Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain

Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population, quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater was recharged by precipitation and was characterized by Ca–HCO₃ type water with depleted δ¹⁸O and δD (mean value of −8.8‰ δ¹⁸O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex (Ca–Na–Mg–HCO₃–Cl–SO₄ type), and heavier δ¹⁸O and δD were observed (around −8‰ δ¹⁸O). Before the surface water with mean δ¹⁸O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ¹⁸O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal end of the fan. The groundwater underwent chemical evolution from Ca–HCO₃, Na–HCO₃, to Na–SO₄. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical evolution, and groundwater flow paths in the complex alluvial fan aquifer system.     

Microbial release of potassium from K-bearing minerals by thermophilic fungus Aspergillus fumigatus

A strain of thermophilic fungus Aspergillus fumigatus was cultured with K-bearing minerals to determine if microbe-mineral interactions enhance the release of mineralic potassium. Experiments were carried out in two settings, one with the mineral grains and the fungal cells in direct contact, and the other employing a membrane (pore size 0.22 μm) to separate the two. Measurements over a period of 30 days showed that, irrespective of the experimental setup, the concentration of free K in the culture was drastically higher than those in any of the control experiments where no living organism was present. Moreover, the occurrence of mineral-cell physical contact enhanced potassium release by an additional factor of 3 to 4 in comparison to the separation experiments. For contact experiments, Electron Probe Microanalysis revealed the formation of mycelium-mineral aggregates, and Atomic Force Microscopy imaging further indicated the possible ingestion of mineral particles by the fungus cells. Contrasting to what was observed and expected in control experiments, the potassium solubilization rate showed a positive dependence upon pH when fungi and minerals were mixed directly, and exhibited no correlations with solution acidity if cell-rock contact was restrained. These results appear to suggest that A. fumigatus promoted potassium release by means of at least three likely routes, one through the complexation of soluble organic ligands, another appealing to the immobile biopolymers such as the insoluble components of secretion, and the third related to the mechanical forces in association with the direct physical contact between cells and mineral particles.     

CO2地质埋存渗漏风险及补救对策

目前,将CO2埋存于地下深部地质构造（如油气藏、煤层、地下含水层及岩溶盐腔）的减排方案能有效地减缓温室效应而备受关注。无论什么储集体,我们都希望CO2在地下埋存的时间越长越好。然而,对于一项具体工程的实施,必然存在一些客观和主观因素造成CO2渗漏,比如废弃井的不完善或不合理处理、地层断裂系统和水动力系统以及地震所造成的渗漏等等。存在渗漏就可能会对周围人和生态环境造成危害。因此,进行CO2地质埋存的风险评估是相当有必要的,是我们能长期有效安全地进行该项减排方案必不可少的基础和保证。本文即想从建立一套完整的风险评估、管理和监测体系的角度并以加拿大Weyburn油田为例,深入分析CO2地质埋存中可能存在的渗漏风险和途径,建立CO2渗漏风险评估机制,并针对具体的渗漏可能性提出相应的补救对策,为全球范围内,尤其对我国刚刚开展CO2地质埋存研究工作提供一些有益的思路。     

华南前寒武系基底变质杂岩和中-新生代地幔岩的稀有气体同位素组成及其大地构造意义

对华南前寒武系变质岩浆杂岩稀有气体He、Ne、Ar和Xe的系统研究表明:扬子克拉通基底为含高³He的下地壳"原始岩石层",(³He/⁴He)×10^-6比值为2.8～4.6;而华夏板块基底变质岩浆杂岩则是在缺乏³He、低(³He/⁴He)×10^-8比值(3.15～17.7)的构造环境下形成的大陆中-上地壳变质岩浆杂岩层,反映出两者基底性质迥然不同。华南中-新生代爆破岩筒He同位素组成相反,相对稳定的扬子克拉通(³He/⁴He)×10^-8比值仅0.18～4.22,而郯庐-四会-吴川断裂以东,中-新生代活动地块(太平洋构造域)(³He/⁴He)×10^-8比值高达3.7～20.5。He同位素表明郯庐-四会-吴川断裂带为切割深至地幔的边界深大断裂,是扬子克拉通与华夏板块间的边界且控制了燕山期火山-侵入岩浆向西扩展。Ar同位素组成表明华南大陆中-新生代地幔形成接近"均一"的地幔组份。¹³⁶Xe/¹³⁰Xe-¹²⁹Xe/¹³⁰Xe相关组份表明它们具有地幔柱岩石同位素组成特征。     

Application of Monte-Carlo statistical experiments in design of ocean engineering——Estimating the parameters, models and probabilities

Recently, some results have been acquired with the Monte- Carlo statistical experiments in the design of ocean en gineering. The results show that Monte-Carlo statistical experiments can be widely used in estimating the parameters of wave statistical distributions, checking the probability model of the long- term wave extreme value distribution under a typhoon condition and calculating the failure probability of the ocean platforms.     

机载雷达高度计对海况及海面风速的测量研究

运用我国自行研制的ＺＨＧ－１型Ｘ波段机载雷达高度计于１９９５年４月１３日－４月１８日在青岛附近海域进行的海上飞行实验数据，及导出的均方根波高、有效波高、均方根波陡算法模型，得到了上述海况参数值。     

大西洋中脊TAG热液活动区中热液沉积物的稀土元素地球？…

用ＩＣＰ－ＭＳ对ＴＡＧ热液活动区表层热液沉积物中６个块状硫化物样品进行了稀土元素分析。所有样品均表现出正Ｅｕ异常和ＬＲＥＥ相对富集的球粒陨石标准化配分模式,热液沉积物样品中稀土元素组成的变化是由于海底热液循环体系中热液流体和涨水不同程度混合作用的结果,     

黄海的风、潮混合特征及其对冷水团边界的影响

本文第一作者早在1985年就提出,潮混合效应控制着夏季黄海冷水团的边界及海面冷水分布(赵保仁,1985)。1987年又进一步通过水文调査资料和卫星图片给出了黄海周围的浅水陆架锋(或称潮汐锋)的分布及强锋区的跨锋断面中的温度、盐度和坏流结构特征,并指出夏季的黄海沿岸流在性质上属沿锋面运动的强流(赵保仁,1987a,b),而后又对黄海西部的陆架锋进行了一次专门调査(赵保仁等,1991)。此外,他还指出黄海的强温跃层的形成和转移现象也与潮混合现象密切相关(赵保仁,1989)。因此,研究潮混合现象对阐明发生在黄海的多水文物理现象都是至关重要的。 为深入了解黄海的潮混合特征,作者把渤海、黄海和东海作为一个整体完成了一次精度较高的潮汐、溯流数值计算,在潮汐、潮流的分布方面,揭示了前人尚未阐明的一些特征。本文根据这些数值结果,计算了近最大潮流流速和层化参数,阐明了渤海、黄海和东海的潮混合特征及其对降温期黄海冷水团分布变化的影响。此外,还用 Sim pson等人(1981)的能量模式计算了南黄海西部的风、潮混合效率。     

Robust adaptive control of underactuated ships on a linear course with comfort

This paper addresses an important problem in ship control application—the robust stabilization of underactuated ships on a linear course with comfort. Specifically, we develop a multivariable controller to stabilize ocean surface ships without a sway actuator on a linear course and to reduce roll and pitch simultaneously. The controller adapts to unknown parameters of the ship and constant environmental disturbances induced by wave, ocean current and wind. It is also robust to time-varying environmental disturbances, time-varying change in ship parameters and other motions of the ship such as surge and heave. The roll and pitch can be made arbitrarily small while the heading angle and sway are kept to be in reasonably small bounds. The controller development is based on Lyapunov’s direct method and backstepping technique. A Lipschitz continuous projection algorithm is used to update the estimate of the unknown parameters to avoid the parameters’ drift due to time-varying environmental disturbances. Simulations on a full-scale catamaran illustrate the effectiveness of our proposed controller.     

分潮波模型多资料数值计算方法研究 Ⅱ.有限差分最小二乘方法

对含多资料的分潮波模型的超定问题进行探讨，建立一种有限差分—最小二乘方法，该方法使得岸边资料直接进入了计算方程，并保证岸界法向流速为零条件。通过对渤海的四大分潮的试算，证实本方法可行。