Influence of m-cresol purple indicator additions on the pH of seawater samples: correction factors evaluated from a chemical speciation model

The perturbation of the indicator m-cresol purple on the pH in seawater is illustrated in diagrams, representing measurements in 1-cm and 5-cm cells. The diagrams apply to a measured pH interval of 7.4–8.4 using a 2-mM stock solution of m-cresol purple sodium salt dissolved in seawater. The magnitude of the perturbation is described as correction values, i.e., the change in seawater pH caused by the indicator. The diagrams are based on calculations made by using the equilibrium speciation programme, MARINHALT. From these calculations, and least squares fitting methods, pH correction values are described in terms of the pH difference between each seawater sample and the pH of an indicator stock solution. Calculations are performed for a typical high latitude water and a north Pacific deep water. Diagrams are presented for a salinity of 35 and a temperature of 15°C. Responses to salinities between 32 and 36 and temperatures 15–25°C are illustrated as well. A ±0.05 pH difference between a seawater sample and an indicator stock solution gives a correction of less than 0.001 pH unit for a 1-cm cell. For a 5-cm cell, pH differences between the indicator stock solution and a seawater sample as large as ±0.3 cause corrections smaller than ±0.001 pH unit. Calculations demonstrate that the five-fold lower indicator concentration used with 5-cm cells decreases the perturbation effect by approximately a factor of five relative to 1-cm cells.     

A Holocene record of climate change,fire ecology and human activity from montane Flat Top Bog,Maui

A sediment core from a high-elevation bog on Maui in the Hawaiian Islands contains evidence for drier conditions between 9.4–5.8 kyr BP, followed by a wetter interval between 5.8–2.2 kyr BP, and a variable late Holocene. These precipitation changes may be a reflection of vertical displacements of the upper boundary of the mid-Pacific Trade Wind Inversion (TWI) cloud layer. Fires, probably volcanically ignited, occurred in the forests prior to human arrival. Polynesian activity in this high-elevation, remote site was apparently limited, with no pollen, charcoal, or sedimentological evidence for local anthropogenic disturbance. After European contact, grass fires increased and introduced plant species invaded the site. Values for Cd, Cu, Pb, and Zn in sediments throughout the Holocene indicate low trace-metal deposition from atmospheric particulates at the site, even in the twentieth century.This paper is one of a series of papers guest edited by Dr. Mark Brenner on tropical paleolimnology     

Geochemical processes in a Mediterranean Lake: a high-resolution study of the last 4,000 years in Zoñar Lake,southern Spain

High-resolution geochemical analysis of a 6-m-long sediment core from Zoñar Lake, southern Spain, provides a detailed characterization of major changes in lake and watershed processes during the last 4,000 years. Geochemical variables were used as paleolimnological indicators and complement Zoñar Lakes’s paleoenvironmental reconstruction based on sedimentological and biological proxies, which define periods of increasing allochthonous input to the lake and periods of dominant autochthonous sedimentation. Chemical ratios identify periods of endogenic carbonate formation (higher Ca/Al, Sr/Al and Ba/Al ratios), evaporite precipitation (higher S/Al, Sr/Al ratios), and anoxic conditions (higher Mo/Al, U/Th ratios and Eu anomaly). Higher productivity is marked by elevated organic carbon content and carbonate precipitation (Mg/Ca). Hydrological reconstruction for Zoñar Lake was based on sedimentological, mineralogical and biological proxies, and shows that lower lake levels are characterized by Sr-rich sediments (a brackish lake with aragonite) and S-rich sediments (a saline lake with gypsum), while higher lake levels are characterized by sediments enriched in elements associated with alumino-silicates (Al, K, Ti, Fe, trace and rare earth elements), reflecting fresher conditions. Geochemical indicators also mark periods of higher detrital input to the lake related to human activity in the watershed: (1) during the Iberian Roman Humid Period (650 BC–AD 300), around the onset of the Little Ice Age (AD 1400), during the relatively drier Post-Roman and Middle Ages (AD 800–1400), and over the last 50 years, due to mechanized farming practices. Heavy metal enrichment in the sediments (Cu and Ni) suggests intensification of human activities during the Iberian Roman Period, and the use of fertilizers during the last 50 years.     

Relationships between Holocene sea-level variations,trophic development,and climatic change in Negra Lagoon,Southern Uruguay

Paleolimnological data are presented on trophic development, climatic change and sea level variations in Negra Lagoon, a 142 km² coastal lagoon in southern Uruguay. Using a sediment core that extended to the early Holocene, analyses of organic matter, carbonate, diatoms and opal phytoliths allowed us to track changes in trophic state and paleosalinity levels, which were closely related to Holocene sea level variation, temperature and humidity. Diatom Association Zones (DAZ) corresponding to transgressive events were dominated by marine/brackish taxa and relatively low organic matter values, while those DAZ corresponding to regressive events showed increases in brackish/freshwater diatoms and organic matter. Opal Phytoliths Association Zones (OPAZ) also were identified, temperature and humidity indices were calculated, and climatic trends were inferred. During the middle Holocene (i.e., ~5000–4000 yr BP), cool–dry climatic conditions were established. After ~4000 yr BP, a transition from cool to warm–humid conditions was observed, but fully warm humid conditions established only after ~1700 yr BP. Such climatic amelioration led to increases in trophic state.     

Performance‐based design using structural optimization

A new methodology for seismic design is proposed based on structural optimization with performance‐based constraints. Performance‐based criteria are introduced for the seismic design of new buildings. These criteria are derived from the National Guidelines for Seismic Rehabilitation of Buildings (Reference [19], Federal Emergency Management Agency (FEMA), ‘NHERP Guidelines for seismic rehabilitation of buildings’, Report Nos 273 and 274, Washington, DC, 1997) for retrofitting existing structures. The proposed design methodology takes into account the non‐linear behaviour of the structure. The goal is to incorporate in the design the actual performance levels of the structure, i.e. how much reserve capacity the structure has in an earthquake of a given magnitude. The optimal design of the structure minimizes the structural cost subjected to performance constraints on plastic rotations of beams and columns, as well as behavioural constraints for reinforced concrete frames. Uncertainties in the structural period and in the earthquake excitation are taken into account using convex models. The optimization routine incorporates a non‐linear analysis program and the procedure is automated. The proposed methodology leads to a structural design for which the levels of reliability (performance levels) are assumed to be quantifiable. Furthermore, the entire behaviour of the structure well into the non‐linear range is investigated in the design process. Copyright © 2000 John Wiley & Sons, Ltd.     

Strain properties of shelf grounds in the area of the Yurii Korchagin Field,North Caspian Sea

Marine disperse grounds from the shelf of the North Caspian Sea were studied using various test methods. The strain modulus and the coefficient of transverse strain were specified by triaxial compression and compression tests. Empirical correlations were found for the strain modulus as a result of both tests for different types of grounds.     

Accretion tectonics and crustal structure in Alaska

The entire width of the North American Cordillera in Alaska is made up of “suspect terranes”. Pre-Late Cretaceous paleogeography is poorly constrained and the ultimate origins of the many fragments which make up the state are unclear. The Prince William and Chugach terranes accreted since Late Cretaceous time and represent the collapse of much of the northeast Pacific Ocean swept into what today is southern Alaska. Greater Wrangellia, a composite terrane now dispersed into fragments scattered from Idaho to southern Alaska, apparently accreted into Alaska in Late Cretaceous time crushing an enormous deep-marine flysch basin on its inboard side. Most of interior eastern Alaska is the Yukon Tanana terrane, a very large entirely fault-bounded metamorphic-plutonic assemblage covering thousands of square kilometers in Canada as well as Alaska. The original stratigraphy and relationship to North America of the Yukon-Tanana terrane are both obscure. A collapsed Mesozoic flysch basin, similar to the one inboard of Wrangellia, lies along the northern margin. Much of Arctic Alaska was apparently a vast expanse of upper Paleozoic to Early Mesozoic deep marine sediments and mafic volcanic and plutonic rocks now scattered widely as large telescoped sheets and Klippen thrust over the Ruby geanticline and the Brooks Range, and probably underlying the Yukon-Koyukuk basin and the Yukon flats. The Brooks Range itself is a stack of north vergent nappes, the telescoping of which began in Early Cretaceous time. Despite compelling evidence for thousands of kilometers of relative displacement between the accreted terranes, and large amounts of telescoping, translation, and rotation since accretion, the resulting new continental crust added to North America in Alaska carries few obvious signatures that allow application of currently popular simple plate tectonic models. Intraplate telescoping and strike-slip translations, delamination at mid-crustal levels, and large-scale lithospheric wedging were important processes in northern Cordilleran tectonic evolution.     

A New Approach for Scientific Data Dissemination in Developing Countries: A Case of Indonesia

This short paper is a progress report on our experiences in Indonesia of collecting, integrating and disseminating both global and local scientific data across the country through the web. Our recent efforts are concentrated on improving local public access to global scientific data, and encouraging local scientific data to be more accessible for global communities. We have maintained a well-connected infrastructure and web-based information management systems to realize these objectives. This paper is especially focused on introducing the ARSIP system for mirroring global data and sharing local scientific data, and the newly developed Indonesian Scientific Index for integrating local scientific data through an automated intelligent indexing system.     

Fracturing and fluid‐flow during post‐rift subsidence in carbonates of the Jandaíra Formation,Potiguar Basin,NE Brazil

Pervasive fracture networks are common in many reservoir‐scale carbonate bodies even in the absence of large deformation and exert a major impact on their mechanical and flow behaviour. The Upper Cretaceous Jandaíra Formation is a few hundred meters thick succession of shallow water carbonates deposited during the early post‐rift stage of the Potiguar rift (NE Brazil). The Jandaíra Formation in the present onshore domain experienced <1.5 km thermal subsidence and, following Tertiary exhumation, forms outcrops over an area of >1000 km². The carbonates have a gentle, <5?, dip to the NE and are affected by few regional, low displacement faults or folds. Despite their simple tectonic history, carbonates display ubiquitous open fractures, sub‐vertical veins, and sub‐vertical as well as sub‐horizontal stylolites. Combining structural analysis, drone imaging, isotope studies and mathematical modelling, we reconstruct the fracturing history of the Jandaíra Formation during and following subsidence and analyse the impact fractures had on coeval fluid flow. We find that Jandaíra carbonates, fully cemented after early diagenesis, experienced negligible deformation during the first few hundreds of meters of subsidence but were pervasively fractured when they reached depths >400–500 m. Deformation was accommodated by a dense network of sub‐vertical mode I and hybrid fractures associated with sub‐vertical stylolites developed in a stress field characterised by a sub‐horizontal σ₁ and sub‐vertical σ₂. The development of a network of hybrid fractures, rarely reported in the literature, activated the circulation of waters charged in the mountainous region, flowing along the porous Açu sandstone underlying the Jandaíra carbonates and rising to the surface through the fractured carbonates. With persisting subsidence, carbonates reached depths of 800–900 m entering a depth interval characterised by a sub‐vertical σ₁. At this stage, sub‐horizontal stylolites developed liberating calcite which sealed the sub‐vertical open fractures transforming them in veins and preventing further flow. During Tertiary exhumation, several of the pre‐existing veins and stylolites opened and became longer, and new fractures were created typically with the same directions of the older features. The simplicity of our model suggests that most rocks in passive margin settings might have followed a similar evolution and thus display similar structures.