SORPTION AND DESORPTION CHARACTERISTICS OF CADMIUM BY FOUR DIFFERENT SOILS IN NORTHEAST CHINA

1IN TR O D U C TIO NA s a persistentand toxic pollutant, cadm ium (C d) canresultin m any adverse health effects in a variety oftis-suesand organssuch asthe lung,kidney,urinary,blad-der,pancreas,breast and prostate (SA TA R U G etal.,2003).C adm ium in so…     

基于N-KD树的空间点数据分组算法

随着科学技术的进步,地理空间数据的分析处理面临着数据量膨胀和计算量高速增长的双重挑战,为了解决海量数据处理速度慢的问题,本文针对空间分布不均匀的点数据,从数据并行的角度,以保持数据的空间邻近性及保证数据分组后各组数据量负载均衡为目标,提出基于N-KD树（Number-K Dimension Tree）数据动态分组的方法,其是一种面向实时变化（数据量和数据空间范围变化）的空间数据动态分组方法。该方法借鉴K-D树的创建和最临近点搜索的思想,通过方差判断数据分布稀疏程度,利用最临近点搜索方法处理边界点,实现空间范围的不均等切分,保证数据分组后各组数据量基本均衡。试验表明,该方法具有较好的动态分组效果与较高的计算效率;支持各种分布状态的空间点数据的分组;分组后各组数据量负载均衡;分组算法本身有支持并行、支持分布式协同工作模式的特点。     

Comparing Solar Minimum 23/24 with Historical Solar Wind Records at 1 AU

Based on the variations of sunspot numbers, we choose a 1-year interval at each solar minimum from the beginning of the acquisition of solar wind measurements in the ecliptic plane and at 1 AU. We take the period of July 2008??C?June 2009 to represent the solar minimum between Solar Cycles 23 and 24. In comparison with the previous three minima, this solar minimum has the slowest, least dense, and coolest solar wind, and the weakest magnetic field. As a result, the solar wind dynamic pressure, dawn?Cdusk electric field, and geomagnetic activity during this minimum are the weakest among the four minima. The weakening trend had already appeared during solar minimum 22/23, and it may continue into the next solar minimum. During this minimum, the galactic cosmic ray intensity reached the highest level in the space age, while the number of solar energetic proton events and the ground level enhancement events were the least. Using solar wind measurements near the Earth over 1995??C?2009, we have surveyed and characterized the large-scale solar wind structures, including fast-slow stream interaction regions (SIRs), interplanetary coronal mass ejections (ICMEs), and interplanetary shocks. Their solar cycle variations over the 15 years are studied comprehensively. In contrast with the previous minimum, we find that there are more SIRs and they recur more often during this minimum, probably because more low- and mid-latitude coronal holes and active regions emerged due to the weaker solar polar field than during the previous minimum. There are more shocks during this solar minimum, probably caused by the slower fast magnetosonic speed of the solar wind. The SIRs, ICMEs, and shocks during this minimum are generally weaker than during the previous minimum, but did not change as much as did the properties of the undisturbed solar wind.     

Lithologic mapping of HED terrains on Vesta using Dawn Framing Camera color data

The surface composition of Vesta, the most massive intact basaltic object in the asteroid belt, is interesting because it provides us with an insight into magmatic differentiation of planetesimals that eventually coalesced to form the terrestrial planets. The distribution of lithologic and compositional units on the surface of Vesta provides important constraints on its petrologic evolution, impact history, and its relationship with vestoids and howardite‐eucrite‐diogenite (HED) meteorites. Using color parameters (band tilt and band curvature) originally developed for analyzing lunar data, we have identified and mapped HED terrains on Vesta in Dawn Framing Camera (FC) color data. The average color spectrum of Vesta is identical to that of howardite regions, suggesting an extensive mixing of surface regolith due to impact gardening over the course of solar system history. Our results confirm the hemispherical dichotomy (east‐west and north‐south) in albedo/color/composition that has been observed by earlier studies. The presence of diogenite‐rich material in the southern hemisphere suggests that it was excavated during the formation of the Rheasilvia and Veneneia basins. Our lithologic mapping of HED regions provides direct evidence for magmatic evolution of Vesta with diogenite units in Rheasilvia forming the lower crust of a differentiated object.     

南京市城市居民对乡村旅游发展的感知及旅游行为研究

运用问卷调查法和基于SPSS软件的统计分析法,以南京市为例,从城市居民感知视角考察乡村旅游的发展情况。从旅游偏好、旅游频率和空间分布等方面探讨城市居民的乡村旅游行为特征,并进一步分析了乡村旅游的知晓度、居民对各乡村旅游点开发水平的感知与其空间分布之间的相关关系,以及居民对乡村旅游发展总体印象与旅游频率之间的相关关系。在此基础上,提出南京市乡村旅游发展的有关对策与建议。     

冬季北极涛动和北极海冰变化对东亚气候变化的影响

本文简要回顾了冬季北极涛动 (北大西洋涛动 )和北极海冰面积变化对东亚气候变化的影响、研究中存在的问题以及目前亟待解决的科学问题。     

Assessing the impacts of ecological-living-productive land changes on eco-environmental quality in Xining City on Qinghai-Tibet Plateau,China

The Ecological-living-productive land(ELPL) classification system was proposed in an effort to steer China's land pattern to an ecological-centered path, with the development model shifting from a single function into more integrated multifunction land use. The focus is coordinating the man-land contradictions and developing an intensive, efficient and sustainable land use policy in an increasingly tense relationship between humans and nature. Driven by socioeconomic change and rapid population growth, many cities are undergoing urban sprawl, which involves the consumption of cropland and ecological land and threatens the ecological balance. This paper aims to quantitatively analyze the critical effects of ELPL changes on eco-environmental quality according to land use classification based on leading function of ecology, living and production from 1990 to 2015 with a case study of Xining City. Also, four future land use scenarios were simulated for2030 using the Future Land Use Simulation(FLUS) model that couples human and natural effects. Our results show a decrease in productive land(PL) and an increase in ecological land(EL) and living land(LL) in Xining City. Forestry ecological land(FEL) covered the top largest proportion; agriculture productive land(APL) showed the greatest reduction and urban and rural living land(U-RLL) presented a dramatic increase. The eco-environmental quality improved in 1990-2010, mainly affected by the conversion of APL to FEL and GEL. However, the encroachment of U-RLL into APL, other ecological land(OEL) and FEL was the main contributor to the decline in eco-environmental quality in 2010-2015 as well as the primary reason for the increase area of lower-quality. The Harmonious Development(HD)-Scenario, characterized by a rational allocation of LL and PL and a better eco-environment, would have implications for planning and monitoring future management of ELPL, and may represent a valuable reference for local policy-makers.     

The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

Heavy metal pollution in sediments of a typical mariculture zone in South China

The heavy metal inventory and the ecological risk of the estuarine sediments in Hailing Bay, an important maricultural zone along the southern coast of China, were investigated. Results show that the surface sediments were mainly polluted by As (2.17-20.34 mg/kg), Ni (1.37-42.50mg/kg), Cu (1.21-58.84 mg/kg) and Zn (11.69-219.22 mg/kg). Furthermore, the aquafarming zone was significantly more polluted than the non-aquafarming zone, and cluster analysis suggested additional sources of heavy metal input in the aquafarming zone. As, Cr, Cu, Ni, Pb and Zn were mainly present in the non-bioavailable residual form in the surface sediments, whereas Cd was predominantly in the highly mobile acid soluble and reducible fractions. The ecological risk of the polluted sediments stemmed mainly from Cd, and from As, Cu and Pb to less degrees. The highest potential risks occurred near the aquaculture base, indicating the need to control heavy metal inputs from aquafarming activities.     

Isolation,purification and characterization of the hydrogen evolution promoting factor of hydrogenase ofSpirulina platensis

A component (s-factor) with obvious promoting effect on hydrogen evolution of hydrogenase has been isolated and extracted from a cell-free preparation ofSpirulina platensis. The effect of the s-factor in the reaction system is similar to that of Na₂S₂O₄, but is coupled with light. The s-factor has the maximum absorption peak at 620 nm in the oxidized state, at 590 nm in the reduced state. The partially purified s-factor showed two bands by SDS-PAGE and is distinctly different from phycocyanin, which has no change of oxidized state and reduced state absorption spectra, and also has no promoting effect on hydrogenase ofSpirulina platensis under the light. The research supported by the NSFC.