The present research elucidates the accelerating effect of alumina minerals on metolachlor transformation using sulfur nucleophiles and also determines the metolachlor transformation mechanisms in the heterogeneous reaction systems. Metolachlor transformation was first systematically investigated under different conditions. Then, the Fourier transform infrared (FTIR) spectra were used to characterize the changes in the surface bonds of the aluminas. The transformation products were qualitatively identified using LC/MS. The results showed that bisulfide can produce efficient metolachlor transformation rates, and the presence of the aluminas can further accelerate the transformation by achieving complete transformation in <21 days. In addition, a higher pH and higher bisulfide concentration are more favorable for metolachlor transformation. When normalized to the surface area, the metolachlor transformation rates were found to follow the order of α‐Al2O3>γ‐AlOOH>γ‐Al2O3 in the presence of different aluminas. FTIR results indicated that the enhancement of metolachlor transformation rates by bisulfide with aluminas can be attributed to the surface active nucleophiles on alumina surfaces formed through Al? S and Al? O bonds. The substitution of chlorine on the metolachlor followed the SN2 mechanism by bisulfide with accelerated rate through mediating the heterogeneous reactions with aluminas. 相似文献
Lung cancer is the second most commonly diagnosed cancer in both men and women in Georgia, USA. However, the spatio-temporal patterns of lung cancer risk in Georgia have not been fully studied. Hierarchical Bayesian models are used here to explore the spatio-temporal patterns of lung cancer incidence risk by race and gender in Georgia for the period of 2000–2007. With the census tract level as the spatial scale and the 2-year period aggregation as the temporal scale, we compare a total of seven Bayesian spatio-temporal models including two under a separate modeling framework and five under a joint modeling framework. One joint model outperforms others based on the deviance information criterion. Results show that the northwest region of Georgia has consistently high lung cancer incidence risk for all population groups during the study period. In addition, there are inverse relationships between the socioeconomic status and the lung cancer incidence risk among all Georgian population groups, and the relationships in males are stronger than those in females. By mapping more reliable variations in lung cancer incidence risk at a relatively fine spatio-temporal scale for different Georgian population groups, our study aims to better support healthcare performance assessment, etiological hypothesis generation, and health policy making. 相似文献
The Sichuan-Tibet railway goes across the Upper Jinsha River, along which a large number of large historical landslides have occurred and dammed the river. Therefore, it is of great significance to investigate large potential landslides along the Jinsha River. In this paper, we inspect the deformation characteristics of a rapid landsliding area along the Jinsha River by using multi-temporal remote sensing, and analyzed its future development and risk to the Sichuan-Tibet railway. Surface deformations and damage features between January 2016 and October 2020 were obtained using multi-temporal InSAR and multi-temporal correlations of optical images, respectively. Deformation and failure signs obtained from the field investigation were highly consistent. Results showed that cumulative deformation of the landsliding area is more than 50 cm, and the landsliding area is undergoing an accelerated deformation stage. The external rainfall condition, water level, and water flow rate are important factors controlling the deformation. The increase of rainfall, the rise of water level, and faster flow rate will accelerate the deformation of slope. The geological conditions of the slope itself affect the deformation of landslide. Due to the enrichment of gently dipping gneiss and groundwater, the slope is more likely to slide along the slope. The Jinsha River continuously scours the concave bank of the slope, causing local collapses and forming local free surfaces. Numerical simulation results show that once the landsliding area fails, the landslide body may form a 4-km-long dammed lake, and the water level could rise about 200 m; the historic data shows that landslide dam may burst in 2–8 days after sliding. Therefore, strategies of landslide hazard mitigation in the study area should be particularly made for the coming rainy seasons to mitigate risks from the landsliding area.
Landslides - From June 10 to 13, 2019, continuous heavy rainfall occurred in Longchuan County, Guangdong Province, yielding a cumulative rainfall of nearly 270 mm. The heavy rainfall... 相似文献