桂西地区二叠系合山组铝土岩的沉积环境*

桂西地区二叠系合山组铝土岩的沉积环境存在海相、陆相之争。通过对桂西二叠系铝土岩的区域调查及钻孔样品微量元素地球化学数据的分析,认为桂西二叠系铝土岩产出于陆相环境。从铝土岩分布情况看,桂西二叠纪各孤立碳酸盐岩台地上均广泛分布铝土岩沉积,该区域产出特征证明矿层是在碳酸盐岩台地全部暴露地表的环境下形成的。从铝土岩层与下伏茅口组灰岩的接触关系来看,铝土岩层底部存在茅口组灰岩砾石,在部分剖面尚见下伏茅口组灰岩中充填铝土岩等现象,说明铝土岩矿化过程直接于茅口组灰岩的古喀斯特面上完成。此外,在矿层中发现古植物根茎化石也是铝土岩形成于陆相环境的有力证据。从微量元素地球化学结果来看,来自铝土岩层样品的硼含量均小于10×10^-6,Sr/Ba值范围为0.29~1.61,平均值为0.92,Rb/K值范围为0.0011~0.0025,平均值为0.0017,以上指标结合V/Zr-Zr/Cu图解的判别,结果均指示铝土岩形成于陆相淡水环境。     

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.     

全国地质灾害趋势预测及预测图编制

区域地质灾害预测是地质灾害研究的难题。本文运用基于地理信息系统的风险评价方法对这一问题进行了探讨。将全国剖分为2700个单元,对地质灾害进行现状评价,并与已数字化的地质灾害图件进行单要素叠加,编制了全国地质现状等值线图,在现状评价基础上,对地质灾害进行趋势预测,将降雨条件、区域地震活动、区域地壳稳定程度、区域岩组条件和人类工程活动等作为区域地质灾害演变的因素,运用模糊综合评判模型进行综合评判,编制了1:600万中国地质灾害趋势预测图。     

隧道支护结构荷载作用的随机反演

提出荷载－结构模式进行随机反分析方法，从隧道支护结构变形反算对应的荷载作用，可反推围岩抗力系数和覆土荷载的分布情况，以及作用于支护结构上各部位的外荷载。提出了以实测位移为基础的样条函数插值．以插值位移补充大量的实测值，满足了反分析所需众多的已知位移数。通过一施工实例对该方法的可行性进行了检验。     

黄铁矿表面及其与Au（HS）2^—溶液作用的STM研究

本文用ＳＴＭ研究了黄铁矿和方铅矿表面的原子结构、纳米级微形貌、电子态分布及其吸附态的特点。ＳＴＭ电流图象揭示了表面缺陷与表面电子态之间的对应关系，硫化和的表面的化学反应活性可能是表现缺陷引起的局域导电性增强有关。ＳＴＭ观察进一步表明黄铁矿和方铅矿对金的硫氢配合物的吸附作用优先发生于扭折位和台阶边缘等高能部位，反映出吸附态的分布也是与表面电子态分布相对应的。这样就从微观领域考证了硫化物表面对化学活性     

Effects of gas pricing reform on China’s price level and total output

Natural gas plays an important role in the mitigation of climate change, yet its development is constrained by the current natural gas pricing mechanism in China. In the context of the natural gas pricing reform, this paper analyzes the potential effects on price level and total output. Through the input–output model, some conclusions are drawn as follows: (1) The gas pricing reform has relatively great impact on the products’ price of the sectors that have large gas consumption, such as industrial sectors and some service sectors, and on the total output of the gas production and supply sectors and the petroleum and natural gas extraction sectors, whereas the reform has relatively small impact on other industries; (2) effects of gas pricing reform on urban and rural residents are dissymmetrical, with larger effects on urban residents and (3) the reform has relatively small impacts on both various price indices and total output levels; thus, the government can realize the promotion of gas pricing reform nationwide at a cost of relatively small increase in general price level and little lose of total output.

     

Experimental research on a new encapsulated heat-generating hydraulic fracturing fluid system

1 IntroductionFracturing plays an important role in increasingthe production and injection and enhancing the final re-covery of oil and gas. At present, the use of ahydroxypropyl guar gum, borate-crosslinked, hydraulicfracturing fluid systemhas become ext…