Geological, mineralogical and geochemical characteristics of the Radzimowice Au–As–Cu deposit from the Kaczawa Mountains (Western Sudetes, Poland): an example of the transition of porphyry and epithermal style

The sheeted quartz–sulfide veins of the Radzimowice Au–As–Cu deposit in the Kaczawa Mountains are related to Upper Carboniferous post-collisional potassic magmatism of the composite Zelezniak porphyry intrusion. Multiple intrusive activity ranges from early calc-alkaline to sub-alkaline and alkaline rocks and is followed by multiple hydrothermal events. Early crustally derived dacitic magma has low mg# (<63) and very low concentrations of mantle-compatible trace elements, high large-ion lithophile elements (LILE), moderate light rare-earth elements (LREE), and low high-field-strength elements (HFSE). Later phases of more alkaline rocks have higher mg# (60–70), and LILE, LREE, and HFSE characteristics that indicate mafic magma contributions in a felsic magma chamber. The last episode of the magmatic evolution is represented by lamprophyre dikes which pre-date ore mineralization and are spatially related to quartz–sulfide–carbonate veins. The dikes consist of kersantite and spessartite of calc-alkaline affinity with K₂O/Na₂O ratios of 1.1–1.9, mg# of 77–79, and high abundances of mantle-compatible trace elements such as Cr, Ni, and V. They have high LILE, low LREE, and low HFSE contents suggesting a subduction-related post-collisional arc-setting. The mineralization started with arsenopyrite that was strongly brecciated and overprinted by multiple quartz–carbonate phases associated with base-metal sulfides and Au–Ag–Bi–Te–Pb±S minerals. The sulfur isotope composition of sulfides ranges from –1.1 to 2.8 ³⁴S and suggests a magmatic source. At least two generations of gold deposition are recognized: (1) early refractory, and (2) subsequent non-refractory gold mineralization of epithermal style. Co-rich arsenopyrite with refractory gold and pyrite are the most abundant minerals of the early stage of sulfide precipitation. Early arsenopyrite formed at 535–345°C along the arsenopyrite–pyrrhotite–loellingite buffer and late arsenopyrite crystallized below 370°C along the arsenopyrite–pyrite buffer. Non-refractory gold associated with base-metal sulfides and with Bi–Te–Ag–Pb–S mineral assemblages has an average fineness of about 685, and is represented by electrum of two generations, and minor maldonite (Au₂Bi). Fluid inclusions from various quartz generations co-genetic with base-metal sulfides and associated with carbonates, tellurides and non-refractory gold indicate fluids with moderate salinity (9–15 wt% NaCl equiv.) and a temperature and pressure drop from 350 to 190°C and 1.2 to 0.8 kbar, respectively. According to the result of the sulfur isotope fractionation geothermometer the temperature of base-metal crystallization was in the range from 322 to 289°C. Preliminary results of oxygen isotope studies of quartz from veins indicate a gradual increase in the proportion of meteoric water in the epithermal stage. The gold to silver ratio in ore samples with >3 ppm Au is about 1:5 (geometric mean). Hydrothermal alteration started with sericitization, pyritization, and kaolinitization in vein selvages followed by alkaline hydrothermal alteration of propylitic character (illitization and chloritization), albitization and carbonatization. The mineralization of the Radzimowice deposit is considered as related to alkaline magmatism and is characterized by the superposition of low-sulfidation epithermal mineralization on higher-temperature and deeper-seated mesothermal/porphyry style.Editorial handling: B. Lehmann     

Linear mechanism of generation and intencification of internal gravity waves in the ionosphere at their interaction with a nonuniform zonal wind: 1. Model of the medium and initial dynamic equations

The specific features of the generation and intensification of internal gravity wave structures in different atmospheric-ionospheric regions, caused by zonal local nonuniform winds (shear flows), are studied. The model of the medium has been explained and an initial closed system of equations has been obtained in order to study the linear and nonlinear dynamics of internal gravity waves (IGWs) when they interact with the geomagnetic field in a dissipative ionosphere (for the D, E, and F regions).     

Refinement of the modified time-to-failure method for intermediate-term earthquake prediction

The modified time-to-failure method for intermediate-term earthquake prediction utilizes empirical relationships to reduce the number of unknown parameters providing a stable and unique solution set. The only unknown parameters in the modified time-to-failure method are the time and size of the impending main shock. The modified time-to-failure equation is used to model the precursory events and a prediction contour diagram is constructed with the magnitude and time-of-failure as the axes of the diagram. The root-mean-square (rms) is calculated for each set of time and magnitude on the prediction diagram representing the difference between the model (calculated) acceleration and the actual accelerated energy release of the precursory events. A small region, corresponding to the low rms region on the diagram, defines the prediction. The prediction has been shown to consistently under-estimate the magnitude and over-estimate the time-of-failure. These shortcomings are caused by an underestimation in energy release of the modified time-to-failure equation at the very end of the sequence. An empirical correction can be applied to the predicted results to minimize this problem. A main shock location search technique has been developed for use with the modified time-to-failure method. The location technique is used to systematically search an earthquake catalog and identify locations corresponding to precursory sequences that display accelerated energy releases. It has shown good results when applied in retrospective predictions, and is essential for the practical application of the modified time-to-failure method. In addition, an observed linear characteristic in long-term energy release can be used to minimize false predictions. The refined empirical relationships that eliminate or constrain unknown constants used in the modified time-to-failure method and the main shock location search technique are used in a practical application in the New Madrid Seismic Zone (NMSZ). The NMSZ, which is over due for a magnitude 6 event according to recurrence rates (Johnston and Nava, 1985), makes this region ideal for testing the method. One location was identified in the NMSZ as a high risk area for an event in the magnitude 4.5 range. The prediction, if accurate, is of scientific interest only because of the relatively small size of the main shock.     

Deposition of trace substances via cloud interception on a coniferous forest at Kleiner Feldberg

A resistance model to calculate the deposition of cloud droplets on a coniferous forest and some improved parameterizations of the indispensable input parameters are described. The deposition model is adapted to the coniferous forest at the Kleiner Feldberg site and verified by the data of a drip water monitoring station below the forest canopy. The measurements of liqud water content, wind speed and trace substance compounds in cloud water of the Ground-based Cloud Experiment (GCE) at Kleiner Feldberg in 1990 are used to calculate the cloud water deposition fluxes and the deposition of trace substances via cloud water interception. The calculated deposition of trace substances via cloud water interceptions is three to six times higher than via rain during the experiment. On a long term data basis the yearly amount of cloud water deposition is 180 mm year^–1 at Kleiner Feldberg site (840 m a.s.l.) while the precipitation amount is 1030 mm year^–1. Due to higher trace substance concentrations in cloud water compared to rain the ionic deposition via cloud water interception and via precipitation were assessed to be of comparable magnitude.     

Oceanic versus island arc origin of ophiolites

The silica content of basaltic rocks is an unreliable variable with which to distinguish ultramafic-mafic complexes developed at ocean ridges from those potentially formed beneath volcanic island arcs. Data from Appalachian ophiolites supports the view that silica metasomatism is responsible for the high silica content of supposed calc-alkaline basaltic rocks found in ophiolites such as Troodos, and that the high-silica (70 wt.%) leucocratic rocks associated with ophiolites are of tholeiitic rather than calc-alkaline parentage. The use of titanium as a discriminant of tectonic environment is also suspect because the titanium content of basalts associated with Appalachian ophiolites as well as those recently recovered from the Atlantic ocean floor ranges from values even lower than those typical of island arc tholeiites to values typical of abyssal tholeiites. However, the internal stratigraphy of ophiolites in both the Appalachian and Tethyan systems can only be explained on the basis of the postulate that ophiolites originate at oceanic spreading centres rather than beneath island arcs.     

Solar rotation, 1966–1978

Photospheric and chromospheric spectroscopic Doppler rotation rates for the full solar disk are analyzed for the period July, 1966 to July, 1978. An approximately linear secular increase of the equatorial rate of 3.7% for these 12 years is found (in confirmation of Howard, 1976). The high latitude rates above 65 ° appear to vary with a peak-to-peak amplitude of 8%, or more, phased to the sunspot cycle such that the most rapid rotation occurs at, or following, solar maximum. The chromosphere, as indicated by H, has continued to rotate on the average 3% faster than the photosphere agreeing with past observations. Sources of error are discussed and evaluated.Operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

Nature and significance of the Neoproterozoic Sturtian–Marinoan Boundary,Northern Adelaide Geosyncline,South Australia

The Cryogenian succession of the Northern Flinders Ranges reveals a complex sedimentary record between the Sturtian and Marinoan glacial deposits. A major unconformity separates the Sturtian and Marinoan-aged sedimentary successions in the area. This forms a subaerial erosion surface with terrestrial and marginal marine infill directly above the Angepena and Balcanoona Formations in their respective localities. This exposure surface is here correlated with the previously documented submarine unconformity between the Yankaninna Formation and the underlying deep marine Tapley Hill Formation. This erosional event provides a chronostratigraphic marker horizon that coincides approximately with thepreviously defined Sturtian–Marinoan Time Series boundary in the Northern Flinders Ranges. These stratigraphic relationships also constrain lateral facies relationships between the Oodnaminta ReefComplex (Balcanoona Formation) and the Angepena Formation. Similarly, the shallow-water Weetootla Dolomite is correlated with the deeper water carbonates of the Yankaninna Formation.