FT-IR Spectroscopic Investigation of Hydrous Components in Sillimanite from Eastern Ghat Granulite Belt, India

FT-IR spectra of sillimanite samples from high grade regionally metamorphosed rocks belonging to the granulite terrain (amphibolite to pyroxene granulite facies) deciphers prominent OH features. Heating experiments indicate growth of prominent band at 3161cm⁻¹. Heating above 1000°C all OH features disappear in intensity into broad features with slight shift of bands towards lower energies. Complete dehydration requires temperatures above 1000°C. Coexistence of boron and OH features are also observed in all sillimanite samples. The high temperature behaviour of sillimanite from the granulite terrain discerns that the hydrous species in sillimanite were incorporated much below 700°C, however, secondary hydration due to pegmatite activity, retrograde metamorphism and migmatisation is not ruled out. Thus a near anhydrous condition were probably not achieved during the granulite facies metamorphism in Eastern ghat granulite terrain.     

Environmental impact on groundwater of Maheshwaram Watershed,Ranga Reddy district,Andhra Pradesh

Maheshwaram watershed is situated in Ranga Reddy district of at a distance of about 30 km south of Hyderabad. The watershed has an area of 53 km² and has hard rock aquifers with semi-arid climate. The study area has been expanding at a fast pace and now has the distinction of being one of the fastest growing urban centers, facing the problem of groundwater depletion and quality deterioration due to the absence of perennial source of surface water and also due to over exploitation. Human activities involving industrial and agricultural development and the inadequate management of land and water resources have, directly or indirectly resulted in the degradation of environment viz. water and soil.     

Trace metal assessment in soils in a small city and its rural surroundings,Pensacola, FL,USA

This study assesses the origin and pollution of trace metals in surface soils in a region with contrasting land uses (urban vs. rural). Principal component analysis (PCA) reveals that Cr and Ni are predominantly of geogenic origin. These two trace metals are also the only ones with statistically significant correlations with soil particle size and organic matter content. Copper, Pb and Zn, and possibly Hg, are of anthropogenic origin, but their concentrations rarely reach levels described as strongly polluted by pollution indexes. The concentrations of these anthropogenic trace metals are statistically not different in urban and rural areas, except for Pb that is higher in the urban area. This general lack of a difference between the two land uses indicates that the influence of this small urban area on trace metal concentrations in soils is minor. Lead and Zn have the most, but still a modest number, of strongly polluted sites, mainly in an industrial part of the city. GIS analysis shows that, based on the pollution load index (PLI), overall concentrations of trace metals also reach their highest levels in that industrial area. These observations indicate that the influence of industry on trace metal pollution in soil exceeds that of other urban activities in the region. Local background concentrations were found to be very different from general crustal background concentrations. This demonstrates the importance of the careful selection of a background type in studies like this.     

Hydrogeochemical parameters for assessment of groundwater quality in a river sub-basin

Hydrogeochemical studies were carried out in the Ghataprabha River sub-basin to assess the quality and suitability of groundwater for domestic and irrigation purposes. In the present study, an integrated, geophysical and chemical investigation was carried out in the basaltic terrain. Groundwater samples were collected covering the entire major hydrogeological environment for one hydrological cycle. Comparison of the groundwater quality in relation to drinking water quality standards proves that most of the water samples are not suitable for drinking. Chemical indices such as sodium percentage, sodium adsorption ratio and chloroalkaline indices used for evaluating the water quality for irrigation suggest that the majority of the groundwater samples were good for irrigation. Positive values of 74% of groundwater samples indicated the absence of base exchange reaction (chloroalkaline disequilibrium) and negative ratio of 26% samples indicated a base exchange reaction (chloroalkaline equilibrium). Resistivity tomography studies revealed that the high concentration of total dissolved solids, chloride and sodium were due to the local anthropogenic activities and weathering of basalt rocks.     

Role of Crystal Interlocking on the Strength of Brittle Rocks

Results of an experimental programme on heterogeneous rock-like specimens of dental plaster confirm the pronounced role of tensile microcracks on brittle failure. Microbuckling of very small rock-columns formed amid closely located tensile cracks was observed as the key incident connecting stable phenomenon of tensile cracking to unstable phenomenon of shearing and subsequent macroscopic failure. Using the classical beam and buckling theories and considering geometry of the problem a new failure criterion is proposed. As a novel attempt, this new failure criterion relates the compressive strength of rock to three basic microstructural properties, i.e. degree of crystal interlocking, average Young modulus and average tensile strength of rock forming minerals.     

Trace element and REE geochemistry of fine- and coarse-grained sands in the Ordos deserts and links with sediments in surrounding areas

In addition to mineral analyses, REE and trace element geochemical characteristics of fine- and coarse-grained sands in the Ordos deserts and other sediments in surrounding areas are investigated.Commonly the samples consist of quartz, feldspar and muscovite and less clinochlore, dolomite and ankerite. In few samples muscovite is absent.REE and trace compositions are spatially uniform for the same grain-size sands, suggesting that they could have the same sources or/and were well homogenized. However, fine- and coarse-grained sands in the Ordos deserts show different REE and trace element compositions. Fine-grained sands show higher contents of REE and trace elements than those of coarse-grained sands. They differ in Eu anomalies and (La/Yb)_N ratios although both fractions are characterized by the steep LREE and smooth HREE patterns. The fine- and coarse-grained sands are also distinct in some characteristic element ratios (e.g., Th/Co, La/Sc, Th/Sc and Y/Ni).REE and trace element patterns of the two different grain-size fractions are closely associated with geological properties of individual sources rather than the mineralogical differentiation induced by wind sorting. The coarse-grained sands mainly resulted from sandstone weathering in the Ordos deserts and movements of coarse particles by wind. REE and trace element patterns of fine-grained sands in the Ordos deserts differ from those of sandstones in the Ordos deserts, the alluvial sands in the surrounding mountains and the coarse fluvial sands in the Yellow River. They resemble the fine fluvial sands in the Yellow River. In addition, arid areas of Northwest China such as the Tarim Basin and the Alxa Plateau should not be ruled out as the source of the fine-grained sands in the Ordos deserts because these arid areas reserve plenty of fine-grained sediments and also located in the upwind directions of the Ordos deserts.     

Numerical modeling of tide-surge interaction along Orissa coast of India

The Orissa coast of India is one of the most vulnerable regions of extreme sea levels associated with severe tropical cyclones. There was extensive loss of life and property due to the October 1999 super cyclone, which devastated large part of the Orissa coast. The shallow nature of the head bay, presence of a large number of deltas formed by major rivers of Orissa such as Mahanadi and Dhamra, and high tidal range are responsible for storm surge flooding in the region. Specifically, rising and falling tidal phases influence the height, duration, and arrival time of peak surge along the coast. The objective of the present study is to evaluate the tide-surge interaction during the 1999 Orissa cyclone by using nonlinear vertically integrated numerical models. The pure tidal solution for the head bay region of the Bay of Bengal provides the initial condition for the fine resolution nested grid Orissa model. However, the feedback from the Orissa model does not affect the head bay model as the study provides a one-way interaction. Numerical experiments are performed to study the tide-surge interaction by considering various relative phases of the tidal waves with the surge-wave produced by 1999 Orissa cyclone. The comparison, although utilizing only the limited estimates of tidal data, appears adequate to assert that the principal features are reproduced correctly.     

A two-stage evolution of Visakhapatnam-Paradip shelf,east coast of India,from magnetic studies

A detailed analysis of bathymetry and magnetic data of Visakhapatnam-Paradip shelf, east coast of India revealed three major structural lineaments over the shelf/slope of the area. Models derived from the anomalies associated with the trends indicate that trend A represents horst and graben type continental basement while trend B is due to a series of dyke intrusions. Trend C off Chilka lake forms the northward extension of 85°E lineation from deep sea Bengal Fan. A two stage evolution of the eastern continental margin of India has been inferred from the study of this part of the margin, viz., the rift stage evidenced by dyke intrusions of reverse polarity located within the inner part of the shelf and post-rift stage characterized by vertical tectonics in the form of a horst and graben type continental basement. The hotspot related aseismic 85°E ridge further complicated the tectonics of this part of the area.