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991.
Thomas A. Vogel Timothy P. Flood Lina C. Patino Melissa S. Wilmot Raymond Patrick R. Maximo Carmencita B. Arpa Carlo A. Arcilla James A. Stimac 《Contributions to Mineralogy and Petrology》2006,151(3):267-281
Silicic volcanic deposits (>65 wt% SiO2), which occur as domes, lavas and pyroclastic deposits, are relatively abundant in the Macolod Corridor, SW Luzon, Philippines.
At Makiling stratovolcano, silicic domes occur along the margins of the volcano and are chemically similar to the silicic
lavas that comprise part of the volcano. Pyroclastic flows are associated with the Laguna de Bay Caldera and these are chemically
distinct from the domes and lavas at Makiling stratovolcano. As a whole, samples from the Laguna de Bay Caldera contain lower
concentrations of MgO and higher concentrations of Fe2O3(t) than the samples from domes and lavas. The Laguna de Bay samples are more enriched in incompatible trace elements. The silicic
rocks from the domes, Makiling Volcano and Laguna de Bay Caldera all contain high alkalis and high K2O/Na2O ratios. Melting experiments of primitive basalts and andesites demonstrate that it is difficult to produce high K2O/Na2O silicic magmas by fractional crystallization or partial melting of a low K2O/Na2O source. However, recent melting experiments (Sisson et al., Contrib Mineral Petrol 148:635–661, 2005) demonstrate that extreme
fractional crystallization or partial melting of K-rich basalts can produce these silicic magmas. Our model for the generation
of the silicic magmas in the Macolod Corridor requires partial melting of mantle-derived, evolved, moderate to K-rich, crystallized
calc-alkaline magmas that ponded and crystallized in the mid-crust. Major and trace element variations, along with oxygen
isotopes and ages of the deposits, are consistent with this model.
Electronic Supplementary Material Supplementary material is available for this article at 相似文献
992.
Much of southern and eastern Africa is semi-arid and heavily groundwater dependent. Borehole drilling commenced over a hundred years ago with magnetic and electrical resistivity surveys for borehole siting being introduced from 1936. Formalised training of hydrogeologists led in the 1970s to an almost standard approach to hydrogeological investigation and a period of stability followed, during which some major investigations were carried out. A period of decentralisation and fragmentation has since taken place in many parts of southern and eastern Africa, and groundwater monitoring and management are inadequate in many countries. All but six of the 14 SADC (Southern African Development Community) member states reportedly have an adequate monitoring network in place. However, groundwater demand is increasing and hydrogeologists need to promote the use of appropriate methodologies as an essential part of tackling the severe issues now facing the water sector in the region. 相似文献
993.
Many Precambrian granulite-facies metamorphic complexes contain so-called straight gneisses, which are massive rocks with a clearly pronounced blastomylonitic texture, lineation, and gneissosity. These rocks occur exclusively in high-temperature ductile shear zones, which can develop either during the primary exhumation of rock complexes or during the overprinting by high-temperature dynamometamorphism. The main criterion for distinguishing between these two types of straight gneisses is the configuration of their P-T trajectories, which are recorded in the mineral assemblages in these rocks and their host gneisses. Ductile shear zones developed in Archean granulite gneisses simultaneously with their exhumation, and, hence, their P-T trajectories are segments of decompression and/or isobaric cooling paths. Straight gneisses in Proterozoic polymetamorphic complexes commonly compose high-temperature ductile shear zones overprinted on Archean granulite complexes, and the P-T paths of these rocks are Z-shaped. This means that, at a constant pressure in the middle part of the continental crust, the T min of the older P-T trajectory corresponded to T max of the younger trajectory, and often T max–T min > 100°C. Such ductile shear zones commonly have a strike-slip morphology and can be easily seen in aerial photographs and discerned during structural geological surveying. These zones can overprint older gneisses without any notable thermal effect on the latter. Relations of this type were identified in the granulite complexes of Limpopo in South Africa, Sharyzhalgai in the southwestern Baikal area, and Lapland in the Kola Peninsula. The results of our research propose a solution for the well-known problem of the significant discrepancies between the isotopic ages in high-temperature-high-pressure complexes and the partial or complete distortion of radiogenic isotopic systems under the effect of a newly inflowing metamorphic fluid. The application of geochronologic techniques to these situations is senseless, and only P-T trajectories provide insight into the actual age relations between the discrete tectono-metamorphic stages. It is thus expedient to conduct not only structural studies of metamorphic complexes but also their detailed petrological examination and the calculation of their P-T paths before geochronologic dating. 相似文献
994.
S. C. Choi Onyx W. H. Wai Thomas W. H. Choi X. D. Li C. W. Tsang 《Environmental Geology》2006,51(3):455-461
Partitioning of heavy metals (Cd, Cr, Cu, Pb, Zn) in marine sediments collected from various sites in Hong Kong waters were
determined using sequential extraction method. Sediments from Kellette Bank, located in Victoria Harbour, had higher metal
concentrations especially Cu and Zn than most other sites. Slightly over 20% of total Cu and Cr existed as readily available
forms in Peng Chau and Kellette Bank. At most sampling sites, over 15% of the Cu existed as the exchangeable form indicating
that Cu could be readily released into the aqueous phase from sediments. A significantly higher percentage of Pb and Zn was
associated with the three non-residual fractions. Hence, there is a greater environmental concern for remobilization of Pb
and Zn compared with Cr. The high amount of residual Cd (>50%) and the relatively lower Cd content indicate that little environmental
concern is warranted for the remobilization of Cd. Distribution of metals in sediments collected from different depth at Kellette
Bank shows that metal concentrations decreased with profile depth. The levels of Pb and Zn associated with the two readily
available fractions increased sharply in the surface sediment. These metals represented the pollutants, which were introduced
into the area in the mid-eighties through early nineties as a result of rapid economic and industrial development in the territory.
As significant portions of these metals were bound to the readily available phases in the surface sediments, metal remobilization
could be a concern.
An erratum to this article can be found at 相似文献
995.
C. E. Runge A. Kubo B. Kiefer Y. Meng V. B. Prakapenka G. Shen R. J. Cava T. S. Duffy 《Physics and Chemistry of Minerals》2006,33(10):699-709
The equation of state of MgGeO3 perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V 0) of 182.2 ± 0.3 Å3 and bulk modulus (K 0) of 229 ± 3 GPa, with the pressure derivative (K′0 = (?K 0/?P) T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V 0 = 180.2 Å3, K 0 = 221.3 GPa, and K′0 = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO3 post-perovskite phase near the observed phase transition pressure (~65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO3 phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO3 system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates. 相似文献
996.
D. C. Smith 《Mineralogy and Petrology》2006,88(1-2):87-122
Summary The stoichiometry of pyroxenes {viiiX2+
viY2+
ivZ4+
2 O6} and garnets {xiiX2+
3
viY3+
2
ivZ4+
3 O12} is re-evaluated by a theoretical crystal-chemical approach that takes into account natural phenomena that do not fit with
conventional anhydrous stoichiometric mineralogy: the existence in eclogites of microinclusions of other minerals that may
have been exsolved from previous supersilicic or subsilicic UHPM pyroxene or garnet. Different definitions of supersilicic
and subsilicic are discussed and the one based on the ability to exsolve SiO2 and leave behind a stoichiometric pyroxene or garnet is recommended for general adoption. The SHAND system (S = Si et al.; H = H; A = Al et al.; N = Na et al.; D = divalents)
for projecting multivariate chemical space involving 23 cations and 104 selected natural or potential mineral species on to
two essential diagrams (SAND and SHND) is described in full for the first time. Numerous possible chemical exchanges are considered
and justified with respect to known mineral phenomena such as cation vacancies, octahedral silicon or protonation. Several
new potential end-members are presented, in particular “supersilipyx”, “supersiligar” and “subsiligar”. It is suggested that
small quantities of these end-members can be incorporated into UHPM solid-solutions and lead to various exsolution phenomena
during eclogite exhumation. 相似文献
997.
Conceptual hydrodynamic model of the Pamukkale hydrothermal field, southwestern Turkey, based on hydrochemical and isotopic data 总被引:4,自引:1,他引:4
Cüneyt Dilsiz 《Hydrogeology Journal》2006,14(4):562-572
The results of study on the hydrochemical and isotope characteristics of shallow and deep waters at Pamukkale hydrothermal
field Turkey are described in order to obtain a better understanding of the hydrological circulation. The field can be grouped
into two groundwater sub-systems; cold water springs of Ca–HCO3 type (10–12 °C), and CO2-rich thermal waters of Ca–HCO3–SO4 type (25–58 °C). The occurrence of these water types is closely related to the morphology of the region, where intense tectonism
formed horst and graben structures. Hence, two hydrogeological systems were defined: a deep geothermal system which is related
to extensive and deep circulation of meteoric water in the regional flow system, and a shallow system which is related to
local groundwater flow through sedimentary strata. The meteoric water falling at higher elevations percolates to the local
groundwater system at a shallow level and flows to the deep geothermal system. During a deep convection cycle from a recharge
to discharge area, the cold water attains heat from the asthenospheric intrusions, causing it to ascend. Variations of chemical
and isotopic composition of thermal waters result from their mixing with cool groundwater in a shallow aquifer during their
ascent to the surface.
Résumé Les résultats d'une étude portant sur les caractéristiques hydrochimiques et isotopiques de puits phréatiques et profonds situés dans le champ hydrothermal de Pamukkale, sont décrits de telle manière à éclairer le fonctionnement des circulations hydrologiques. Le champ peut étre divisé en deux sous-systèmes d'eaux souterraines, l'un avec des eaux de sources froides (10–12 °C) de type Ca–HCO3, et les eaux thermales (25–58 °C) riches en CO2 et de type Ca–HCO3–SO4. L'occurrence de ces types d'eaux est fermement liée à la morphologie de la région, oùne tectonique intense a engendré des structures en horsts et en grabens. Dés lors deux systèmes hydrogéologiques ont été définis : un système profond, qui est lié à la circulation extensive et profonde des eaux météoritiques dans le système régional d'écoulement, et un système phréatique lié aux écoulements locaux des eaux souterraines à travers les strates sédimentaires. Les eaux météoritiques aux altitudes élevées, percolent jusqu'aux systèmes locaux phréatiques, puis coulent jusqu'aux systèmes géothermaux plus profonds. Durant le cycle de convection profond des zones de recharge jusqu'aux zones de décharge, l'eau froide atteint les zones chaudes liées aux intrusions athenosphériques, provoquant la remontée. Les variations de la composition chimique et isotopique des eaux thermales résultent dans leurs mélanges avec des eaux souterraines froides dans les aquifères phréatiques durant leur remontée jusqu'à la surface.
Resumen Se describen los resultados del estudio de las características isotópicas e hidroquímicas de las aguas someras y profundas para obtener un mejor entendimiento de la circulación hidrológica del campo hidrotermal Pamukkale. El campo puede agruparse en dos sub-sistemas de agua subterránea: manantiales de agua fría del tipo Ca–HCO3 (10–12°C) y aguas termales ricas en CO2 del tipo Ca–HCO3–SO4(25–58°C). El ambiente de estos tipos de aguas se relaciona estrechamente con la morfología de la región donde el tectonismo intenso ha formado estructuras extensionales tipo graben y horst. Se definieron dos sistemas hidrogeológicos: un sistema geotermal profundo que se relaciona con la circulación profunda y extensa de agua meteórica en el sistema regional de flujo y un sistema somero el cual se relaciona con flujo local de agua subterránea a través de estratos sedimentarios. El agua meteórica que cae en altas elevaciones percola al sistema local de agua subterránea en un nivel somero y fluye hacia el sistema geotermal profundo. Durante un ciclo de convección del área de recarga hacia la zona de descarga, el agua fría se calienta a partir de los intrusivos astenosféricos lo que ocasiona que asciendan. Como resultado de la mezcla de las aguas recalentadas, con agua subterránea fría en un acuífero somero durante el ascenso hacia la superficie, se derivan variaciones en la composición química e isotópica de las aguas termales.相似文献
998.
Tenerife basically consists of three Miocene shield volcanoes, the Anaga, the Teno and Central shield, as well as the Pliocene Cañadas volcano. The temporal evolution and structural significance of each volcano with respect to the history of Tenerife is still a matter of debate. We present paleomagnetic results in order to enhance the view of the volcanic history of the Teno volcano by means of magnetostratigraphy. It is found that the initial subaerial phase shows reverse magnetizations throughout. After two major sector collapses, dominantly normally magnetized lavas extruded. Comparisons of observed magnetic polarities with the geomagnetic polarity timescale show that these volcanic activities occurred within 0.4 Myr between 6.3 and 5.9 Ma. Significantly younger flows, ~ 5.3 Myr old according to their radiometric age, revealed again normal polarity throughout. The absence of inversely magnetized lavas in-between the two normal periods indicates a volcanic hiatus or erosional phase. The evolutionary sequence and the estimated high production rates for the initial building phase are similar as would be expected for a hotspot volcano. The average geomagnetic field for 6.0 ± 0.2 Ma is close to an axial dipole field showing a slight far-sided/right-handed effect. The field strength, determined by Thellier-type intensity determinations, corresponds to a virtual axial dipole moment of 4.9 × 1022 A m2. This value is approximately half of the present day field strength, but similar to values obtained for the mid-Miocene. It also corresponds to the proposed tertiary low-field level of the geomagnetic dipole moment. 相似文献
999.
C. Albarrán-Liso M. M. Jordán-Vidal T. Sanfeliu-Montolio M. J. Liso-Rubio 《Environmental Geology》2006,49(7):1043-1050
The necessity of eliminating debris from a granite quarry has awakened an interest in applications of by-products, called
“marginal arids”, in different fields, like construction and foundations for roadways, restoration, material for the manufacture
of artificial rocks, and artesian products etc. Conclusions obtained from the results of tests carried out by X-ray diffraction
of granite quarry by-products in Extremadura, Spain, submitted to different treatments, are established. Test pieces from
two quarries are analyzed and compared generally and specifically, for commercial use. Finally, conclusions relating to essays
in test pieces and mineral dynamics of marginal arid granite are exposed. 相似文献
1000.
Neetu Agnihotri P. Chittibabu Indu Jain P. C. Sinha A. D. Rao S. K. Dube 《Natural Hazards》2006,39(1):83-101
The paper describes a two-dimensional bay–river coupled numerical model for storm surges along the Andhra coast of India.
The effect of the Krishna and Godavari rivers on the surge development is analysed. A comparative study of the surge generated
by a tropical cyclone with and without the inclusion of rivers is done in detail. Three cyclones that struck the Andhra coast
in November 1977, May 1990 and November 1996 were used for the simulation studies. It is found that the idealized model without
a river overestimates the sea-level elevation as compared to a more realistic bay–river coupled model. The temporal variation
of surge values at the mouth of the rivers is also studied for all three cyclone cases. It is found that the effect of the
presence of rivers depends on the strength of the cyclone, its point of landfall and the location of the rivers with respect
to the landfall point. 相似文献