Electron density distribution of FeTiO<Subscript>3</Subscript> ilmenite under high pressure analyzed by MEM using single crystal diffraction intensities

Many of ilmenites ABO₃ compounds bearing transition elements have semiconductive, ferroelectric and antiferromagnetic properties. The high-pressure diffraction studies of FeTiO₃ have been conducted up to 8.2 GPa using synchrotron radiation in KEK at Tsukuba with diamond anvil cell. The compression mechanism of FeTiO₃ ilmenite has been investigated by the structure refinements converged to the reliable factors R = 0.05. The deformations of the FeO₆ and TiO₆ octahedra were reduced with increasing pressure. In order to elucidate the electric conductivity change with pressure, electron density distribution of ilmenite have been executed by maximum entropy method (MEM) using single-crystal diffraction intensity data. MEM based on F _obs(hkl) of FeTiO₃ clearly shows electron density in comparison with the difference Fourier synthesis based on F _obs(hkl) − F _calc(hkl). The radial distribution of the electron density indicates electron localization around the cation positions. The bonding electron density found in bond Fe–O and Ti–O is lowered with pressure. The isotropic temperature factors B _iso become smaller with increasing pressure. Nevertheless the thermal vibration is considerably restrained by the compression, the electric conductivity is enhanced with pressure. Neither charge transfer nor electron hopping between Fe and Ti along the c axis in FeTiO₃ is plausible under high pressure. But the electric conductivity due to electron super-exchange in Fe–Fe and Ti–Ti has been clarified by the MEM electron density distribution. The anisotropy in the electric conductivity has been clarified.     

Borehole water and hydrologic model around the Nojima fault, SW Japan

The active fault drilling at Nojima Hirabayashi after the 1995 Hyogoken-nanbu (Kobe) earthquake (M_JMA = 7.2) provides us with a unique opportunity to investigate subsurface fault structure and the in-situ properties of fault and fluid. The borehole intersected the fault gouge of the Nojima fault at a depth interval of 623 m to 625 m. The lithology is mostly Cretaceous granodiorite with some porphyry dikes.The fault core is highly permeable due to fracturing. The borehole water was sampled in 1996 and 2000 from the depth interval between 630 and 650 m, just below the fault core. The chemical and isotopic compositions were analyzed. Carbon and oxygen isotope ratios of carbonates from the fault core were analyzed to estimate the origin of fluid.The following conclusions were obtained. (1) The ionic and isotopic compositions of borehole water did not change from 1996 to 2000. They are mostly derived from local ground water as mentioned by Sato and Takahashi [Sato, T., Takahashi, M., 2000. Chemical and isotopic compositions of groundwater obtained from the Hirabayashi well. Geological Survey of Japan Interim Report No. EQ/00/1, 187–192.]. (2) Geochemical speciation revealed that the borehole water was derived from a relatively deep reservoir, which may be situated at a depth of 3 to 4 km where the temperature is about 80–90 °C. (3) The shallower part of the Nojima fault (shallower than the reservoir depth) has not been healed from the hydrological viewpoints 5 years after the event, in contrast to the rapid healing detected by S wave splitting [Tadokoro, K., Ando, M., 2002. Evidence for rapid fault healing derived from temporal changes in S wave splitting, Geophys. Res. Lett., 29, 10.1029/2001GL013644.]. (4) Precipitation of calcite from the present borehole water since drilling supports the idea of precipitation of some calcite in coseismic hydraulic fractures in the fault core [Boullier, A-M., Fujimoto, K., Ohtani, T., Roman-Ross, G., Lewin, E., Ito, H., Pezard, P., Ildefonse, B., 2004. Textural evidence for recent co-seismic circulation of fluids in the Nojima fault zone, Awaji Island, Japan., Tectonophysics, 378, 165–181.]. (5) Carbon and oxygen isotope ratios of calcite indicated that the meteoric water flux had been localized at the fault core. (6) A difference in the carbon isotope ratio between the footwall and the hanging wall suggests that the fault has been acted as a hydrologic barrier, although the permeability along the fault is still high.     

Fault configuration produced by initial arc rifting in the Parece Vela Basin as deduced from seismic reflection data

Abstract   The Parece Vela Basin (PVB), which is a currently inactive back-arc basin of the Philippine Sea Plate, was formed by separation between the Izu-Ogasawara Arc (IOA) and the Kyushu-Palau Ridge (KPR). Elucidating the marks of the past back-arc opening and rifting is important for investigation of its crustal structure. To image its fault configurations and crustal deformation, pre-stack depth migration to multichannel seismic reflection was applied and data obtained by the Japan Agency for Marine-Earth Science and Technology and Metal Mining Agency of Japan and Japan National Oil Corporation (Japan Oil, Gas and Metals National Corporation). Salient results for the pre-stack depth-migrated sections are: (i) deep reflectors exist around the eastern margin of KPR and at the western margin of IOA down to 8 km depth; and (ii) normal fault zones distributed at the eastern margin of the KPR (Fault zone A) and the western margin of the IOA (Fault zone B) have a total displacement of greater than 500 m associated with synrift sediments. Additional normal faults (Fault zone C) exist 20 km east of the Fault zone B. They are covered with sediment, which indicates deposition of recent volcanic products in the IOA. According to those results: (i) the fault displacement of more than 500 m with respect to initial rifting was approximately asymmetric at 25 Ma based on PSDM profiles; and (ii) the faults had reactivated after 23 Ma, based on the age of deformed sediments obtained from past ocean drillings. The age of the base sediments corresponds to those of spreading and rotation after rifting in the PVB. Fault zone C is covered with thick and not deformed volcanogenic sediments from the IOA, which suggests that the fault is inactive.     

On the relation between the solar activity cycle and the solar tidal force induced by the planets

The cross-correlation coefficient (t) of the solar tidal force induced by the planets f(x + t) with the sunspot number g(x) during a period of 44 years is about -0.7 when t is about -2 years. This fact will be useful for predicting solar activity. The solar tidal force was calculated from 1928 to 1971 for every degree on the equatorial plane and every time every planet moves one degree. As the solar tidal force, we used the moving annual average by months of the square of the vertical tidal force on the sun, and as the sunspot number we used the Zürich mean annual sunspot number.     

Magnetic field and current sheets in the corona above active regions

A new method for the calculation of coronal magnetic field is proposed and it is shown to reproduce the EUV features in the corona as observed by Skylab experiments satisfactorily well. One of the remarkable points is that it reproduces the loopy threads in the active region corona and also the large scale field lines connecting active regions. The existence of coronal current is expected wherever the present coronal-current-free model fails to represent the feature. A method of calculating the coronal sheet-current is also developed with the purpose of knowing the shape of the current sheet and the amount of magnetic stress energy stored due the the presence of it by comparing the calculated field configuration with the observed local distortion of the EUV threads. This may be used in pinning down the possible site of the flare and in discussing the flare occurrence in terms of the energy stored there.During the preparation of this work, Poletto et al. (1975) calculated the magnetic field shape in Schmidt's method to compare with the soft X-ray feature obtained by Skylab.     

Status of butyltin pollution along the coasts of western Japan in 2001, 11 years after partial restrictions on the usage of tributyltin

Restrictions on the use of tributyltin (TBT) in aquaculture and on boats in coastal regions, except for ocean-going vessels, have been in place in Japan since 1990 due to the strong toxic effects of TBT on marine organisms. However, TBT pollution along the Japanese coasts has been reported after this legislation was enacted. In order to elucidate the present status of contamination by butyltin (BT) compounds, we measured the levels of BTs [monobutyltin (MBT), dibutyltin (DBT) and TBT] in seawater and Caprella spp. samples obtained from the western part of Seto Inland Sea, Uwa Sea and Uranouchi Bay in western Japan during March to September, 2001. Butyltins were detected in more than 90% of the seawater samples (n = 59), with average concentrations of 8.2 ± 9.2 (SD) ng MBT L⁻¹, 3.3 ± 3.0 ng DBT L⁻¹ and 9.0 ± 7.0 ng TBT L⁻¹. Among 41 stations situated on coastal lines, a sufficient number of Caprella organisms for chemical analysis could be collected from only 16 stations. The butyltin concentrations in seawater and Caprella samples from Uwa Sea and Uranouchi Bay, in which the dominant industry in both waters is aquaculture, showed significantly higher than or no significant differences from those samples from the western part of Seto Inland Sea, a major heavy-industry area in Japan. As the TBT concentration in seawater increased, the number of Caprella organisms collected decreased. The mean TBT concentration among the seawater samples was above the estimated lowest observable effect concentration (LOEC) that reduces the survival rate of Caprella danilevskii. Thus, the present study indicates that TBT is still a potential ecological hazard to the survival of marine invertebrates inhabiting coasts along western Japan, even 11 years after the partial ban on TBT usage was implemented.     

DECADAL CLIMATE VARIABILITY OF RAINFALL AROUND THE MIDDLE AND LOWER REACHES OF THE YANGTZE RIVER AND ATMOSPHERIC CIRCULATION

1 INTRODUCTION Summer climate plays an especially important role in the people’s daily life around East Asia, one of the most populated regions in the world, for most of the regions receive more than 70% of the annual precipitation in summer due to the effect of monsoon climate. Global climate change caused by mankind activities have become a hot topic in recent years, though it is still not clear how these activities result in the climate change around East Asia. Successive studies (Qi…     

Recent increase of DIC in the western North Pacific

The temporal variation of the total dissolved inorganic carbon (DIC) content in the western North Pacific is investigated by comparing the DIC distribution obtained from the data sets of three different periods, the GEOSECS data observed in 1973, the CO₂ dynamics Cruise data observed in 1982, and recent Japanese data sets observed during the early 1990s. The overall feature of the signal of temporal DIC change during 1973 and early 1990s agreed with that of former studies, and did not significantly change with the calculation scheme (the grid-selection method vs. the multiple regression method). The observed increase in DIC among the different time scales showed a good inner consistency, which also indicates the stability of the method used in the DIC change calculation. The apparent rate of increase of the DIC inventory in the upper 1000 m water column, however, differed significantly by the data set used for the calculation: It was 5.6±2.4 g C/m²/year, based on the data comparison between 1982 and the early 1990s, while it became 7.6±2.4 g C/m²/year when based on the data between 1973 and the early 1990s. This result provides us an information about the data-dependency on the former estimation of temporal DIC change.     

Nutrient and carbon removal ratios and fluxes in the Ross Sea, Antarctica

Net community production (NCP) and nutrient deficits (Def(X)) were calculated using decreases in dissolved CO₂ and nutrient concentrations due to biological removal in the upper 200 m of the water column during four cruises in the Ross Sea, Antarctica along 76°30′S in 1996 and 1997. A comparison to excess dissolved and particulate organic carbon showed close agreement between surplus total organic carbon (TOC) and NCP during bloom initiation and productivity maximum; however, when TOC values had returned to low wintertime values NCP was still significantly above zero. This seasonal NCP, 3.9±1 mol C m⁻², must be equivalent to the particle export to depths greater than 200 m over the whole productive season. We estimate that the annual export was 55±22% of the seasonal maximum in NCP. The fraction of the seasonal maximum NCP that is exported through 200 m is significantly higher than that measured by moored sediment traps at a depth of 206 m. The removal of carbon, nitrate and phosphate (based on nutrient disappearance since early spring) and their ratios showed significant differences between regions dominated by diatoms and regions dominated by the haptophyte Phaeocystis antarctica. While the ΔC/ΔN removal ratio was similar (7.8±0.2 for diatoms and 7.2±0.1 for P. antarctica), the ΔN/ΔP and ΔC/ΔP removal ratios for diatoms (10.1±0.3 and 80.5±2.3) were significantly smaller than those of P. antarctica (18.6±0.4 and 134.0±4.7). The similarity in ΔC/ΔN removal ratios of the two assemblages suggests that preferential uptake of phosphate by diatoms caused the dramatic differences in ΔC/ΔP and ΔN/ΔP removal ratios. In contrast to low ΔC/ΔP and ΔN/ΔP removal ratio in diatom-dominated areas early in the growing season, deficit N/P and C/P ratios in late autumn indicate that the elemental stochiometry of exported organic matter did not deviate significantly from traditional Redfield ratios. Changes in biologically utilized nutrient and carbon ratios over the course of the growing season indicated either a substantial remineralization of phosphate or a decrease in phosphate removal relative to carbon and total inorganic nitrogen over the bloom period. The species dependence in C/P ratios, and the relative constancy in the C/N ratios, makes N a better proxy of biological utilization of CO₂.