A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere.
An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of
the IO A2Π3/2 ← X2Π3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument
was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N2O/CF3I/N2 mixtures with O3 actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration
period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer)
campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured
significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing
the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum
at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF. 相似文献
Carbon and nitrogen stable isotopes were used to investigate spatial variation in terrestrial particulate organic matter (POM) input to a coastal area off the Tagus river estuary. Isotopic variation in higher trophic level organisms was also examined, along the coast. This study was carried out in late summer, after a period of 3 months of low river flow. The overall aim was to determine if under such conditions the coastal area is enriched by the river plume and, particularly, if lower secondary productivity should be expected in some areas. Spatial variation was detected as a gradient of decreasing terrestrial input with increasing distance from the river. It was concluded that terrestrial carbon input was also incorporated into higher trophic levels and that organisms with lower mobility are more sensitive to the gradient in terrestrial input. Even in low flow conditions the whole fishing area remained under the influence of the river plume, which still accounted for 24% of the total POM 30 km from the river mouth. Additionally, δ15N values indicated pollution input from the river Tagus. 相似文献
Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility. 相似文献
Bathymetric, 9.5-kHz long-range sidescan sonar (OKEAN), seismic reflection and sediment-core data are used in the analysis
of two tectonic troughs south of Crete, Eastern Mediterranean Sea. Here, up to 1.2 s two-way travel time (TWTT) of strata
have accumulated since the Middle Miocene in association with extension in the South Aegean region. The study area comprises
>100-km- long by >25-km-wide basins filled by sediments subdivided into two seismic units: (1) an upper Unit 1 deposited in
sub-basins which follow the present-day configuration of the southern Cretan margin; (2) a basal Unit 2, more than 500 ms
(TWTT) thick, accumulated in deeper half-graben/grabens distinct from the present-day depocentres. Both units overlap a locally
stratified Unit 3 comprising the pre-Neogene core complex of Crete and Gavdos. In this work, the interpreted seismic units
are correlated with the onshore stratigraphy, demonstrating that denudation processes occurring on Crete and Gavdos in response
to major tectonic events have been responsible for high sedimentation rates along the proximal southern Cretan margin. Consequently,
topographically confined sedimentary units have been deposited south of Crete in the last 12 Ma, including turbidites and
other mass-flow deposits fed by evolving transverse and axial channel systems. Surface processes controlling facies distribution
include the direct inflow of sediment from alluvial-fan systems and incising mountain rivers onto the Cretan slope, where
significant sediment instability processes occur at present. In this setting, seismic profiles reveal eight different types
of stratigraphic contacts on basin-margin highs, and basinal areas show evidence of halokinesis and/or fluid escape. The acquired
data also show that significant changes to the margin’s configuration occurred in association with the post-Alpine tectonic
and eustatic episodes affecting the Eastern Mediterranean. 相似文献
Centennial–millennial dynamics of tropical salt marsh vegetation are documented in the pollen record from marine core MD03-2622, Cariaco Basin, Venezuela, which spans the glacial period between 63 and 29 ka. Five rapid and abrupt expansions of salt marsh vegetation are linked with North Atlantic Heinrich events (HEs). Within each event, a recurrent pattern – starting with species of Chenopodiaceae, followed by grasses, and subsequently by Cyperaceae species – suggests a successional process that is determined by the close relationship between sea-level and community dynamics. The salt tolerant Chenopodiaceae, at the base of each sequence, indicate hypersaline intertidal environments, which were most likely promoted by extremely dry atmospheric conditions. Rapid sea-level rise characterizes the onset of HE stadials, causing erosion of marsh sediments, and continued recruitment of pioneer species (Chenopodiaceae), which are the only ones capable of tolerating the rapid rate of disturbance. Once, as sea-level drops or as rise decelerates, marsh plants are able to trap and stabilize sediments, favouring the establishment of more competitive species (graminoids). The increment of marsh height as a result of autochthonous sediment accumulation reduces the extent of hypersaline environments, and allows the establishment of mesohaline species. These results add to the scarce knowledge on tropical salt marsh ecosystems, and provide independent paleoclimatic evidence on sea-level changes occurring simultaneously with Antarctica climate variations. 相似文献
Vicksburg loess is characterized by preferred orientation of constituent grains, which on the average dip 4° toward the west (N 80–85°W). This investigation was undertaken to study, quantitatively, the relationship between natural fabric anisotropies of Vicksburg loess and the orientation of applied stress distribution Results of the study indicate the fabric anisotropies in Vicksburg loess are reflected by definite variation in triaxial shear strength of dry and moist specimens.
In two series of triaxial tests, ultimate strength of the loess is maximum where σ1 is perpendicular to grain orientation, and it is reduced where the principal stresses are 45° to the fabric plane. In this respect, Vicksburg loess may serve as a structural model for granular earth materials in illustrating the influence of fabric on ultimate strength. Moreover, the Mohr-Coulomb fracture line consists of two line segments, with an increase in slope at higher confining pressure. This characteristic suggests that poorly-cemented sands, or sandstones, and silts, or siltstones, may undergo two failures: one at small strains where cement bonds are disrupted and the other at larger strains where internal shearing resistance of granular components is exceeded. 相似文献
The quantitative study of the distribution and taxonomic composition of recent living and dead (without plasma) benthic foraminifers revealed three foraminiferal assemblages in the bottom sediments of the Pacific Ocean at depths of 3350 to 4981 m. The assemblage dominated by the epibenthic Lagenammina difflugiformis, Reophax dentaliniformis, and Saccorhiza ramosa occupies the slopes of underwater hills. The assemblage with a high share of the infaunal Cribrostomoides subglobosum, C. nitidum, and Ammobaculites agglutinans is registered on the abyssal plateau. The assemblage with a significant proportion of the large Astrorhiza and Reophax species, which are characterized by an active way of life, populates gentle slopes and narrow depressions with potentially strong bottom currents. 相似文献