马拉雅构造结的演化

在野外填图,构造观察及前人研究的基础上,本文识别并描述了东喜马拉雅构造结中的推覆断裂、正断裂及走滑断裂、背斜(形)和向斜(形)等构造类型,讨论了这些构造位置及与印度板块挤入,印支地块旋转的关系,还探讨了东喜马拉雅构造结对印度板块持续向北推挤下的特殊应变调节方式。在印度大陆部分,东喜马拉雅构造结由3个向外逐渐变新的构造结组成,即北东向的南迦巴瓦峰复式背斜、北西向的桑复式向斜及北东向的阿萨母复式向斜。上述3个构造结是协调印度板块的挤入、喜马拉雅弧的扩展及印支地块的旋转的构造。在欧亚大陆内部的冈底斯岛弧,在派区及阿尼桥走滑断裂协调下,高喜马拉雅结晶岩的基底挤入冈底斯岛弧内部,在大拐弯顶端形成向上的挤出构造。在南迦巴瓦峰构造结的北西侧,由于掀斜式抬升及重力滑动,使得冈底斯盖层与结晶基底脱耦,上盘盖层沿东久向北西方向滑动。在南迦巴瓦峰构造结北东侧,由于印支地块的挤出和旋转,形成一系列的北西向走滑断裂,如实皆断裂、嘉黎-高黎贡断裂、澜沧江断裂及红河断裂等。     

喜马拉雅中东部镜像均衡重力异常的形成研究

青藏高原南缘处于重力不均衡状态,由北向南可依次分为高原近重力均衡区、喜马拉雅山正均衡异常区和山前盆地负均衡异常区,正、负异常呈现壮观的镜像分布。本文选取喜马拉雅中东部的均衡重力异常数据,结合地貌高程、地壳厚度、降雨量、冰川及山前沉积等的分布状况,探讨地貌分异与均衡重力异常分布的相互关系。由上述资料获得3条跨越喜马拉雅山的综合剖面,结果显示喜马拉雅中东部正均衡重力异常的分布与冰川、河流等代表的地表剥蚀作用存在明显的空间耦合关系,而与降雨量无直接联系,山前盆地负均衡重力异常与沉积厚度的分布也存在很好的耦合。利用数值模型计算得到了喜马拉雅地区的均衡调整时间域在1 Ma左右的时间尺度内。通过与地貌响应时间域相对比,以及对地表剥蚀厚度的估计,认为山脉地区的正均衡异常主要由地壳厚度补偿不足引起(侧重Airy假说),而山前盆地的负均衡异常主要由低密度沉积层的分布引起(侧重Pratt假说),由于地貌响应时间快于均衡调整时间,在大约5～2 Ma以来,地壳的均衡调整始终延迟于山脉的持续剥蚀和山前的持续沉积,使得岩石圈朝着"反均衡"方向演变,最终形成了喜马拉雅现今壮观的镜像均衡重力异常分布。     

盆山系统沉积学-兼论华北和塔里木地区研究实例

在地球科学领域盆山系统可以作为一种新的地质单元或整体进行研究。在评述国内外研究成果基础上,本文提出了盆山系统分类三原则:即板块构造单元（位置）、盆山形成演化的构造动力学体制、构造-古地理特征或区域源-汇构造-沉积属性,并由此将盆山系统划分为陆内、陆缘（陆洋）和洋内盆山系统三大类及下属十四个亚类。进而论述了盆山系统沉积学的研究体系,其中构造-地层单元与等时地层格架、物源示踪与源汇体系、综合沉积记录及古构造-古气候演变等三方面是研究基础,沉积体系（域）与综合构造-古地理是核心,而盆山演化动力学为学科目标。以华北东部陆内盆山系统为例,研究指出西伯利亚板块与华北-蒙古联合块体的碰撞隆升,形成了该区侏罗纪-早白垩世早期最显著的陆内山-盆系统,而苏鲁造山带碎屑物源影响甚微;以塔里木陆缘盆山系统为例,初步揭示了泥盆-石炭纪西南天山被动陆缘与东南天山弧相关陆缘盆山系统的差异记录。研究认为,为了深化盆山动力学研究,现阶段特别值得在物源示踪与源汇体系、综合沉积记录及古构造-古气候演变方面加强盆山系统沉积学工作。     

GDZ-300L型履带式全液压多功能钻机的设计

主要介绍了GDZ-300L型履带式全液压多功能钻机总体结构设计、动力机的确定、液压系统设计、机械传动系统设计、主要技术参数等内容。样机试制和野外生产试验结果表明：该钻机结构紧凑、质量轻、钻进能力强、可靠性高。