Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).     

关于对海洋监测人员培训的初步探讨

文章从海洋监测人员培训的起源与发展、存在问题和建议等方面对此项工作进行了论述。分析了此项工作取得的成绩与发展现状。通过对该工作开展过程中得到的经验与教训,提出了对此项工作的建议。     

Integration of GIS and video surveillance

This paper discusses the integration of three-dimensional (3D) geographic information systems (GIS) and video surveillance systems using augmented reality (AR) techniques. The motivation for this integration is to overcome problems faced by conventional video surveillance systems. Explicit information concerning which camera currently monitors what area in such systems is missing; therefore, insight into the situation depends heavily on the operator’s training and experience. To ensure the complete coordination and monitoring of a situation in a system with multiple cameras, it is necessary to introduce a single reference system. GIS arises as a natural solution because it not only provides a solid ground truth but also provides semantic information that can be highly important in certain video surveillance applications. To integrate information into a GIS application, that information must be georeferenced. Based on our previous research regarding the addition of georeferencing information to surveillance video, this paper introduces models that can be applied to help integrate video and GIS. With an analogy to Milgram’s continuum between the real world and virtual reality, and analogous to the augmented reality and augmented virtuality in Milgram’s continuum, two models of integration are defined here: GIS-augmented video and video-augmented GIS. Then, we define the architecture of GIS-based video surveillance based on these proposed integration models, and finally, a prototype is implemented. The implemented prototype serves as a basis for analysing possible applications of real-world systems based on the integration of GIS and video.     

A parallel algorithm for coverage optimization on multi-core architectures

Location siting is an important part of service provision, with much potential to impact operational efficiency, safety, security, system reliability, etc. A class of location models seeks to optimize coverage of demand for service that is continuously distributed across space. Decision-making and planning contexts include police/fire resource allocation for a community, siting cellular towers to support cell phone signal transmission, locating emergency warning sirens to alert the public of severe weather and other related dangers, and many others as well. When facilities can be sited anywhere in continuous space to provide coverage to an entire region, this is a very computationally challenging problem to solve because potential demand for service is everywhere and there are an infinite number of potential facility sites to consider. This article develops a new parallel solution approach for this location coverage optimization problem through an iterative bounding scheme on multi-core architectures. The developed approach is applied to site emergency warning sirens in Dublin, Ohio, and fire stations in Elk Grove, California. Results demonstrate the effectiveness and efficiency of the proposed approach, enabling real-time analysis and planning. This work illustrates that the integration of cyberinfrastructure can significantly improve computational efficiency in solving challenging spatial optimization problems, fitting the themes of this special issue: cyberinfrastructure, GIS, and spatial optimization.     

Molecular characterization of sulfate-reducing bacteria community in surface sediments from the adjacent area of Changjiang Estuary

Sulfate-reducing bacteria (SRB), which obtain energy from dissimilatory sulfate reduction, play a vital role in the carbon and sulfur cycles. The dissimilatory sulfite reductase (Dsr), catalyzing the last step in the sulfate reduction pathway, has been found in all known SRB that have been tested so far. In this study, the diversity of SRB was investigated in the surface sediments from the adjacent area of Changjiang Estuary by PCR amplification, cloning and sequencing of the dissimilatory sulfite reductase beta subunit gene (dsrB). Based on dsrB clone libraries constructed in this study, diversified SRB were found, represented by 173 unique OTUs. Certain cloned sequences were associated with Desulfobacteraceae, Desulfobulbaceae, and a large fraction (60%) of novel sequences that have deeply branched groups in the dsrB tree, indicating that novel SRB inhabit the surface sediments. In addition, correlations of the SRB assemblages with environmental factors were analyzed by the linear model-based redundancy analysis (RDA). The result revealed that temperature, salinity and the content of TOC were most closely correlated with the SRB communities. More information on SRB community was obtained by applying the utility of UniFrac to published dsrB gene sequences from this study and other 9 different kinds of marine environments. The results demonstrated that there were highly similar SRB genotypes in the marine and estuarine sediments, and that geographic positions and environmental factors influenced the SRB community distribution.     

Application of 2D numerical model to unsteady performance evaluation of vertical-axis tidal current turbine

Tidal current energy is renewable and sustainable, which is a promising alternative energy resource for the future electricity supply. The straight-bladed vertical-axis turbine is regarded as a useful tool to capture the tidal current energy especially under low-speed conditions. A 2D unsteady numerical model based on Ansys-Fluent 12.0 is established to conduct the numerical simulation, which is validated by the corresponding experimental data. For the unsteady calculations, the SST model, 2×10~5 and 0.01 s are selected as the proper turbulence model, mesh number, and time step, respectively. Detailed contours of the velocity distributions around the rotor blade foils have been provided for a flow field analysis. The tip speed ratio(TSR) determines the azimuth angle of the appearance of the torque peak, which occurs once for a blade in a single revolution. It is also found that simply increasing the incident flow velocity could not improve the turbine performance accordingly. The peaks of the averaged power and torque coefficients appear at TSRs of 2.1 and 1.8, respectively. Furthermore, several shapes of the duct augmentation are proposed to improve the turbine performance by contracting the flow path gradually from the open mouth of the duct to the rotor. The duct augmentation can significantly enhance the power and torque output. Furthermore, the elliptic shape enables the best performance of the turbine. The numerical results prove the capability of the present 2D model for the unsteady hydrodynamics and an operating performance analysis of the vertical tidal stream turbine.     

Numerical Analysis of Gravity Coring Using Coupled Eulerian-Lagrangian Method and a New Corer

The shortcomings of gravity corers in sampling marine sediments have been observed extensively in various field tests. In order to optimize the coring, this article provides an alternative numerical way to model the gravity coring and analyze the sampling effect. Based on this analysis, a new hydraulic hammer corer is devised. A coupled Eulerian-Lagrangian method with capability of simulating the problem involving extreme deformation, penetration is used to simulate the coring process. The results show that the hydrostatic pressure and deviator stress increase and reach their peak when the pile tip is slightly above or at the level of the observation point and then drop rapidly when the pile tip slides below the observation point. In addition, the stress path indicates that the soil element sustains plastic compression before yielding and then expands until recovering to the original state. The obvious “under-sampling” phenomenon is also well-captured by the finite element model.     

不同刚度植物杆群对规则波传播及紊动特性影响研究

以不同刚度硅胶圆杆群为概化植物模型,测定其抗弯弹性模量,通过波浪水槽实验,研究规则波在不同刚度植物杆群内的流速分布、紊动特征及不同刚度杆群的消浪效果。实验结果表明,当波浪通过柔性杆群时,受其摆动的影响,流速周期变化从单峰型逐渐转变成双峰型,杆群刚度越小形成的二次波峰越明显;不同刚度杆群内水体紊动强度变化显示,杆群刚度越大,造成杆群内水体的紊动强度越大;随着杆群抗弯弹性模量的增大,其消浪系数也增大,消浪系数的增长与材料的抗弯弹性模量值非线性关系,而是在某一弹性模量范围内,对消浪系数的影响较为敏感。     

Contribution of phytoliths to total biogenic silica volumes in the tropical rivers of Malaysia and associated implications for the marine biogeochemical cycle

The contribution of phytoliths to total biogenic silica (BSi) volumes in rivers worldwide, and the associated implications for the biogeochemical cycle, require in-depth study. Based on samples from rivers in Peninsular Malaysia, this project investigated the source and characteristics of BSi found in Asian tropical rivers, as well as the process of reverse weathering taking place in these fluvial systems. Results indicated that BSi samples collected in sediments consisted of phytolith, diatom and sponge spicules. Phytoliths, predominantly of the elongate form, comprised 92.8%–98.3% of BSi in the Pahang River. Diatom BSi in this river consisted mainly of pennatae diatoms, but represented a relatively small proportion of the total BSi volume. However, diatom BSi (predominantly of the Centricae form) was more prevalent in the Pontian and Endau Rivers with shares of 68.8% and 79.3% of the total BSi volumes, respectively, than Pahang River. Carbon contents of the BSi particulates ranged from 1.85% to 10.8% with an average of 4.79%. These values are higher than those recorded in other studies to date, and indicate that BSi plays a major role in controlling permanent carbon burial. This study suggests that phytoliths from terrestrial plants are the primary constituents of BSi in the rivers of Peninsular Malaysia, and therefore represent a significant proportion of the coastal silica budget.