The effect of chemical composition and oxygen fugacity on the electrical conductivity of dry and hydrous garnet at high temperatures and pressures

The in situ electrical conductivity of hydrous garnet samples (Py₂₀Alm₇₆Grs₄–Py₇₃Alm₁₄Grs₁₃) was determined at pressures of 1.0–4.0 GPa and temperatures of 873–1273 K in the YJ-3000t apparatus using a Solartron-1260 impedance/gain-phase analyzer for various chemical compositions and oxygen fugacities. The oxygen fugacity was controlled by five solid-state oxygen buffers (Fe₂O₃ + Fe₃O₄, Ni + NiO, Fe + Fe₃O₄, Fe + FeO, and Mo + MoO₂). Experimental results indicate that within a frequency range from 10⁻² to 10⁶ Hz, electrical conductivity is strongly dependent on signal frequency. Electrical conductivity shows an Arrhenius increase with temperature. At 2.0 GPa, the electrical conductivity of anhydrous garnet single crystals with various chemical compositions (Py₂₀Alm₇₆Grs₄, Py₃₀Alm₆₇Grs₃, Py₅₆Alm₄₃Grs₁, and Py₇₃Alm₁₄Grs₁₃) decreases with increasing pyrope component (Py). With increasing oxygen fugacity, the electrical conductivity of dry Py₇₃Alm₁₄Grs₁₃ garnet single crystal shows an increase, whereas that of a hydrous sample with 465 ppm water shows a decrease, both following a power law (exponents of 0.061 and −0.071, respectively). With increasing pressure, the electrical conductivity of this hydrous garnet increases, along with the pre-exponential factors, and the activation energy and activation volume of hydrous samples are 0.7731 ± 0.0041 eV and −1.4 ± 0.15 cm³/mol, respectively. The results show that small hopping polarons ( \textFe_\textMg ^· ) \left( {{\text{Fe}}_{\text{Mg}}^{ \cdot } } \right) and protons ( \textH ^· {\text{H}}^{ \cdot } ) are the dominant conduction mechanisms for dry and wet garnet single crystals, respectively. Based on these results and the effective medium theory, we established the electrical conductivity of an eclogite model with different mineral contents at high temperatures and high pressures, thereby providing constraints on the inversion of field magnetotelluric sounding results in future studies.     

砂岩储层中原生孔隙的破坏与保存机制研究进展

埋藏条件下原生孔隙的破坏与保存机制是含油气盆地砂岩储层质量研究的一个核心领域,其在油气地质学研究中的意义不言而喻。与次生孔隙的形成与保存机制相比,影响原生孔隙破坏与保存的因素有着其特殊的复杂性和多样性。在总结国内外研究进展的基础上,试图深入理解不同成岩机制在砂岩储层原生孔隙破坏与保存中的意义和作用,包括破坏机制（如机械压实、胶结作用等）和保存机制（如地层超压、颗粒包膜、盐体侵位和烃类占位等）。目前难以实现砂岩储层质量钻前准确预测的一个困难在于无法明确原生孔隙演化的动力和过程,将来成岩作用、流体作用、沉积过程和盆地演化的更紧密结合可能是解决砂岩储层原生孔隙破坏与保存机制研究中最有希望的发展方向之一。     

Evaluating climate change adaptation efforts on the US 50 states’ hazard mitigation plans

Climate change brings uncertain risks of climate-related natural hazards. The US Federal Emergency Management Agency (FEMA in Climate change: long-term trends and their implications for emergency management, 2011. https://www.fema.gov/pdf/about/programs/oppa/climate_change_paper.pdf) has issued a policy directive to integrate climate change adaptation actions into hazard mitigation programs, policies, and plans. However, to date there has been no comprehensive empirical study to examine the extent to which climate change issues are integrated into state hazard mitigation plans (SHMPs). This study develops 18 indicators to examine the extent of climate change considerations in the 50 SHMPs. The results demonstrate that these SHMPs treat climate change issues in an uneven fashion, with large variations present among the 50 states. The overall plan quality for climate change considerations was sustained at an intermediate level with regard to climate change-related awareness, analysis, and actions. The findings confirm that climate change concepts and historic extreme events have been well recognized by the majority of SHMPs. Even though they are not specific to climate change, mitigation and adaptation strategies that can help reduce climate change risks have been adopted in these plans. However, the plans still lack a detailed assessment of climate change and more incentives for collaboration strategies beyond working with emergency management agencies.     

Assessment of trace metals contamination in stream sediments and soils in Abuja leather mining,southwestern Nigeria

This study is aimed at determining the level of environmental degradation as well as the concentration of trace elements in soil and stream sediments in order to evaluate the environmental impact of the mining operation. Twenty-five (25) soils and ten (10) stream sediment samples were collected from the study area. The physicochemical parameters were determined using appropriate instrumentation with the aid of a digital pH meter (Milwaukee meter) to measure the pH and electrical conductivity, total dissolved solids, moisture content and loss on ignition of the soil and stream sediment samples. The pH of the soil sample ranged from (6.10 to 7.19); Electrical conductivity ranged from (21.3 to 279.4 µS/cm), moisture content varied from (0.60% to 7.20%), and the LOI ranged from (2.03% to 18.62%). The results of the analysis showed that the concentrations of the trace elements in the soils and stream sediment samples were slightly higher than the background values. Plots of the trace elements in stream sediment samples show moderate, consistent decrease downstream except at points where there was mine water discharge into the main river. The pollution levels of heavy metals were examined in stream sediment and soil samples using different assessable indices, such as the enrichment factor, which showed significant-moderate enrichment for Cr, Th, Nb, Zn, Pb, Y and Zr and the geo-accumulation index, which showed practically moderate contamination with Cr, Ni and Sr based on regional background reference values. Geo-accumulation index and contamination index for soils and stream sediment revealed uncontaminated to moderate contamination. Likewise, elements with moderate contamination were Cr, Ni and Sr. The Pearson correlation showed that there were significant positive associations among selected metals in soil and stream sediment samples.     

Development of efficiently coupled thermo-hydro-mechanical model to predict hydraulic fracture morphology in heavy oil reservoirs

The aim of the study involves examining the effect of heavy oil viscosity on fracture geometry in detail by establishing a heavy oil fracturing model and conventional fracturing model based on thermal–hydraulic–mechanical (THM) coupled theory, Walther viscosity model, and K–D–R temperature model. We consider viscosity and density within the heavy oil fracturing model as functions of pressure and temperature while that as constants within the conventional fracturing model. A heavy oil production well is set as an example to analyze the differences between the two models to account for the thermo-poro-elastic effect. The results show that temperature exhibits the most significant influence on the heavy oil viscosity while the influence of pressure is the least. In addition, a cooling area with a width of 0–1 m and varied length is generated near the fracture. The heavy oil viscosity increases sharply in this area, thereby indicating an area of viscosity increment. The heavy oil viscosity increases faster and is closer to wellbore, and a high viscosity increment reduces the mobility of the heavy oil and prevents the fracturing fluid from entering into the reservoir. The special viscosity distribution results in significant differences in pore pressure, oil saturation, and changing trends between these two models. In the heavy oil reservoir fracturing model, the thermal effect completely exceeds the influence of pore elasticity, and the values of the fracture length, width, and static pressure exceed those calculated in the conventional fracturing model. Thus, a comparison of the measured values indicates that the results obtained by considering viscosity as a function of temperature and pressure are more accurate. Therefore, the results of this study are expected to provide good guidelines for the design of heavy oil fracturing.     

Discovery of the early Jurassic Gajia mélange in the Bangong–Nujiang suture zone: Southward subduction of the Bangong–Nujiang Ocean?

International Journal of Earth Sciences - Mélange records a series of geological processes associated with oceanic subduction and continental collision. This paper reports for the first time...     

Lithofacies paleogeography mapping and reservoir prediction in tight sandstone strata: A case study from central Sichuan Basin,China

Sand-rich tight sandstone reservoirs are potential areas for oil and gas exploration. However, the high ratio of sandstone thickness to that of the strata in the formation poses many challenges and uncertainties to traditional lithofacies paleogeography mapping. Therefore, the prediction of reservoir sweet spots has remained problematic in the field of petroleum exploration. This study provides new insight into resolving this problem, based on the analyses of depositional characteristics of a typical modern sand-rich formation in a shallow braided river delta of the central Sichuan Basin, China. The varieties of sand-rich strata in the braided river delta environment include primary braided channels, secondary distributary channels and the distribution of sediments is controlled by the successive superposed strata deposited in paleogeomorphic valleys. The primary distributary channels have stronger hydrodynamic forces with higher proportions of coarse sand deposits than the secondary distributary channels. Therefore, lithofacies paleogeography mapping is controlled by the geomorphology, valley locations, and the migration of channels. We reconstructed the paleogeomorphology and valley systems that existed prior to the deposition of the Xujiahe Formation. Following this, rock-electro identification model for coarse skeletal sand bodies was constructed based on coring data. The results suggest that skeletal sand bodies in primary distributary channels occur mainly in the valleys and low-lying areas, whereas secondary distributary channels and fine deposits generally occur in the highland areas. The thickness distribution of skeletal sand bodies and lithofacies paleogeography map indicate a positive correlation in primary distributary channels and reservoir thickness. A significant correlation exists between different sedimentary facies and petrophysical properties. In addition, the degree of reservoir development in different sedimentary facies indicates that the mapping method reliably predicts the distribution of sweet spots. The application and understanding of the mapping method provide a reference for exploring tight sandstone reservoirs on a regional basis.     

Optimization of concurrent mining and reclamation plans for single coal seam: a case study in northern Anhui, China

The extraction of underground ore body inevitably causes a large amount of land subsidence. Current reclamation technologies in China mainly focus on stable subsided land, which means most of the affected lands are submerged into water because of the high groundwater table in some areas, leading to the loss of soils and inefficient reclamation. Therefore, a new technology for reclaiming unstable subsiding land is being studied for restoring farmland as much as possible, based on a case study in northern Anhui, China. In consideration of the mining plan, subsidence processes in various stages were analyzed and some related factors such as vertical subsidence, post-mining slope, water area, and land use condition were also simulated. Due to mining activities, useful farmland has gradually decreased to merely 14.4 % of the pre-mining area. In this study, the following stages were modeled from pre-mining to post-mining: (1) percentage of farmland was 100 % in stage (a) (pre-mining), (2) 72.5 % in stage (b), (3) 67.3 % in stage (c), and (4) 14.4 % in stage (d) (post-mining). The results show that 86.6 % of cultivated land was submerged into water and lost its capacity for cultivation after coal mining. Reclamation plans for stages (b), (c), and (d) were made by a traditional reclamation method called “Digging Deep to Fill Shallow”. Based on scenario simulation of reclamation, the farmland reclamation percentages were improved to 78.3, 73.3, and 40.70 %, respectively. Taking the percentage of reclaimed farmland as the preferred standard, concurrent mining and reclamation for stage (b) and (c) could increase farmland reclamation percentages to 37.6 and 32.6 %, respectively, compared with the farmland reclamation percentage of post-mining [reclaiming the land in stage (d)]. The results reveal that optimum reclamation time should be at stage (b). Therefore, under current technical conditions, concurrent mining and reclamation could enhance the quantity of cultivated land and provide better land protection and food security in the mined areas with high groundwater table.     

Laboratory investigation of hydraulic fracture propagation using real-time ultrasonic measurement in shale formations with random natural fractures

The significance of natural fractures in unconventional shale hydrocarbon formations has opened new research frontiers in hydraulic fracturing. Among many of its unique contributions to gas production, the interaction between natural fractures and hydraulic fractures has long been experimentally and computationally investigated. Here, we experimentally investigated the evolution of the fracturing network with a self-developed ultrasonic testing system. Laboratory experiments are proposed to study the propagation of hydraulic fracture in naturally fractured model blocks that contain random micro-fractures. Our analysis suggests that the total fracture width obtained by ultrasonic pulse velocity (UPV) can reflect the dynamic evolution of the fracturing network. The nonlinear fracturing network evolution process is closely related to the variation of the total fracture width. It is suggested from the total fracture width that the maximum fracture network can be realized with greater natural fracture density, large injection rate, and smaller stress ratio. The study presents a better insight into the response of random naturally fractured shale formation under hydraulic fracturing treatment by analyzing the variation of UPV in real time.     

δ18O and δ13C in fossil shells of Radix sp. from the sediment succession of a dammed palaeo‐lake in the Yarlung Tsangpo valley,Tibet, China

A series of confirmed and suspected dammed palaeo‐lake sedimentary successions is scattered within the middle Yarlung Tsangpo valley in Tibet. However, the chronology, the genesis of the dam and its location, the water level of the dammed lake, the process of dam failure and the spatiotemporal relationships between the sedimentary successions remain controversial. Here, we focus on one sedimentary succession of the suspected dammed palaeo‐lake at Xigazê. We measured the grain‐size distribution, magnetic susceptibility, organic and inorganic carbon content, and δ¹³C_org and δ¹⁵N_total ratios of the sediments. In addition, we measured the δ¹⁸O_shell and δ¹³C_shell values of modern and fossil Radix sp. shells, and the δ¹⁸O_water and δ¹³C_DIC values of the ambient water with different hydrological regimes. The results indicate that the δ¹⁸O_shell values of modern Radix sp. and the δ¹⁸O_water of the ambient water body significantly depend on its hydrological status. In addition, a strong positive relationship was observed between δ¹⁸O_shell values of modern Radix sp. shells and the δ¹⁸O_water of the ambient water on the Tibetan Plateau. According to this correlation, the δ¹⁸O_water values of the palaeo‐water body are reconstructed using the δ¹⁸O_shell values of Radix sp. fossil shells in the Xigazê section. Further, based on the δ¹⁸O_shell values of fossil Radix sp., the reconstructed δ¹⁸O_water of the palaeo‐water body and the specific habitats of Radix sp., we infer that the sedimentary succession in the Xigazê broad valley was mainly formed within the backwater terminal zone of a dammed palaeo‐lake and that the elevation of the water level of the lake was approximately 3811 m a.s.l. AMS ¹⁴C dating indicates that the deposits of the dammed palaeo‐lake were formed at about 33–22 cal. ka BP. Finally, the presence of Radix sp. fossil shells within the Xigazê section suggests that Radix sp. survived the late Last Glacial Period on the Tibetan Plateau.