Natural radioactivity in sediment of Wei River,China

The concentrations of natural radionuclides in sediment of Wei River of China were measured using γ-ray spectrometry with the aim of estimating the radiation hazard as establishing a database for radioactivity levels of river sediment of China. The activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in sediment samples ranged from 10.4 to 39.9 Bq kg⁻¹, 15.3 to 54.8 Bq kg⁻¹ and 514.8 to 1,175.5 Bq kg⁻¹, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities of Chinese soil and Shaanxi soil. Radium equivalent activity (Ra_eq), external hazard index (H _ex) and representative level index (I _γr) were calculated for the samples to assess the radiation hazards arising due to the use of these sediment samples in the construction of dwellings. All the sediment samples have Ra_eq lower than the limit of 370 Bq kg⁻¹, H _ex less than unity and I _γr close to 1 Bq kg⁻¹. The overall mean outdoor terrestrial gamma dose rate is 64.8 nGy h⁻¹ and the corresponding outdoor annual effective dose is 0.079 mSv. None of the studied location is considered a radiological risk and sediment can be safely used in construction.     

Application of MODFLOW and geographic information system to groundwater flow simulation in North China Plain, China

MODFLOW is a groundwater modeling program. It can be compiled and remedied according to the practical applications. Because of its structure and fixed data format, MODFLOW can be integrated with Geographic Information Systems (GIS) technology for water resource management. The North China Plain (NCP), which is the politic, economic and cultural center of China, is facing with water resources shortage and water pollution. Groundwater is the main water resource for industrial, agricultural and domestic usage. It is necessary to evaluate the groundwater resources of the NCP as an entire aquifer system. With the development of computer and internet information technology it is also necessary to integrate the groundwater model with the GIS technology. Because the geological and hydrogeological data in the NCP was mainly in MAPGIS format, the powerful function of GIS of disposing of and analyzing spatial data and computer languages such as Visual C and Visual Basic were used to define the relationship between the original data and model data. After analyzing the geological and hydrogeological conditions of the NCP, the groundwater flow numerical simulation modeling was constructed with MODFLOW. On the basis of GIS, a dynamic evaluation system for groundwater resources under the internet circumstance was completed. During the process of constructing the groundwater model, a water budget was analyzed, which showed a negative budget in the NCP. The simulation period was from 1 January 2002 to 31 December 2003. During this period, the total recharge of the groundwater system was 49,374 × 10⁶ m³ and the total discharge was 56,530 × 10⁶ m³ the budget deficit was −7,156 × 10⁶ m³. In this integrated system, the original data including graphs and attribution data could be stored in the database. When the process of evaluating and predicting groundwater flow was started, these data were transformed into files that the core program of MODFLOW could read. The calculated water level and drawdown could be displayed and reviewed online.     

Timing of UHP metamorphism in the Hong’an area,western Dabie Mountains,China: evidence from zircon U–Pb age,trace element and Hf isotope composition

The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies. These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ Lu_N ≥ 14) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and ¹⁷⁶Lu/¹⁷⁷Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf model ages (T _DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Experimental investigation on thermochemical sulfate reduction by H2S initiation

Hydrogen sulfide (H₂S) is known to catalyze thermochemical sulfate reduction (TSR) by hydrocarbons (HC), but the reaction mechanism remains unclear. To understand the mechanism of this catalytic reaction, a series of isothermal gold-tube hydrous pyrolysis experiments were conducted at 330 °C for 24 h under a constant confining pressure of 24.1 MPa. The reactants used were saturated HC (sulfur-free) and CaSO₄ in the presence of variable H₂S partial pressures at three different pH conditions. The experimental results showed that the in-situ pH of the aqueous solution (herein, in-situ pH refers to the calculated pH of aqueous solution under the experimental conditions) can significantly affect the rate of the TSR reaction. A substantial increase in the TSR reaction rate was recorded with a decrease in the in-situ pH value of the aqueous solution involved. A positive correlation between the rate of TSR and the initial partial pressure of H₂S occurred under acidic conditions (at pH ∼3-3.5). However, sulfate reduction at pH ∼5.0 was undetectable even at high initial H₂S concentrations. To investigate whether the reaction of H₂S_(aq) and occurs at pH ∼3, an additional series of isothermal hydrous pyrolysis experiments was conducted with CaSO₄ and variable H₂S partial pressures in the absence of HC at the same experimental temperature and pressure conditions. CaSO₄ reduction was not measurable in the absence of paraffin even with high H₂S pressure and acidic conditions. These experimental observations indicate that the formation of organosulfur intermediates from H₂S reacting with hydrocarbons may play a significant role in sulfate reduction under our experimental conditions rather than the formation of elemental sulfur from H₂S reacting with sulfate as has been suggested previously (Toland W. G. (1960) Oxidation of organic compounds with aqueous sulphate. J. Am. Chem. Soc.82, 1911-1916).Quantification of labile organosulfur compounds (LSC), such as thiols and sulfides, was performed on the products of the reaction of H₂S and HC from a series of gold-tube non-isothermal hydrous pyrolysis experiments conducted at about pH 3 from 300 to 370 °C and a 0.1-°C/h heating rate. Incorporation of sulfur into HC resulted in an appreciable amount of thiol and sulfide formation. The rate of LSC formation positively correlated with the initial H₂S pressure. Thus, we propose that the LSC produced from H₂S reaction with HC are most likely the reactive intermediates for H₂S initiation of sulfate reduction. We further propose a three-step reaction scheme of sulfate reduction by HC under reservoir conditions, and discuss the geological implications of our experimental findings with regard to the effect of formation water and oil chemistry, in particular LSC content.     

圆柱螺线法测斜计算中的数值方法

圆柱螺线法是井眼轨迹计算中最常使用的方法之一,在实钻轨迹监控、中靶分析和预测、井身质量评价等实际问题中都有重要的应用.但是当井段2个端点的井斜角之差或者方位角之差等于零时,圆柱螺线法坐标计算公式需要进行特殊处理才能正常计算;在井斜角之差或者方位角之差很小时,坐标计算会出现较大误差.对圆柱螺线法坐标计算公式进行了改进,用一组计算公式统一处理井斜角之差或者方位角之差等于零和不等于零的情况,提高了坐标的数值计算的精度和稳定性.对圆柱螺线型井眼轨迹的平均井眼曲率的数值计算进行了研究,提出了使用高斯型数值积分公式计     

基于AGA的SVM需水预测模型研究

需水预测是一个由城市人口、工业水平、社会经济水平共同作用的多因素、多层次的复杂非线性系统.其结果将直接影响受区域水资源承载力约束的产业结构、布局形态等决策.作为一种集中参数预报方法,支持向量机方法具有对未来样本的较好的泛化性能,对于这类资料缺乏、系统结构尚欠清晰的问题可以取得较好的模拟和预测结果.基于此,本文将支持向量机方法引入需水预测领域,建立了需水预测支持向量机模型.同时,本文将加速遗传算法和支持向量机方法耦合起来,构造了支持向量机模型参数的自适应优化算法.模型在珠海市的应用实例表明:与简单遗传算法比较,AGA的模型参数寻优效率更高;与BP神经网络模型相比,SVM模型较好地解决了小样本、经验性等问题,并取得了较高的预测精度.     

西沙群岛红藻研究Ⅲ

本文继续报道我国西沙群岛产的十种红藻，其中梨形葡萄藻[Botryocladia pyriformis (Boergesen) Kylin]，聚集腔节藻(Coelarthrum coactum Okam. et Segawa)，渐狭下舌藻(Hypoglossum attenuatum Gardner)，棍棒内管藻[Endosiphonia clavigera (Wolny) Falkenberg],匍甸软骨藻(Chondria repens Boergesen)和扩展软骨藻(Chondria expansa Okam.)等六种为我国新记录；西沙软骨藻(Chondria xishaensis sp. nov.)为一新种;矮孔果藻和梨形葡萄藻的四分孢子囊均为首次记述。     

马里亚纳弧前区锥形海山岩石学及成因

锥形海山是马里亚纳弧前区非火山成因的海山。它是由俯冲的太平洋板块对仰冲板块的上推作用,地壳下的上地幔物质底辟侵入的结果。海山顶部的岩石是由蛇纹石化超镁铁质方辉橄榄岩组成。其主要矿物成分为斜方辉石、橄榄石、尖晶石、磁铁矿、蛇纹石和碳酸盐。手标本呈显晶质块状构造,薄片中呈粒状、残留状、筛网状及斑状变晶结构。岩石化学特征表现为:低Si和Al,高M/F值,含水,亏损了所有过渡金属。岩石的成因属超基性岩浆直接结晶,后经海水的参入,在热液作用下普遍发生蛇纹石化和碳酸盐化。     

Taxonomy and ultrastructure of five species of Tetraselmis (Prasinophyceae) isolated from China seas

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｇｅｎｕｓＴｅｔｒａｓｅｌｍｉｓＳｔｅｉｎ ( 1 878)ｉｓａｇｒｅｅｎｆｌａｇｅｌｌａｔｅｓ (Ｐｒａｓｉｎｏｐｈｙｃｅａｅ)ｔｈａｔｃｏｎｓｉｓｔｓｏｆｍａｎｙｍａｒｉｎｅａｓｗｅｌｌａｓａｆｅｗｆｒｅｓｈｗａｔｅｒｓｐｅｃｉｅｓ .Ｍａｒｉｎｅｓｐｅｃｉｅｓｏｆｔｅｎｏｃｃｕｒｉｎｄｅｎｓｅｐｏｐｕｌａ ｔｉｏｎｓｃａｕｓｉｎｇｂｌｏｏｍｓｉｎｔｉｄｅｐｏｏｌｓｏｒｂａｙｓ ,ｔｈｅｒｅｂｙｂｅｉｎｇｉｍｐｏｒｔａｎｔｔｏａｎｕｎｄｅｒｓｔａｎｄｉｎｇｏｆｔｈｅｄｙｎａｍ…     

罗氏沼虾育苗用水中Mg2+与Ca2+含量及Mg2+/Ca2+对出苗率的影响

１９９１年３－６月和１９９２年３－６月在南汇县东海水产养殖公司对罗氏沼虾育苗用水调配原则与不同基础水的调配方法进行试验研究。结果表明，育苗用水中Ｍｇ＾２＋与Ｃａ＾２＋含量及Ｍｇ＾２＋／Ｃａ＾２＋必须达到一定的范围，这是调配的基本原则。以鱼塘水作基础水时，需添加６种化学药品，其中Ｍｇ＾２＋与Ｃａ＾２＋含量可适范围分别为３００．０－４４０．０ｍｇ／Ｌ与１７０．０－２４４．０ｍｇ／Ｌ，Ｍｇ＾２＋／Ｃａ＾