Spatial and temporal variability of the ratios between the nitrate and phosphate concentrations in the Sea of Okhotsk

The relation between the nitrate and phosphate concentrations in the Sea of Okhotsk and the bordering waters of the Pacific Ocean were studied. The surveys were carried out in the autumn, spring, and summer of 2001–2002. For the deepwater part of the sea, the relation [NO^? ₃] = ((14.88 ± 0.07) × [PO^3? ₄] ? 5.46 ± 0.17) was found. The coefficients in the equation given are statistically different from those in the similar equation for the Pacific waters: [NO^? ₃] = (16.05 ± 0.15) × [PO^3? ₄]-(7.23 ± 0.36). In the northern part of the sea; on the shelf; in the slope area; and, especially, in the deep waters of the TINRO Depression, the linear dependence between the phosphate and nitrate concentrations was distorted. This feature was described in terms of nitrate deficiency. The maximum values of this deficiency were found in the near-bottom waters. The principal processes that might cause the nitrate deficiency were considered: the difference in the oxidation rates of the nitrogen and phosphorus organic compounds, the matter transfer between the continent and the sea, the different efficiency of the biogenic burial of nitrogen and phosphorus in the bottom sediments, and the denitrification in the upper layer of the bottom sediments. It was shown that the most probable cause of the nitrate deficiency was the denitrification. The loss of inorganic nitrogen owing to the supply of the waters of the Sea of Okhotsk to the Pacific Ocean was estimated as ～2.5 × 10¹¹ mol N/year.     

Study of the ice conditions in the Gulf of Ob

The results of theoretical studies of fracture lines in the ice floes of the Gulf of Ob as a function of the coefficient of internal sliding are presented in this paper. An estimate of the fractal dimensions of the emerging topological structures and the results of the calculation of stresses in the ice cover of the Gulf of Ob are presented as functions of different directions of external forcing caused by the joint action of winds and currents on the ice. The geographical locations of the zones of possible loads are shown, together with the estimates of the hummock sizes in the zones of the maximal compression of the ice floes in the Gulf of Ob.     

Quasi-biennial variations in ozone and meteorological parameters over western Europe from ozonesonde data

Quasi-biennial variations in vertical profiles of ozone, temperature, air pressure, and zonal and meridional wind velocities are analyzed from ozonesonde data obtained at the western European stations of Lindenberg, Hohenpeissenberg, and Payerne. The effect of quasi-biennial variations manifests itself variously in different variables and is nonuniform in altitude. The period of quasi-biennial variations is not constant, and the values of the mean period group mainly around 2 and 2.5 years. As in the North American region, the effects of quasi-biennial variations in different parameters of the stratosphere and troposphere over western Europe are due to a combination of the effects of the quasi-biennial oscillation (QBO) in the equatorial stratosphere, the El Niño-Southern Oscillation (ENSO), and the North Atlantic Oscillation (NAO). The observed 2.5-year variations in stratospheric ozone are related to the equatorial QBO to a larger extent in comparison with variations in other variables. It seems likely that a determining influence on variations in stratospheric wind and temperature is exerted by the ENSO. Variations in tropospheric and stratospheric parameters with a mean period of about 2 years are due to the ENSO and NAO effects.     

Features of wind waves at the southeastern coast of Sakhalin according to bottom-pressure measurements

The results of wind-wave measurements with bottom-pressure sensors are discussed. These measurements were performed at the southeastern coast of the Island of Sakhalin in 2006–2009. The problems of converting data obtained with these sensors into water-level displacent in the context of the linear theory are noted. Twenty records with a duration of 2 weeks to 3 months were obtained. These records contain from 150000 to 1200000 waves for three different observation points located at the southeastern coast of Sakhalin in the regions of the village of Vzmor’ye, Lake Izmenchivoye, and the Cape of Ostryi. The estimates obtained for wave-height distributions were approximated by the Weibull distribution. They were compared to the theoretical Rayleigh, Forristall, Weibull, and Glukhovskii distributions. As one would expect, in the region of small wave heights, all distributions prove to be close to one another, and, for large wave heights, the Weibull distribution is preferred.     

Geoelectric section of the Central Tien Shan: Sequential inversion of the magnetovariational and magnetotelluric data along the Naryn Line

The paper presents the results of 2D inversion of deep magnetotelluric (MT) and magnetovariational (MV) soundings along the Naryn Line. The method of partial (sequential) inversions is used. According to this method, at the first stage, magnetovariation responses are used for the localization of deep anomalies of electrical conductivity, and then the magnetotelluric sounding data are invoked to refine the structure of the host medium and the structural details in the upper part of the section. It is shown that this approach enables one to estimate the informativeness of separate components of the electromagnetic field, to reduce the distorting influence of the near-surface geoelectric inhomogeneities, and to increase the stability of the final solution of the inverse problem.     

Paleoproterozoic quartz-pebble conglomerate type uranium mineralisation in Mankarhachua area,Angul district,Orissa

Ground Radiometric survey of Paleoproterozoic pyritiferous quartz-pebble conglomerate (QPC) occurring to the north of Pallahara area led to the discovery of a QPC type uranium mineralisation near Mankarhachua village. Significant radioactivity is recorded in three sub-parallel uraniferous QPC horizons with metamorphosed pebbly to medium grained recrystallised massive sandstones. Detrital grains of uranothorite, thorite, radioactive allanite, monazite, zircon, minute uraninite grains in carbonaceous matter and thucolite contributes to the radioactive phases present in QPC matrix. Adsorbed U on limonite and goethite, secondary uranyl minerals in matrix, along bedding planes and fractures are commonly observed. This discovery has opened up a new horizon for future exploration for QPC type uranium mineralization in the area. The paper presents observations on geology, radioactivity, petrological and geochemical nature of the uraniferous QPC horizons.     

Effects of soil type and fertilizer on As speciation in rice paddy contaminated with As-containing pesticide

Inorganic arsenic (As) pesticides have been widely used for decades in many countries. However, insufficient data are available on the chemical speciation of inorganic arsenicals in tropical paddy soils. Inorganic As-containing pesticides were used in tropical countries, a few decades ago, however, their fate have not been studied. Hence, the objective of this study was to determine fractionation of inorganic arsenicals and to assess As lability with/without fertilizer application using a static incubation experiment. Eight soils from wet and dry regions of Sri Lanka were amended with 1,000 mg/kg arsenate for this purpose. The FT-IR and XRF results suggested that soils in the wet region were rich in Fe/Al-oxides. Paddy soils in the dry zone showed high As lability. These low-humic gley soils have low Fe/Al oxyhydroxide and alkaline pH. In contrast, the wet zone had soils with higher As retention capacity, high amounts of Fe/Al oxyhydroxide, and acidic pH. Arsenic lability increased considerably 30 days after fertilizer application. Overall, As lability was mainly influenced by soil mineralogical and chemical properties, i.e., Fe/Al oxyhydroxide, pH, organic matter, and fertilizer application.     

Way forward to achieve sustainable and cost-effective biofuel production from microalgae: a review

Driven by policies aimed at enhancing energy security and mitigating greenhouse gas emissions, the production and use of biofuels have significantly increased in recent years. Microalgae owing to its multiple advantages which include high lipid content, sustainable biomass production, effective land and water utilization are the most potential biofuel feedstock that can provide drop-in fossil fuel replacements without stimulating competition for agricultural resources and are considered to be more environmentally benign than the first- and second-generation biofuel feedstocks. However, there are many existing technical and scientific impediments that are yet to be resolved. Keeping this in view, the present review provides a concise account of the microalgal species known to accumulate high levels of lipid and describes the main factors that should be taken into consideration while selecting suitable algal strains for mass cultivation. The underlining advantages and limitations of raceway pond and photobioreactor cultivation systems are also examined. The recent advances in genetic engineering of microalgae to improve biomass and lipid productivity are then highlighted, which include the ongoing debate over the biosafety issues pertinent to the use of genetically modified algae. Furthermore, a wide range of high-value products that can be co-produced from microalgae have been discussed. The review concludes with a comprehensive summary of the major techno-economic constraints to commercialization of algal-derived biofuels along with promising methods for overcoming these challenges in order to produce cost-competitive and environmentally sustainable biofuel.     

A comparison of methods of strain determination in rocks from southwest Dyfed (Pembrokeshire) and adjacent areas

A variety of methods devised in the last twelve years for measuring two-dimensional strain ratios have been applied to the same deformed oolitic limestone from southwest Dyfed. Their relative merits are discussed. A graphical method for studying relative locations of marker objects is described and its application to a variety of rocks illustrated. It is shown to have theoretical and practical advantages, while giving values of two-dimensional strain ratios comparable with those of other methods.     

Effect of major ion variations in the marine environment on the specific gravity-conductivity-chlorinity-salinity relationship

Partial equivalent conductances and partial equivalent volumes of the major constituents in seawater were used to evaluate the specific gravity-conductivity-chlorinity-salinity relationships in the marine environment. For example, in the open ocean, the relationships between Cl‰ and both S‰ and specific gravity are valid to within 0.014‰ and 0.014 σ_t, respectively. The relationships between conductivity and S‰ and specific gravity are valid to within 0.006‰ and 0.007 σ_t. In river diluted nearshore areas specific gravity anomalies inferred from Cl‰, can be as great as 0.06 σ_t and 0.04 σ_t when inferred from a conductivity ratio measurement.