Occurrence of hydroxylated polychlorinated biphenyls in the brain of cetaceans stranded along the Japanese coast

Levels of hydroxylated polychlorinated biphenyls (OH-PCBs) and PCBs were measured in the brain of melon-headed whales (MW: Peponocephala electra), striped dolphins (SD: Stenella coeruleoalba) and finless porpoises (FP: Neophocaena phocaenoides) stranded along the Japanese coast during 2002-2003. Levels of OH-PCBs (including identified and unknown OH-P(5)CB, -H(6)CB, -H(7)CB and O(8)CB congeners) in the brain of MW, SD and FP were in the range of 20-290, 21-330 and 170-240pg/g wet wt., respectively. Observed OH-PCB levels were 2-3 orders of magnitude lower than PCBs in the same individuals. OH-PCBs/PCBs ratios in MW, SD and FP brain were lower than those in blood of humans and wildlife and in the brain of polar bears reported previously. OH-PCBs were also detected in maternal and fetal brain of SD (1 pair), suggesting transfer of OH-PCBs into the fetal brain of odontocete cetaceans. When fetus/dam concentration ratios of OH-PCB congeners detected in maternal and fetal brain were estimated, the values were higher than those of PCB congeners, implying that OH-PCBs in maternal blood could be more easily transferred into fetal brain via placenta than PCBs.     

Nutrient and Phytoplankton Dynamics in Harima-Nada, Eastern Seto Inland Sea, Japan During a 35-Year Period from 1973 to 2007

Long-term monitoring of water quality and phytoplankton was conducted at 19 sampling stations in Harima-Nada, eastern Seto Inland Sea, Japan for 35 years from 1973 to 2007. There were two significant long-term changes, an increase in winter water temperatures of 0.042°C year^?1, and a decrease in dissolved inorganic nitrogen (DIN) from about 10 μM in the 1970s to ~5 μM in the late 1990s due to the reduction in nutrient inputs. DIN concentrations and total phytoplankton cell density were both higher during the 1970s to the early 1980s and then exhibited a significant decrease in the mid 1980s and remained relatively constant thereafter. Diatoms were the dominant phytoplankton group (>90%) over the 35-year period, and there was a dramatic shift from Skeletonema dominance (~70%) to Chaetoceros in the mid 1980s. This shift in diatom species may be attributed to differences in the life cycle of Skeletonema and Chaetoceros and the response to the decrease in DIN concentration.     

Characteristics and climatic sensitivities of runoff from a cold‐type glacier on the Tibetan Plateau

Model calculations are made in order to understand the characteristics and response to climate change of runoff from a cold glacier on the Tibetan Plateau. Some 20% of meltwater is preserved at the snow–ice boundary due to refreezing, since the glaciers in mid to northern Tibet are sufficiently cooled during the previous winter. Sensitivity to alterations in meteorological parameters has revealed that a change in air temperature would cause not only an increase in melting by sensible heat, but also a drastic increase in melting due to lowering of the albedo, since some of the snowfall changes to rainfall. In addition, it was suggested that a decrease in precipitation would cause a lowering of the surface albedo, with a resulting increase in the contribution of glacier runoff to the total runoff of river water. This study shows the first quantitative evaluation of the above effects, though they have been suggested qualitatively. The seasonal sensitivity of glacier runoff was examined by changing the dates given for a meteorological perturbation for a period of only 5 days. It was revealed that changes in both air temperature and precipitation during the melting season strongly affected glacier runoff by changing the surface albedo, though these perturbations only slightly altered the annual averages. Copyright © 2006 John Wiley & Sons, Ltd.     

Neoproterozoic mafic-ultramafic layered intrusion in Quruqtagh of northeastern Tarim Block,NW China: Two phases of mafic igneous activity with different mantle sources

In this paper we report zircon U–Pb age, chemical compositions of rock-forming minerals, and whole-rock elemental and Sr–Nd isotopic data for the No. II mafic-ultramafic intrusive complex (N2MC) in the Quruqtagh area at the northeastern margin of the Tarim Block, northwestern China to evaluate its petrogenesis and tectonic significance. The N2MC with an exposure area of ca. 12 km² has a funnel-shaped cross-section and intruded the Paleoproterozoic basement. U–Pb zircon dating gives a crystallization age of 760 ± 6 Ma. Rock types of the N2MC include lherzolite, pyroxenite, gabbro and minor diorite. Major elements geochemistry of these rocks exhibits a tholeiitic trend with a wide range of SiO₂ contents (38.8–60 wt.%). On the other hand, they are systematically enriched in LILE, LREE and depleted in HFSE and HREE, thus leading to low HFSE/LREE ratios (e.g., Nb/La ≈ 0.3). Isotopically, the studied rocks are characterized by negative whole-rock εNd(t) values (? 7.6 to ? 2.8) and variable high (⁸⁷Sr/⁸⁶Sr)_i (0.7095–0.7059). These features, together with chemical compositions of the rock-forming minerals and the presence of the primary phlogopite and hornblende, suggest that N2MC was likely formed via crystal fractionation/cumulation (with negligible crustal contamination) of a tholeiitic magma derived from a metasomatized subcontinental lithosphere mantle (SCLM) in an extensional environment. The enrichment of the mantle source could be ascribed to the metasomatism by subducted-slab-released fluids before partial melting. Overall, reported Neoproterozoic igneous rocks throughout the Tarim Block constitute two major phases of Neoproterozoic igneous activities, i.e., ca. 825–800 Ma and ca. 780–745 Ma, respectively. Similar to that of many other Rodinian continents, this feature is interpreted to be related to the two phases of Neoproterozoic mantle plume activity under the Rodinia. Furthermore, there exist two types of mafic-ultramafic complex at Quruqtagh, i.e., the ca. 820 Ma carbonatite-bearing and the ca. 760 Ma tholeiitic, which could reflect the presence of two different mantle sources.     

A physically based distributed subsurface–surface flow dynamics model for forested mountainous catchments

This study was designed to develop a physically based hydrological model to describe the hydrological processes within forested mountainous river basins. The model describes the relationships between hydrological fluxes and catchment characteristics that are influenced by topography and land cover. Hydrological processes representative of temperate basins in steep terrain that are incorporated in the model include intercepted rainfall, evaporation, transpiration, infiltration into macropores, partitioning between preferential flow and soil matrix flow, percolation, capillary rise, surface flow (saturation‐excess and return flow), subsurface flow (preferential subsurface flow and baseflow) and spatial water‐table dynamics. The soil–vegetation–atmosphere transfer scheme used was the single‐layer Penman–Monteith model, although a two‐layer model was also provided. The catchment characteristics include topography (elevation, topographic indices), slope and contributing area, where a digital elevation model provided flow direction on the steepest gradient flow path. The hydrological fluxes and catchment characteristics are modelled based on the variable source‐area concept, which defines the dynamics of the watershed response. Flow generated on land for each sub‐basin is routed to the river channel by a kinematic wave model. In the river channel, the combined flows from sub‐basins are routed by the Muskingum–Cunge model to the river outlet; these comprise inputs to the river downstream. The model was applied to the Hikimi river basin in Japan. Spatial decadal values of the normalized difference vegetation index and leaf area index were used for the yearly simulations. Results were satisfactory, as indicated by model efficiency criteria, and analysis showed that the rainfall input is not representative of the orographic lifting induced rainfall in the mountainous Hikimi river basin. Also, a simple representation of the effects of preferential flow within the soil matrix flow has a slight significance for soil moisture status, but is insignificant for river flow estimations. Copyright © 2005 John Wiley & Sons, Ltd.     

Near-Infrared Colors of the Binary Kuiper Belt Object 1998 WW 31

We have measured near-infrared colorsof the binary Kuiper Belt object (KBO)1998 WW₃₁ using the Subaru Telescope withadaptive optics. The satellite was detectednear its perigee and apogee(0.18“ and 1.2” apart from the primary).The primary and the satellite have similar H–Kcolors, while the satellite is redder thanthe primary in J–H. Combined with the Rband magnitude previously published byVeillet et al., 2002, the color of the primaryis consistent with that of optically red KBOs. Thesatellite's R-, J-, H-colors suggest thepresence of ～1 μm absorption band dueto rock-forming minerals. If the surface of thesatellite is mainly composed by olivine, thesatellite's albedo is higher value than the canonicallyassumed value of 4%.