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111.
Juraj Majzlan Peter Glasnák Robert A. Fisher Mary Anne White Michel B. Johnson Brian Woodfield Juliana Boerio-Goates 《Physics and Chemistry of Minerals》2010,37(9):635-651
Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C
p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe3(SO4)2(OH)6, where A = K, Na, Rb, and NH4. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred
to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:
There are additional configurational entropies of 13.14 and 8.23 J mol−1 K−1 in defect and NH4-jarosite, respectively. A detailed analysis of the synchrotron X-ray diffraction patterns showed a large anisotropic peak
broadening for defect and NH4-jarosite. The fits to the low-temperature (approx. <12 K) C
p data showed that our samples can be divided into two groups. The first group is populated by the K-, Na-, Rb-, and NH4-jarosite samples, antiferromagnetic at low temperatures. The second group contains the H3O-jarosite (studied previously) and the defect jarosite. H3O- and defect jarosite are spin glasses and their low-T
C
p was fit with the expression C
p = γT + ΣB
j
T
j
, where j = (3, 5, 7, 9). The linear term is typical for spin glasses and the sum represents the lattice contribution to C
p. Surprisingly, the C
p of the K-, Na-, Rb-, and NH4-jarosite samples, which are usually considered to be antiferromagnetic at low temperatures, also contains a large linear
term. This finding suggests that even these phases do not order completely, but have a partial spin-glass character below
their Néel transition temperature. 相似文献
Sample | Chemical composition | S o/(J mol−1 K−1) |
---|---|---|
K-jarosite | K0.92(H3O)0.08Fe2.97(SO4)2(OH)5.90(H2O)0.10 | 427.4 ± 0.7 |
Na-jarosite | Na0.95(H3O)0.05Fe3.00(SO4)2(OH)6.00 | 436.4 ± 4.4 |
Rb-jarosite | RbFe2.98(SO4)2(OH)5.95(H2O)0.05 | 411.9 ± 4.1 |
NH4-jarosite | (NH4)0.87(H3O)0.13Fe3.00(SO4)2(OH)6.00 | 447.2 ± 4.5 |
Defect jarosite | K0.94(H3O)0.06Fe2.34(SO4)2(OH)4.01(H2O)1.99 | 412.7 ± 4.1 |
112.
113.
The gravity map of the Aveiro Basin, North West Portugal was produced in 2000/2001 and some limited two dimensional (2D) interpretation was carried out. It is intended in this article to advance the interpretation and modelling of the original Aveiro basin gravity data. Thus, the data were processed and the horizontal gradient, the second vertical derivative and downward continued field computed. The corresponding maps have been processed and a new interpretation of the basin tectonic features has been proposed. This is compared with the previous geological and tectonic information obtained from former surveys and local boreholes. As the next step a more detailed modelling of the Aveiro Basin took place. Bearing the interpretation of the basin tectonic features in mind, several north–south and east–west gravity profiles were established and modelled. The proposed models were presented and discussed. As a result, a comprehensive mass distribution model for the basin was proposed. Finally, comparison was made between the new gravity model and the previously published tectonic features map. This modelling is particularly useful for groundwater protection, exploration and exploitation and also for the dimensioning of drilling operations. Bearing in mind the geomorphology of the basin the gravity method is a very economical tool for the investigation of basin structures. 相似文献
114.
Dr. J. Ulrych Dr. E. Pivec Dr. K. Zák Dr. J. Bendl Dr. P. Bosák 《Mineralogy and Petrology》1993,48(1):65-81
Summary Dykes of alkaline and ultramafic carbonate lamprophyres (monchiquite-ouachitite and aillikite) intrude the Carboniferous sediments of Central Bohemia. Their characteristic feature is the presence of substantial amounts of a sodalite group mineral (presumably haüyne), carbonate and barite. Isotopic compositions of
13C (–3.4 to –6.2) and
18O ( + 13.5 to + 15.9) indicate that the carbonate is of primary magmatic origin and that fluids were formed at temperatures of 500 to 350°C. High contents of CO2 (3.6 to 17.6 wt.%) and incompatible elements, high LREE/HREE ratios (30.0 to 57.7), and low Rb/Sr (0.025 to 0.078) and87Sr/86Sr (0.7038 to 0.7042) ratios suggest the ultramafic lamprophyres are related to deep-seated carbonated magmas of mantle origin. Low degree of partial melting ( < 1%) of the mantle peridotite is envisaged, with additional transport of fluids rich in incompatible elements into the crustal chamber. Alkaline lamprophyres are fractionated derivatives which originated from the same source. Magma intrusion from different levels of a magma chamber into fracture zones under horizontal tension without a central intrusion could result in variability in lamprophyre composition (cumulates or evolved derivatives).
With 8 Figures 相似文献
Alkalische und ultramafische Karbonat-Lamprophyre der zentralen böhmischen Karbonbecken, Tschische Republik
Zusammenfassung Alkalische und ultramafische Karbonat-Lamprophyrgänge (Monchiquit-Ouachitit und Aillikit) intrudieren in karbonische Sedimente Zentralböhmens. Sie sind charakterisiert durch das Auftreten von beträchtlichen Mengen an Mineralen der Sodalith-Gruppe (v.a. Haüyn), Karbonaten und Baryt. Ihre Isotopenzusammensetzung von 13C (–3.4 bis –6.2) und 18O (13.5 bis 15.9) zeigt, daß die Karbonate primär magmatischen Ursprungs sind und daß assoziierte Fluide in einem Temperaturbereich von 350 bis 500°C gebildet wurden. Hohe Gehalte an CO2 (3.6 bis 17.6 Gew. %), inkompatiblen Elementen, hohe LREE/HREE-Verhältnisse (30.0 bis 57.7), sowie niedrige Rb/Sr—(0.025 bis 0.078) und87Sr/86Sr-(0.7038 bis 0.7042) Verhältnisse lassen vermuten, daß die ultramafischen Lamprophyre mit karbonatischen Magmen des Mantels in Beziehung stehen. Eine niedrige Aufschmelzungsrate ( < 1%) von Mantelperidotit mit zusätzlichem Transport von, an inkompatiblen Elementen angereicherten Fluiden, in die krustale Magmenkammer wird diskutiert. Alkalische Lamprophyre sind als stärker fraktionierte Magmen, die derselben Quelle entstammen, zu verstehen. Die Intrusion der aus verschiedenen Bereichen der Magmenkammer stammenden Magmen in durch horizontale Dehnung verursachte Störungszonen könnte das Fehlen eines zentralen Intrusionskörpers und die unterschiedliche Zusammensetzung der Lamprophyre (Kumulate oder entwickelte Derivate) erklären.
With 8 Figures 相似文献
115.
P. Daněk 《GeoJournal》1993,30(3):249-254
In the 1991 population census, 1.4 million inhabitants of the Czech Republic applied for Moravian or Silesian nationality, which did not exist before.They expressed their consciousness of territorial appurtenance to the historical provinces of Moravia and Silesia and by this declaration they set it above the appurtenance to the Czech nation. New social cleavage thus developed in ethnically almost homogeneous environment of the Czech Republic, which constitutes a potential threat of the further splitting of the State. Trying to find the causes of such a phenomenon, the author deals with the territorial differentiation of these inhabitants and factors which influenced it. The close interconnection with political demands is stressed. The insensive centralizing measures of the communist regime are considered as the direct impulses of the present development. The phenomenon is understood as a specific manifestation of the posttotalitarian social crisis in Central and Eastern Europe. 相似文献
116.
Diamond in metasedimentary crustal rocks from Pohorje,Eastern Alps: a window to deep continental subduction 下载免费PDF全文
M. Janák N. Froitzheim K. Yoshida V. Sasinková M. Nosko T. Kobayashi T. Hirajima M. Vrabec 《Journal of Metamorphic Geology》2015,33(5):495-512
We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp3‐bonded carbon, in most cases centred between 1332 and 1330 cm?1, with a full width at half maximum between 3 and 5 cm?1. Several spectra show Raman bands typical for disordered graphitic (sp2‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO2 and CH4 in polyphase inclusions. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units. 相似文献
117.
Réka?LukácsEmail author Szabolcs?Harangi Olivier?Bachmann Marcel?Guillong Martin?Dani?ík Yannick?Buret Albrecht?von?Quadt István?Dunkl László?Fodor Jakub?Sliwinski Ildikó?Soós János?Szepesi 《Contributions to Mineralogy and Petrology》2015,170(5-6):52
A silicic ignimbrite flare-up episode occurred in the Pannonian Basin during the Miocene, coeval with the syn-extensional period in the region. It produced important correlation horizons in the regional stratigraphy; however, they lacked precise and accurate geochronology. Here, we used U–Pb (LA-ICP-MS and ID-TIMS) and (U–Th)/He dating of zircons to determine the eruption ages of the youngest stage of this volcanic activity and constrain the longevity of the magma storage in crustal reservoirs. Reliability of the U–Pb data is supported by (U–Th)/He zircon dating and magnetostratigraphic constraints. We distinguish four eruptive phases from 15.9 ± 0.3 to 14.1 ± 0.3 Ma, each of which possibly includes multiple eruptive events. Among these, at least two large volume eruptions (>10 km3) occurred at 14.8 ± 0.3 Ma (Demjén ignimbrite) and 14.1 ± 0.3 Ma (Harsány ignimbrite). The in situ U–Pb zircon dating shows wide age ranges (up to 700 kyr) in most of the crystal-poor pyroclastic units, containing few to no xenocrysts, which implies efficient recycling of antecrysts. We propose that long-lived silicic magma reservoirs, mostly kept as high-crystallinity mushes, have existed in the Pannonian Basin during the 16–14 Ma period. Small but significant differences in zircon, bulk rock and glass shard composition among units suggest the presence of spatially separated reservoirs, sometimes existing contemporaneously. Our results also better constrain the time frame of the main tectonic events that occurred in the Northern Pannonian Basin: We refined the upper temporal boundary (15 Ma) of the youngest counterclockwise block rotation and the beginning of a new deformation phase, which structurally characterized the onset of the youngest volcanic and sedimentary phase. 相似文献
118.
Zusammenfassung Bei dem Versuch, die Kristallstruktur von Bonchevit zu bestimmen, stellte sich heraus, daß dieses Mineral—bis dahin PbBi4S7—aus zwei Phasen besteht. Der Hauptanteil wurde eindeutig als Galenobismutit identifiziert. Der Rest wies nach den Gitterkonstanten (a0=13,58±0,02 Å, b0=20,51±0,07 Å, c0=4,09±0,07 Å) auf ein bisher unbekanntes Mineral hin. Die Raumgruppe ist Bbmm. Ein indiziertes Pulverdiagramm und die dazugehörigen d-Werte werden angegeben.Die Emissionsspektralanalyse zeigt Pb und Bi als Hauptkomponenten, Cu und Ag als Nebenkomponenten und Spuren von Zn und Sn. Die Strukturanalyse führte zu der Formel Me5S6, wobei die Me-Atome etwa gleich schwer sind, so daß als chemischo Formel nur Pb3Bi2S6 mit Z=4 in Frage kommt.Strukturell gehört das Mineral in die Gruppe Andorit-Ramdohrit-Fizelyit. Die Verwandtschaft bzw. Identität des Minerals mit anderen Mineralen und synthetischen Verbindungen wird diskutiert.
Mineralogical data on a sulphosalt from the Rhodope mountains, Bulgaria
Summary During an attempt to determine the crystal structure of bonchevite, this mineral was found to consist of two phases. Previously it was thought to have the composition PbBi4S7. The main constituent could unambiguously be identified as galenobismutite. For the rest the lattice constants (a0=13.58±0,02 Å, b0=20.51±0,07 Å, c0=4.09±0.07 Å), indicated a new mineral. Space group is Bbmm. An indexed powder diagram (with d-values) is given.The emission spectrographic analysis shows Pb and Bi to be main components, Cu and Ag to be minor components, and traces only of Zn and Sn. The structure analysis has led to the formula Me5S6, with Me-atoms of approximately the same atomic number; therefore, the chemical formula has to be Pb3Bi2S6, with Z=4.In a structural classification the mineral belongs to the andoriteramdohrite-fizelyite-group. The relationships to or the identity with other minerals and synthetic compounds are discussed.相似文献
119.
Dušan Němec 《Contributions to Mineralogy and Petrology》1969,20(3):235-243
The determination of the fluorine content of courmalines yielded 0.28% as an average value for schorlites and dravites and 0.97% for elbaites. The plot of the fluorine contents against the lithium contents shows that the distribution of projection points for pink or green elbaites differs from that for lithian indigolites. Tourmalines are poorer in fluorine than lightcoloured micas at the same stage of pegmatite evolution. Individual regions with pegmatite occurrences can be characterized as rich or poor in fluorine according to the fluorine contents in the tourmalines and micas contained in the pegmatites. 相似文献
120.
The Horní Slavkov–Krásno Sn–W ore district is hosted by strongly altered Variscan topaz–albite granite (Krudum granite body) on the northwestern margin of the Bohemian Massif. We studied the fluid inclusions on greisens, ore pockets, and ore veins from the Hub Stock, an apical expression of the Krudum granite. Fluid inclusions record almost continuously the post-magmatic cooling history of the granite body from ~500 to <50°C. Rarely observed highest-temperature (~500°C) highest-salinity (~30?wt.% NaCl eq.) fluid inclusions are probably the result of secondary boiling of fluids exsolved from the crystallizing magma during pressure release which followed hydraulic brecciation of the gneissic mantle above the granite cupola. The greisenization was related to near-critical low-salinity (0–7?wt.% NaCl eq.) aqueous fluids with low amount of CO2, CH4, and N2 (≤10?mol% in total) at temperatures of ~350–400°C and pressures of 300–530 bar. Crush-leach data display highly variable and negatively correlated I/Cl and Br/Cl values which are incompatible with both orthomagmatic and/or metamorphic origin of the fluid phase, but can be explained by infiltration of surficial and/or sedimentary fluids. Low fluid salinity indicates a substantial portion of meteoric waters in the fluid mixture that is in accordance with previous stable isotope data. The post-greisenization fluid activity associated with vein formation and argillitization is characterized by decreasing temperature (<350 to <50°C), decreasing pressure (down to ~50–100 bar), and mostly also decreasing salinity. 相似文献