辽南复州湾太原组的燕海扇类

本文记述了发现于辽南复州湾上石炭统太原组的燕海扇类,计5属17种。讨论了Annuliconcha与Paradoxipecten的属征及有关问题。上述发现在东北地区尚属首次。     

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

Effect of some additives on synthesis of zeolite from coal fly ash

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.     

Cross-formational hydrocarbon fluid flows in the Tertiary deltaic system of the Beaufort–Mackenzie Basin

Molecular and isotopic compositions of crude oils in the Beaufort–Mackenzie Basin confirm three genetic end-member oil groups and suggest extensive cross-formational hydrocarbon fluid flows in the Tertiary deltaic system. Inter- and intra-fractional variations in the geochemistry of the Tertiary-reservoired oils indicate that the oil source/maturity signatures were substantially masked by biomarkers that were picked up along migration pathways. Thus, many of the previously recognized “immature non-marine oils” are in fact thermally mature, probably derived from unpenetrated deeper marine source rocks. Although the effective source rock volumes have not been evaluated and their exact stratigraphic levels remain unknown, the relative timing of oil generation versus trap formation, rather than poor source quality, may be the cause of under-filled traps in the offshore area.     

Are the South and North Liaohe Groups of North China Craton different exotic terranes? Nd isotope constraints

The Liaohe Group is an important Paleoproterozoic stratigraphic unit in the northeastern part of the North China Craton and is traditionally subdivided into the North and South Liaohe Groups. Associated with both the North and South Liaohe Groups are voluminous Paleoproterozoic granitoid rocks, named the Liaoji granitoids. Different tectonic models, including terrane amalgamation, continent–arc collision and rift closure, have been proposed to interpret the tectonic setting and evolution of the North and South Liaohe Groups and associated Liaoji granitoids. At the centre of the controversy between these models is whether or not the North and South Liaohe Groups developed on the same Archean basement. Nd isotopic geochemistry of the Liaoji granitoids provides important constraints on this controversial issue. The Liaoji granitoids associated with the North and South Liaohe Groups display similar ε_Nd values, restricted to a narrow range from 0 to 2, implying that these granitoid rocks were derived from the same or a similar magma source. Moreover, the Liaoji granitoids associated with the North and South Liaohe Groups have similar Nd model ages (T_DM), ranging from 2.4 to 2.6 Ga, suggesting that the protoliths of the Liaoji granitoids associated with both groups may have formed simultaneously, and that the basement rocks underneath the Liaoji granitoids and associated North and South Liaohe Groups belong to the same continental block rather than two different blocks. Combining lithological, structural and geochronological considerations, we interpret the North and South Liaohe Groups as having developed on a single late Archean basement that underwent Paleoproterozoic rifting associated with the intrusion of the Liaoji granitoids and the formation of the Liaohe Group, and closed upon itself in the Paleoproterozoic.     

Weathering and climate change since l820 AD in Hoh Xil, Qinghai-Xizang Plateau, China——Evidence from element geochemistry of lake sediments of Gulug Co Lake

Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the dement composition of lake sediments from Gulug Co Lake, Hoh Xil, Qing- hai-Xizang Plateau, chemical index of alteration （CIA）, index of composition variability （ICV） and other element ratios have been used to establish the weathering sequence of this area since 1820 AD. The weathering is so weak that the element composition change is more sensitive to climate change and autochthonous processes. From 1820 to 1984 AD, there were two drier periods with a wetter interval from 1870 to 1945 AD. After 1984 the weather showed a tendency of becoming wet.     

我国入境旅游和经济增长关系分析

文章分析了入境旅游发展的区域差异，并用Granger因果检验来考察入境旅游和各区域经济增长之间是否存在相应的因果关系，Granger因果检验的结果表明在东部地区，入境旅游和经济增长存在单向因果关系。东部地区的入境旅游对区域的经济增长产生显著影响。但是全国和中西部地区的入境旅游与经济增长之间不存在显著的因果关系。类似地，东部地区入境旅游增长是其第三产业增长的Granger原因。但是全国和中西部地区的入境旅游和相应区域第三产业的增长并不存在显著的因果关系。在区域层面上。只有少数区域支持入境旅游是区域GDP增长的Granger原因，它们是东部地区的北京、广东、上海、天津、福建、江苏、浙江、海南和广西；中部地区的黑龙江和湖南以及西部地区的云南和陕西。在这些省区市。入境旅游对区域经济增长产生显著的影响。但总体而言，入境旅游在我国还没有足够的发展。     

Modeling the seismic response of basin-edge structure by a sequential waveform method

A sequential waveform method is developed to simulate the seismic response of basin-edge structure excited by a plane incident P-wave. The full procedure involves: (a) a previous parameterization of the investigated model using the seismic wave velocities and depths of the sedimentary stratifications; (b) an input motion determined from the records at stations installed on hard rock; (c) forward computation of the P-SV elastic wave field by means of a two-dimensional finite difference (FD) method; (d) the optimization of the model vector using simulated annealing technique and comparing the simulated seismic response of the tested structure with the observed wave field; (e) the correction of the initial model by trial-and-error by testing the differences between synthetics and observed data, and (f) the final solution obtained by iteration using the conjugate gradient algorithm. The search of an optimal basin-edge model has been parallel processed by varying the shapes and velocities of strata on the basis of the fitting of relative timing, amplitude and phase between the output and the observed data. The input motion and sensitivity have been checked and the validity of the method has been demonstrated by numeric analysis. Using the teleseismic records generated by 7 earthquakes recorded at 26 broadband seismic stations, we have studied the seismic velocity structure of the southern edge of the Jiyang depression located in the Bohai Bay basin, northern China. Two cross sections show an agreement between the velocity results and the geological sections available in the region. In addition, we obtain evidence of three hidden faults under the sections and features that suggest major extensions at the Paleogene.     

Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China

Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (C_org), extractable extracellular carbon (C_ext), total soil nitrogen (N_t), alkali-hydrolyzable nitrogen (N_ah), total phosphorus (P_t), available phosphorus (P_a) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation–extraction, FE-C_mic, and by calculation from substrate-incubation respiration, SIR-C_mic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of C_mic/C_org and BR/C_mic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as C_org and C_ext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-C_mic, SIR, and SIR-C_mic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with the land degradation.     

Distribution of cadmium, chromium, copper, lead and zinc in marine sediments in Hong Kong waters

Partitioning of heavy metals (Cd, Cr, Cu, Pb, Zn) in marine sediments collected from various sites in Hong Kong waters were determined using sequential extraction method. Sediments from Kellette Bank, located in Victoria Harbour, had higher metal concentrations especially Cu and Zn than most other sites. Slightly over 20% of total Cu and Cr existed as readily available forms in Peng Chau and Kellette Bank. At most sampling sites, over 15% of the Cu existed as the exchangeable form indicating that Cu could be readily released into the aqueous phase from sediments. A significantly higher percentage of Pb and Zn was associated with the three non-residual fractions. Hence, there is a greater environmental concern for remobilization of Pb and Zn compared with Cr. The high amount of residual Cd (>50%) and the relatively lower Cd content indicate that little environmental concern is warranted for the remobilization of Cd. Distribution of metals in sediments collected from different depth at Kellette Bank shows that metal concentrations decreased with profile depth. The levels of Pb and Zn associated with the two readily available fractions increased sharply in the surface sediment. These metals represented the pollutants, which were introduced into the area in the mid-eighties through early nineties as a result of rapid economic and industrial development in the territory. As significant portions of these metals were bound to the readily available phases in the surface sediments, metal remobilization could be a concern. An erratum to this article can be found at