碘化氨除锡后封闭酸溶-电感耦合等离子体质谱测定锡矿石中的共生和伴生元素

锡矿石是难分解的矿物,主要存在形式是锡石(SnO_2),且共生和伴生元素多,常用的酸溶方法几乎不能溶解SnO_2,从而给锡矿石中的共生与伴生元素的准确测定带来困难。本文基于碘化氨在较低温度下熔融可产生无水状态的碘化氢,利用碘化氢的酸性和氨的还原性分解SnO_2,使Sn呈SnI_4升华分离的原理处理锡矿石。实验中以高纯铂丝作催化剂,加入碘化铵在450℃的马弗炉中分解锡矿石30 min,使得Sn以SnI_4形式挥发,除锡率达到98%以上,再用2 mL氢氟酸和1 mL硝酸封闭溶解残渣,电感耦合等离子体质谱测定钴镍铜铌钽钍铀等24个共生和伴生元素。元素检出限在0. 001～2. 9μg/g之间,90%以上元素的相对标准偏差(RSD)小于5%,相对误差小于10%。本方法解决了锡矿石难分解的问题,可测定共存金属元素,也适合测定Sn含量在1. 27%～62. 49%之间的锡矿石中的微量和痕量元素及锡精矿中的微量元素。     

Origin of complex zoning in olivine from diverse,diamondiferous kimberlites and tectonic settings: Ekati (Canada), Alto Paranaiba (Brazil) and Kaalvallei (South Africa)

Olivine in kimberlites can provide unique insights into magma petrogenesis, because it is the most abundant xenocrystic phase and a stable magmatic product over most of the liquid line of descent. In this study we examined the petrography and chemistry of olivine in kimberlites from different tectonic settings, including the Slave craton, Canada (Ekati: Grizzly, Koala), the Brasilia mobile belt (Limpeza-18, Tres Ranchos-04), and the Kaapvaal craton, South Africa (Kaalvallei: Samada, New Robinson). Olivine cores display a wide range of compositions (e.g., Mg# = 78–95). The similarity in olivine composition, resorption of core zones and inclusions of mantle-derived phases, indicates that most olivine cores originated from the disaggregation of mantle peridotites, including kimberlite-metasomatised lithologies (i.e. sheared lherzolites and megacrysts). Olivine rims typically show a restricted range of Mg#, with decreasing Ni and increasing Mn and Ca contents, a characteristic of kimberlitic olivine worldwide. The rims host inclusions of groundmass minerals, which implies crystallisation just before and/or during emplacement. There is a direct correlation between olivine rim composition and groundmass mineralogy, whereby high Mg/Fe rims are associated with carbonate-rich kimberlites, and lower Mg/Fe rims are correlated with increased phlogopite and Fe-bearing oxide mineral abundances. There are no differences in olivine composition between explosive (Grizzly) and hypabyssal (Koala) kimberlites. Olivine in kimberlites also displays transitional zones and less common internal zones, between cores and rims. The diffuse transitional zones exhibit intermediate compositions between cores and rims, attributed to partial re-equilibration of xenocrystic cores with the ascending kimberlite melt. In contrast, internal zones form discrete layers with resorbed margins and restricted Mg# values, but variable Ni, Mn and Ca concentrations, which indicates a discrete crystallization event from precursor kimberlite melts at mantle depths. Overall, olivine exhibits broadly analogous zoning in kimberlites worldwide. Variable compositions for individual zones relate to different parental melt compositions rather than variations in tectonic setting or emplacement mechanism.

     

An agent-based evacuation model for the 2011 Brisbane City-scale riverine flood

In this study, an agent-based model is proposed in order to provide new insights into the policy analysis and strategy assessment of city-scale evacuation management. The proposed model is suitable for assessment of the influence of different departure times and communications among peer evacuees on the number of residents at risk who arrive at official shelters. A case study is applied to build a simulation model for the coastal city of Brisbane in Australia. The Brisbane River catchment experiences regular flooding almost every year; the second severest flood since the twentieth century occurred in 2011. During that event, over 15,000 properties were inundated and around 3600 households evacuated in metropolitan Brisbane alone. Making use of high-performance computing clusters, the evacuation simulation was coupled with results from a validated hydrodynamic model to test a variety of escaping scenarios based on the 2011 flood situation. This case study demonstrates the proposed model’s capacity to represent the dynamic evacuation process and also shows that the model is able to help develop flood emergency plans and evaluate response measures through exploring key elements in a range of scenarios.     

粗粒碎屑岩砾石定向性定量表征方法及应用

砾石定向性可用于辅助判断粗粒沉积物沉积环境的介质动力性质与强度。在岩芯图像分析与测量的基础上,运用砾石长轴视倾角玫瑰花图中任意相邻三个小扇形的半径之和的最大值（参数a）和小扇形半径大小偏离程度（参数σ）对玛湖地区百口泉组砂砾岩中砾石定向性进行等级划分和定量表征。通过该方法的应用,建立了该区不同级别砾石定向性的定量划分方案:有明显定向性（a大于35%且σ大于4）、有一定定向性（a大于35%且σ小于4）、有模糊定向性（a小于35%且σ大于4）、定向性杂乱（a小于35%且σ小于4）。并对研究区典型季节性辫状河道和暂时性辫状河道的定向性进行了实测,结果表明季节性辫状河道中σ为4.8~8.13,a为40%~62%,而暂时性辫状河道中σ小于4,a小于35%。该方法能够有效表征砾石定向性,并为沉积环境判断提供依据。     

鄂尔多斯盆地中部马五7亚段颗粒滩沉积特征及空间分布

鄂尔多斯盆地中部马家沟组地层蕴含丰富的油气资源,以马五₇亚段为主要储集层位的盐下碳酸盐岩油气勘探近期取得了重要突破。基于钻井、测录井、岩芯及薄片等资料,对盆地中部马五₇亚段颗粒滩沉积特征、纵横向展布规律进行综合分析,进而探讨了研究区沉积古地理格局及其颗粒滩发育控制因素。结果表明:研究区马五₇亚段主要由晶粒白云岩及各类型颗粒白云岩构成,纵向上发育潟湖-颗粒滩-灰泥丘-台坪、潟湖-颗粒滩-滩间海-颗粒滩、潟湖-颗粒滩-灰泥丘三种沉积相序,颗粒滩位于向上变浅旋回的中上部,且常与微生物丘构成丘滩复合体建造,具有良好的储集意义。横向上,马五₇亚段发育两套较大规模的颗粒滩,层位稳定且连续性较好,整体表现为中西部厚而东部较薄的特征,平面上则呈南北向发育并沿东部凹陷环带状分布。研究区沉积规律表明马五₇亚段相对缺乏潮坪相沉积特征,推测其沉积环境更符合局限-蒸发台地。沉积期海平面的频繁变化控制了滩体发育规模及其垂向叠置样式,区内西高东底的古构造格局及其内部的微地貌起伏则决定了马五₇颗粒滩平面分布的差异性。     

岩浆底侵的热-流变学效应及对峨眉山大火成岩省的启示

岩浆底侵在大陆地壳的形成和演化过程中起着非常重要的作用。本文基于二维热传导方程模拟不同规模的地壳底侵产生的热-流变学效应,以及幔源岩浆温度和含水量对底侵厚度的影响;并以现有的岩石地球化学分析、深部地球物理探测结果为约束,模拟了峨眉山大火成岩省内带幔源岩浆底侵对应的地表热流随时间演化,探讨了形成幔源岩浆底侵的潜温和初始熔融的深度制约。结果显示:1)幔源岩浆底侵引起的热扰动的耗散时间取决于岩浆底侵的初始厚度。以幔源岩浆侵入温度为1300℃,20km厚的地壳底侵为例,热扰动完全耗散需经历约150Myr;而5km厚的地壳底侵,只需经历50Myr热扰动已基本耗散殆尽。2)在初始阶段,岩浆底侵会造成岩石圈强度的显著降低;随着热耗散的进行,岩石圈强度会逐渐恢复;在热扰动耗散殆尽之后,岩石圈强度反倒比底侵前的岩石圈强度更大。这表明岩浆底侵不但可以导致地壳增厚,还会最终导致岩石圈的强化。3)温度对地壳底侵厚度的影响比含水量的影响要大得多。将我们的模型应用于峨眉山大火成岩省,结果表明内带地壳底侵的热耗散需持续上百个百万年,岩浆潜温超过1500℃,初始熔融深度超过200km。     

Development of groundwater favourability map using GIS-based driven data mining models: an approach for effective groundwater resource management

The development of groundwater favourability map is an effective tool for the sustainability management of groundwater resources in typical agricultural regions, such as southern Perak Province, Malaysia. Assessing the potentiality and pollution vulnerability of groundwater is a fundamental phase of favourability mapping. A geographic information system (GIS)-based Boolean operator of a spatial analyst module was applied to combine a groundwater potentiality map (GPM) model and a groundwater vulnerability to pollution index (GVPI) map, thereby establishing the favourable zones for drinking water exploration in the investigated area. The area GPM model was evaluated by applying a GIS-based Dempster–Shafer–evidential belief function model. In the evaluation, six geoelectrically determined groundwater potential conditioning factors (i.e. overburden resistivity, overburden thickness, aquifer resistivity, aquifer thickness, aquifer transmissivity and hydraulic conductivity) were synthesized by employing the probability-based algorithms of the model. The generated thematic maps of the seven hydrogeological parameters of the DRASTIC model were considered as pollution potential conditioning factors and were analysed with the developed ordered weighted average–DRASTIC index model algorithms to construct the GVPI map. Approximately 88.8 and 85.71% prediction accuracies for the Groundwater Potentiality and GVPI maps were established using the reacting operating characteristic curve method and water quality status–vulnerability zone relationship scheme, respectively. Finally, the area groundwater favourability map (GFM) model was produced by applying a GIS-based Boolean operator on the Groundwater Potentiality and GVPI maps. The GFM model reveals three distinct zones: ‘not suitable’, ‘less suitable’ and ‘very suitable’ zones. The area analysis of the GFM model indicates that more than 50% of the study area is covered by the ‘very suitable’ zones. Results produce a suitability map that can be used by local authorities for the exploitation and management of drinking water in the area. The study findings can also be applied as a tool to help increase public awareness of groundwater issues in developing countries.     

多尺度空间分析技术遥感影像去雾方法

基于多尺度空间分析技术构建了两种影像去雾方法。多时相参考影像去雾方法利用同一地区没有雾的影像作为参考,运用多尺度空间分析技术获取地面低频信息将雾去除。自动影像去雾方法是基于拓扑分析的多尺度空间分析技术,分析影像的纹理和特征信息,将同一场景中的雾和地面信息分离,从而获得去雾后影像。通过青岛地区大量遥感影像数据测试,证明该方法是非常有效的。     

长江流域地下水资源特征与开发利用现状

为提升对长江流域水文地质和地下水资源的认知程度,突破以往单独从地表水或地下水角度进行评价的局限性,长江流域水文地质调查工程以地球系统科学理论和水循环理论为指导,充分考虑地表水与地下水的转化关系,将水文地质单元和地表水流域有机结合,划分长江流域地下水评价单元,建立典型地下水资源评价模型,开展了新一轮长江流域地下水资源评价。评价结果表明:(1)长江流域水循环要素时空分布不均,降水以中游最多,并由东南向西北递减;地表径流主要集中在夏季,且长江北岸比南岸集中程度更高;蒸散发量总体上呈现东部高于西部的特征,最大值集中在长江中游一带;长江流域地下水位总体保持稳定,丰枯季水位变化总体不大,一般小于2 m;长三角超采区的地下水漏斗面积已明显减小,相关环境地质问题得到了有效控制。(2)2020年长江流域的地下水资源总量2421.70亿m~3/a,其中山丘区地下水资源量2092.79亿m~3/a,平原区地下水资源量331.35亿m~3/a;地下水储存量较2019年整体略有增加趋势,其中四川盆地最为明显,共增加23.72亿m~3。(3)长江流域的水质上游优于下游,优质地下水主要分布在赣南地区和大别山南麓一带,部分地区水质较差的主要原因是原生劣质水的广泛分布。长江流域地下水开发利用水平整体很低,局部地区由于过往不合理的开发所引发的环境地质问题已得到缓解,岩溶塌陷、地面沉降等问题得到了较好控制。建议适当开发利用赣南地区和大别山南麓一带优质的基岩裂隙水。     

阿拉善地块南缘古生代花岗岩类研究进展

阿拉善地块处于华北克拉通,塔里木克拉通和祁连造山带的交汇处,其南缘古生代花岗岩广泛分布。结合近年来阿拉善南缘古生代花岗岩研究成果,从锆石U-Pb年代学和地球化学等方面进行分析总结,认为阿拉善南缘早古生代花岗岩主要受控于祁连造山带的构造演化,其岩浆活动可分为两期,中奥陶世—早志留世和中志留世—早泥盆世,前者处于俯冲环境,后者为后碰撞伸展环境;晚古生代花岗岩仅零星出露于龙首山地区,岩石地球化学特征与宗乃山—沙拉扎山构造带花岗岩相似,与中亚造山带的构造演化相关。并对目前研究中存在的问题和未来研究的方向提出了建议。