河南桐柏围山城层控金银成矿带同位素地球化学

河南省桐柏山区的围山城金银成矿带包括破山特大型银矿、银洞坡大型金矿、银洞岭大型银多金属矿床及一些矿点,赋矿地层是新元古界歪头山组,矿体产状与地层产状一致,形态呈似层状、鞍状或透镜状,层控特征显著。氢-氧-碳同位素地球化学研究指示早、中阶段的成矿流体主要为变质水,晚阶段有大量大气降水加入成矿流体系统。碳-硫-铅同位素指示成矿物质来自于歪头山组地层;钾-氩同位素表明成矿作用(100~140Ma)发生在秦岭陆陆碰撞造山的高峰期之后碰撞挤压向伸展转变的背景下。综合考虑矿带的成矿流体来源、成矿物质来源以及矿床地质特征,认为围山城成矿带属典型的层控造山型金银成矿系统,形成于中生代扬子与华北板块的陆陆碰撞造山体制。     

新疆喀拉萨依含锡花岗岩体地质特征及成岩成矿机制

通过对大量实际资料的分析认为,喀拉萨依含锡花岗岩体形成于造山期后阶段,年龄300Ma左右,岩体中出露的肉红色和灰白色黑云母钾长花岗岩由强分异岩浆先后侵入形成,二者具同源演化关系;原始岩浆为上地壳变碎屑质沉积岩部分熔融形成的黑云母二长花岗质岩浆;发育于岩体边部的云英岩型锡矿化同岩浆期后富含氟的高温气液流体作用有关。     

伏牛山构造带变质流体脉变形特征及构造意义

伏牛山构造带由多条近平行的断裂带和夹持其间的变形岩片组成,洛南-栾川断裂带和瓦穴子-乔端断裂带为其中的两条主要断裂带。这两条断裂带虽遭受多期强烈构造活动的影响,但主造山期的构造特征至今仍然保存完好,并以中深层次的韧性剪切变形为主,形成了典型的糜棱岩和同构造期石英脉。本文从宏观、微观、超微观变形特征及年龄等方面对这些变质流体脉进行了研究,以探讨与其形成密切相关的构造活动特征、年代及其在秦岭造山带和华北板块南缘强变形带中的作用。石英脉中石英颗粒动态重结晶特征总体显示远离剪切带只有少量的膨凸式,靠近断裂带为亚颗粒式,形成核-幔结构,位错特征显示远离剪切带位错密度较小,靠近断裂带较大,位错形态显示瓦乔断裂带以挤压为主,洛南-栾川断裂带以剪切为主。两条断裂带石英脉的变形特征说明它们的糜棱岩化过程均为塑性变形中的晶质塑性变形,形成过程均为挤压在先,剪切在后。所测糜棱岩中石英脉的ESR年龄分别为372.9±30.0 Ma、275.0±20.0 Ma和218.0±20.0 Ma,真实地记录了晚加里东至中-晚海西期北秦岭的构造活动及所受影响。其中372.9±30.0 Ma是宽坪岩块向华北板块下的斜向俯冲汇聚和走滑的年代, 275.0±20.0 Ma是瓦乔断裂带的形成年龄。218.0±20.0 Ma的年龄则反映了华南、华北两大板块印支晚期全面闭合作用在秦岭造山带内部的影响。从以上3个年龄可以看出:北秦岭各构造带自北向南演化,时代上自北向南变新。     

宁芜陶村磁铁矿矿床成矿流体及成矿作用

陶村磁铁矿矿床位于长江中下游成矿带宁芜盆地中段,矿床地质特征及岩浆构造背景与Kiruna型磷灰石-铁氧化物矿床相似。本文在野外工作基础上,通过流体包裹体测温和氢氧硫同位素研究,探讨该矿床成矿流体性质、来源及成矿作用。陶村主要矿石类型为浸染状和脉状磁铁矿,脉状矿石形成稍晚。通过包裹体显微测温获得:磷灰石中包裹体的均一温度集中在210~390℃,盐度集中在15%~23%NaCl_(eqv);石英中包裹体的均一温度集中在330~390℃,盐度主要集中在9%~13%NaCl_(eqv),此外还存在部分高盐度原生包裹体。石英的δD为-96‰~-54‰,δ~(18)O_(H2O)除了一个为8.3‰,其余为1.9‰~4.0‰,指示原始成矿流体为岩浆来源,后期有地表水加入。黄铁矿δ~(34)S为4.8‰~9.3‰,平均值为7.4‰,综合中段地区硫同位素资料,认为成矿流体中的硫来自三叠纪膏盐层与岩浆硫的混合。结合矿床地质特征,陶村成矿作用过程可概括为:岩浆出溶形成的高温含矿气液同化三叠纪膏盐层,带入SO_4~(2-)、Cl~-、Na~+等矿化剂;这种高温气液在岩体内以钠质交代形式富集Fe后,于岩体上部形成浸染状磁铁矿,岩体顶部和边部断裂部位形成(网)脉状磁铁矿。     

Discovery of Eoarchean Meta-Dioritic Rocks in Anshan Area, China and Its Geological Significance

INTRoDUCTIONThe3.8GaBeijiafentrondhjemiticrockwasformedbypartialmeltingofsomeoldercontinentalmaterialintermsofgeochemicalresearches(Waneta1-,l999).Soitisveryim-portanttofindthemoreancientrocksintheAnshanarea.Therecentdiscoveryofthemeta-dioriticrockofEoarchaeanintheDongshanScenicSpotisspecificallyimportantsignifi-canceforit'GEOLOGYANDPETROGRAPHYlntheDongshanScenicSpotoftheAnshancity,thereis.anancientrockbeltbeingmorethanlomwideandstrikingapproximatelyNNW-SSE.Inthebelttherear…     

闽北早古生代岛弧火山岩的岩石地球化学特征

作者系统地研究了福建政和早古生代岛弧火山岩的岩石地球化学特征。研究表明该火山岩是以岛弧拉斑玄武岩-钙碱性火山岩组合为特征的岛弧火山岩系列，并具有从拉斑系列向钙碱性系列演化的特征；该火山岩源于亏损地幔，并且受到一定的陆壳物质混染，基性的拉斑玄武质系列受到陆壳物质混染较少，而中性钙碱性系列则受到较大程度混染。     

Genesis of the Jinchuan PGE deposit, China: evidence from fluid inclusions, mineralogy and geochemistry of precious elements

Summary The Jinchuan deposit is a platinum group element (PGE)-rich sulfide deposit in China. Drilling and surface sampling show that three categories of platinum group element (PGE) mineralization occur; type I formed at magmatic temperatures, type II occurs in hydrothermally altered zones of the intrusion, and type III in sheared dunite and lherzolite. All ore types were analyzed for Os, Ir, Ru, Rh, Pd, Pt and Au, as well as for Cu, Ni, Co and S. Type I ore has (Pt + Pd)/(Os + Ir + Ru + Rh) ratios of <7 and relatively flat chondrite-normalized noble metal patterns; the platinum group minerals (PGM) are dominated by sperrylite and moncheite associated with chalcopyrite, pyrrhotite and pentlandite. Type II has (Pt + Pd)/(Os + Ir + Ru + Rh) ratios from 40 to 330 and noble metal distribution patterns with a positive slope; the most common PGM are sperrylite and Pd bismuthotelluride phases concentrated mostly at the margins of base metal sulfides. Type III ores have the highest (Pt + Pd)/(Os + Ir + Ru + Rh) ratios from 240 to 710; the most abundant PGM are sperrylite and phases of the Pt–Pd–Te–Bi–As–Cl system. It is concluded that the Jinchuan deposit formed as a result of primary magmatic crystallization followed by hydrothermal remobilization, transport, and deposition of the PGE.     

Quantification of electrical resistance to estimate NaCl behavior in a column under controlled conditions

Accurate prediction of solute transport processes in surface water and its underlying bed is an important task not only for proper management of the surface water but also for pollution control in these water bodies. Key issue in this task is an estimation of parameters as diffusion coefficient and velocity for solute transport both in water body and in the underlying bed. This estimation would greatly help us to understand the deposition and release mechanism of solute across the water-bed interface. In this study, a column experiment was conducted in laboratory to estimate the velocity and diffusion coefficient of sodium chloride (NaCl) in water body and underlying sand layer (bed). The column used with a diameter of 30 cm and a height of 100 cm, was filled with sand at the lower half part and water at the upper half part. Total 64 stainless steel electrodes were installed on its surface around. The sodium chloride solution was injected from the top of the column, and electrical resistance between electrodes was monitored for 71 h. Then the dimensionless resistance breakthrough curve was fitted with one dimensional analytic solution for solute transport and the related diffusion coefficient and velocity parameters were estimated. The results show that the NaCl transport velocity was high in the water body but extremely low in the underlying sand layer (bed). The diffusion coefficient estimated in sand layer coincides with those reported well. This indicates that the electrical resistance based solute transport parameter estimation method is not only effective but also has an advantage of multipoints monitoring. This is useful both in mapping solute transport parameter for solute transport process analysis and in providing parameter input for solute transport numerical modeling.     

西准噶尔恰达地区哈尔加乌组火山岩锆石U-Pb年代学、地球化学及地质意义

恰达地区的二叠系哈尔加乌组火山岩分布于唐巴勒蛇绿岩带东侧、准噶尔盆地西南缘,主要岩性为灰绿色-紫红色(气孔)(杏仁)玄武岩-玄武安山岩-安山岩。LA-ICP-MS锆石U-Pb年龄为(296.6±8.1) Ma,MSWD=7.7(93%置信度),时代属早二叠世。地球化学研究表明:该火山岩属亚碱性系列,全碱含量较高(w(Na₂O+K₂O)=3.95%~6.39%)且相对富钠。轻稀土(LREE)相对富集((La/Yb)_N=3.49~14.66)且分馏较好((La/Sm)_N值均大于1.00(1.68~3.51)),重稀土分馏较差((Gd/Yb)_N=1.38~2.56)。仅部分样品有微弱的负铕异常(δEu=0.88~1.15)。微量元素具有大离子亲石元素(LILE)相对富集,高场强元素(HFSE)Nb、Ta相对亏损,Zr、Hf轻微富集的特征。综合火山岩的地球化学特征,结合相关构造判别图解及火山岩所处的区域地质背景,认为哈尔加乌组火山岩的形成背景以板内大陆环境为主,兼有部分弧火山岩的特征,形成于俯冲碰撞造山期后的区域伸展背景下,火山岩的岛弧特征是对碰撞前混染弧组分的继承。     

北秦岭榴辉岩Sm-Nd同位素年龄

采自陕豫交界秦岭群中的榴辉岩主要由石榴子石和绿辉石组成，同时还含有少量的角闪石和金红石。本工作由四个单矿物和全岩五个样，测得Sm－Nd等时年龄为400±16Ma，（r＝0．997575），εNd＝十3．6，说明在加里东期北秦岭造山带发生过高压变质事件。