Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).     

Generic 3D interpolation of Holocene base‐level rise and provision of accommodation space,developed for the Netherlands coastal plain and infilled palaeovalleys

We present an interpolation model that describes Holocene groundwater level rise and the creation of accommodation space in 3D in the Rhine‐Meuse delta – the Netherlands. The model area (ca. 12 400 km²) covers two palaeovalleys of Late Pleistocene age (each 30 km wide) and the overlying Holocene deposits of the Rhine‐Meuse delta, the Holland coastal plain, and the Zuiderzee former lagoon. Water table rise is modelled from 10 800 to 1000 cal. BP, making use of age‐depth relations based on 384 basal peat index points, and producing output in the form of stacked palaeo groundwater surfaces, groundwater age‐depth curves, and voxel sets. These products allow to resolve (i) regional change and variations of inland water table slopes, (ii) spatial differences in the timing and pacing of transgression, and (iii) analysis of interplay of coastal, fluvial and subsidence controls on the provision of accommodation space. The interpolation model is a multi‐parameter trend function, to which a 3D‐kriging procedure of the residuals is added. This split design deploys a generic approach for modelling provision of accommodation space in deltas and coastal lowlands, aiming to work both in areas of intermediate data availability and in the most data‐rich environments. Major provision of accommodation space occurred from 8500 cal BP onwards, but a different evolution occurred in each of the two palaeovalleys. In the northern valley, creation of accommodation space began to stall at 7500 cal BP, while in the southern valley provision of new accommodation space in considerable quantities continued longer. The latter is due to the floodplain gradient that was maintained by the Rhine, which distinguishes the fluvial deltaic environment from the rest of the back‐barrier coastal plain. The interpolation results allow advanced mapping and investigation of apparent spatial differences in Holocene aggradation in larger coastal sedimentary systems. Furthermore, they provide a means to generate first‐order age information with centennial precision for 3D geological subsurface models of Holocene deltas and valley fills. As such, the interpolation is of use in studies into past and present land subsidence and into low land sedimentation.     

Reconciling Multiple Societal Objectives in Cross-Scale Marine Governance: Solomon Islands’ Engagement in the Coral Triangle Initiative

Environmental governance aims to reconcile an expanding set of societal objectives at ever-larger scales despite the challenges that remain in integrating conservation and development at smaller scales. We interrogate Solomon Islands’ engagement in the Coral Triangle Initiative on Coral Reefs, Fisheries and Food Security to contribute new insight on the scalar politics of multi-level marine governance. We show how regional objectives are re-interpreted and prioritized as they translate into national policy and practice. Our data suggest that enhanced coordination of finances and activities, integration of objectives in shared protocols and priority geographies, and a subtle shift in power relations between the state, donors, and implementation partners have resulted from processes of re-scaling. We discuss important procedural adjustments in cross-level and cross-scale governance across jurisdictional, institutional, and sectoral scales. We also reflect on the changing role of national governments in shifts toward large-scale, multi-national initiatives.     

Kinematics of quasars and AGN

The VLBA has been used over a period of four years to study the internal motions within a sample of quasars and AGN. In most sources, features appear to propagate away from the central engine along a well collimated radio jet with apparent transverse velocities between zero and 10c, with some evidence for apparent accelerations and decelerations. The distribution of apparent velocity is not consistent with any simple ballistic model and appears to require either a spread in intrinsic velocity or a difference between the bulk velocity and pattern velocity. The dependence of apparent angular velocity with redshift is consistent with standard Friedmann world models. Further observations of a larger source sample, especially at large redshift may lead to meaningful constraints on world models.     

Comments on EPA Guidance for Ground Water Studies

"The panel provided good, solid, interdisciplinary advice on a variety of challenging, state-of-the-art issues."     

Europeans Test Pesticide Models

This column focuses on recent work in Europe. The intent is to present to American readers relevant studies they would not normally see. Much of the following was presented at the 9th International Congress of Pesticide Chemistry last summer in London. The congress was jointly sponsored by the International Union of Pure & Applied Chemistry and the Royal Society of Chemistry.     

Comparison of vegetation and stream sediment geochemical patterns in northeastern New South Wales

This study compares the geochemical response of stream sediments and adjacent vegetation samples, with variations in drainage catchment lithology and the occurrence of mineralisation, within a 14,000-km² block of the northeastern region of New South Wales, Australia. The area contains a range of lithologies within a Devonian–Permian accretionary complex and Mesozoic sedimentary basin, as well as a wide range of mineral deposits. Sampling was designed to confine each sub-catchment to a single lithological group (mafic and ultramafic rocks, acid intrusives, volcanics, metasedimentary and sedimentary rocks or alluvium). Leaves of over 20 genera, dominated by (Allo-)Casuarina, Eucalyptus, Acacia, Callistemon and Melaleuca, and the <250-μm fraction of the stream sediments were analysed by INAA. The uptake of most trace elements varied between genera, with Callistemon displaying the highest median As and La contents and Eucalyptus the highest Co contents. The stream sediment and vegetation geochemistry reflect both hydromorphic and mechanical dispersion within sub-catchments, with regional patterns dominant over local influences. The vegetation appears to be influenced to a greater extent by hydromorphic dispersion, as indicated by differences in the ratio of leaf to sediment Cr concentrations in sub-catchments draining serpentinites and basalts. Although most known mineral deposits in the region produced anomalies in at least one medium, there was little correlation between the trace element concentrations of the vegetation and stream sediments on a site-by-site basis. A number of Au targets were only detected on the basis of the biogeochemistry and others were only reflected in the stream sediment geochemistry. In general, vegetation displayed more extensive dispersion trains away from mineralisation than did the stream sediments. Differences in the response of the two sampling media suggest their joint use in exploration or environmental surveys to maximise the probability of detecting mineralisation.     

Characteristics of magnetic and non-magnetic lag in the Cobar area, NSW

Geochemical patterns from two lag anomalies in the Cobar region of central New South Wales are described. The region is semi-arid, deeply weathered and some areas are covered by variable thicknesses of aeolian and alluvial transported overburden.Lag morphology and mineralogy are related to landform. In erosional landforms the surface is covered by lag, which is composed of coarse fragments derived locally from bedrock and displays varying degrees of ferruginization, together with a range of secondary pisoids. In depositional landforms the lag is less abundant and contains more pisoids. Deflation by sheetwash may lead to lag being partially buried by alluvium. In a large proportion of pisoid lag, hematite and goethite have been converted to maghemite, allowing ready separation into magnetic and non-magnetic fractions. The non-magnetic fraction is dominated by the lithic lag whereas the magnetic fraction is dominated by pisoid lag.The magnetic and non-magnetic components of the 2–11 mm lag fraction, milled to < 75 μm and subjected to HF-HNO₃-HClO₄ attack, give rise to distinct geochemical patterns at targets related to a variant of the Cobar style of Pb-Zn mineralization with variable silicification and to Zn mineralization in a swarm of quartz and carbonate veinlets. The patterns are influenced by metal source, lag type, surface chemical conditions and landtbrm. Differences in the correlation between metal contents in the magnetic and non-magnetic lag components, and between trace elements and Fe. indicate variable loss of Cu and Zn from the magnetic lag at some targets but retention of Pb. The presence of a readily cxtractable base metal component in the lag has implications for detecting anomalies in transported cover in the region.