Ion microprobe U–Pb dating of zircon with a 15 micrometer spatial resolution using NanoSIMS

We developed a ²³⁸U–²⁰⁶Pb and ²⁰⁷Pb–²⁰⁶Pb zircon dating method using a Cameca NanoSIMS NS50 ion microprobe. A 7-to 9-nA O⁻ primary beam was used to sputter a 15-μm crater, and secondary positive ions were extracted for mass analysis using the Mattauch–Herzog geometry. The multicollector system was modified to detect ⁹⁰Zr⁺, ²⁰⁴Pb⁺, ²⁰⁶Pb⁺, ²³⁸U¹⁶O⁺, and ²³⁸U¹⁶O₂⁺ ions simultaneously. A mass resolution of about 4000 at 10% peak height and with a flat peak top was attained, and the sensitivity of Pb was about 4 cps·nA^− 1·ppm^− 1. A multicrystal zircon standard (QGNG) from South Australia with a U–Pb age of 1842 Ma was used as a reference for Pb⁺/UO⁺–UO₂⁺/UO⁺ calibration, and on the basis of the positive correlation between these ratios, we determined the sample ²⁰⁶Pb/²³⁸U ratios. ²⁰⁷Pb/²⁰⁶Pb ratios were measured by magnetic scanning in single-collector mode. The standard zircons 91500, from Canada, and SL13, from Sri Lanka, were analyzed against QGNG. Observed ²³⁸U–²⁰⁶Pb and ²⁰⁷Pb–²⁰⁶Pb ages agreed well with published ages within experimental error. Then, 16 zircon grains in a metamorphic rock from Nagasaki, Japan, were analyzed. Observed ages were compatible with SHRIMP ages, suggesting that the NanoSIMS with a 15-μm probe diameter is suitable for ion microprobe U–Pb zircon dating.     

Global mapping of the degree of space weathering on asteroid 25143 Itokawa by Hayabusa/AMICA observations

Abstract— We obtained color images of near‐Earth asteroid 25143 Itokawa by the Hayabusa multiband imaging camera to characterize the regional color properties. Images were obtained for the whole disk from the gate position (GP) and home position (HP) at a spatial resolution of 0.8–3.7 m/pixel. Whole‐disk spectra are adjusted to the telescopic data obtained by the University of Hawai'i's 88‐inch telescope using the Eight Color Asteroid Survey (ECAS) system. The disk‐resolved measurements show large variations in the three visible channels. We present a map of an index related to the degree of space weathering, which has been newly developed based on laboratory measurements. We find large variations in the degree of space weathering on Itokawa. Fresh materials are observed in regions of steep slopes and craters, whereas mature materials are ubiquitously distributed. This result suggests that pristine ordinary chondrite‐like materials have been exposed through weathered layers by excavation. By also examining close‐up images obtained during touchdown rehearsal, we find that most rocks in Itokawa's rough terrains are weathered. Instead of a regolith blanket, the surface of this small asteroid is covered with weathered rocks and gravels.     

Internal structures and high-velocity frictional properties of a bedding-parallel carbonate fault at Xiaojiaqiao outcrop activated by the 2008 Wenchuan earthquake

This paper reports internal structures of a bedding-parallel fault in Permian limestone at Xiaojiaqiao outcrop that was moved by about 0.5 m during the 2008 M_W7.9 Wenchuan earthquake. The fault is located about 3 km to the south from the middle part of Yingxiu-Beichuan fault, a major fault in the Longmenshan fault system that was moved during the earthquake. The outcrop is also located at Anxian transfer zone between the northern and central segments of Yingxiu-Beichuan fault where fault system is complex. Thus the fault is an example of subsidiary faults activated by Wenchuan earthquake. The fault has a strike of 243° or N63°E and a dip of 38°NW and is nearly optimally oriented for thrust motion, in contrast to high-angle coseismic faults at most places. Surface outcrop and two shallow drilling studies reveal that the fault zone is several centimeters wide at most and that the coseismic slip zone during Wenchuan earthquake is about 1 mm thick. Fault zone contains foliated cataclasite, fault breccia, black gouge and yellowish gouge. Many clasts of foliated cataclasite and black gouge contained in fault breccia indicate multiple slip events along this fault. But fossils on both sides of fault do not indicate clear age difference and overall displacement along this fault should not be large. We also report results from high-velocity friction experiments conducted on yellowish gouge from the fault zone using a rotary shear low to high-velocity frictional testing apparatus. Dry experiments at normal stresses of 0.4 to 1.8 MPa and at slip rates of 0.08 to 1.35 m/s reveal dramatic slip weakening from the peak friction coefficient of around 0.6 to very low steady-state friction coefficient of 0.1-0.2. Slip weakening parameters of this carbonate fault zone are similar to those of clayey fault gouge from Yingxiu-Beichuan fault at Hongkou outcrop and from Pingxi fault zone. Our experimental result will provide a condition for triggering movement of subsidiary faults or off-fault damage during a large earthquake.     

Alteration of gene expression profiles in the brain of Japanese medaka (Oryzias latipes) exposed to KC-400 or PCB126

Polychlorinated biphenyls (PCBs) are known as neurotoxic chemicals and possibly alter animal behavior. We previously reported that PCB-exposure induced abnormal schooling behavior in Japanese medaka (Oryzias latipes). This abnormal behavior might be caused by the functional alteration of central or terminal nervous system. To understand the mechanism(s) of behavioral change by PCB-exposure, we analyzed the gene expression profiles in the brain of medaka exposed to 3,3′,4,4′,5-pentachlorobiphenyl (PCB126) or a PCB mixture (Kanechlor-400: KC-400) using a cDNA microarray that we constructed. Twelve FLF-II strain medaka (six individuals per treatment) were dietary exposed to PCB126 (0.01 μg/g b.w./day) or KC-400 (1 μg/g b.w./day) for three weeks. For the control, six fish were fed a control diet. After the exposure period, fish were dissected, and the brain samples were collected. The samples from control fish were pooled and used as a common reference in the microarray experiment. Microarray data were normalized by the LOWESS method, and we screened the genes whose expression levels were altered more than 1.5-fold. Gene expression profiling showed 97 down-regulated and 379 up-regulated genes in the brain of medaka exposed to PCB126. KC-400 exposure suppressed 15 genes and induced 266 genes in medaka brain. Among these genes, the expression levels of 7 and 188 genes were commonly down- or up-regulated, respectively in both treatment groups. On the other hand, 31 gene expressions were significantly different between PCB126 and KC-400 treatment groups, and three out of 31 genes were received opposite effects. In addition, the microarray data showed that thyroid hormone-responsive genes were up-regulated by PCB-exposure, which may imply that PCBs or their metabolites mimic thyroid hormone effects in the brain of PCB-exposed medaka.     

Alteration of gene expression profiles in the brain of Japanese medaka (Oryzias latipes) exposed to KC-400 or PCB126

Polychlorinated biphenyls (PCBs) are known as neurotoxic chemicals and possibly alter animal behavior. We previously reported that PCB-exposure induced abnormal schooling behavior in Japanese medaka (Oryzias latipes). This abnormal behavior might be caused by the functional alteration of central or terminal nervous system. To understand the mechanism(s) of behavioral change by PCB-exposure, we analyzed the gene expression profiles in the brain of medaka exposed to 3,3',4,4',5-pentachlorobiphenyl (PCB126) or a PCB mixture (Kanechlor-400: KC-400) using a cDNA microarray that we constructed. Twelve FLF-II strain medaka (six individuals per treatment) were dietary exposed to PCB126 (0.01 microg/g b.w./day) or KC-400 (1 microg/g b.w./day) for three weeks. For the control, six fish were fed a control diet. After the exposure period, fish were dissected, and the brain samples were collected. The samples from control fish were pooled and used as a common reference in the microarray experiment. Microarray data were normalized by the LOWESS method, and we screened the genes whose expression levels were altered more than 1.5-fold. Gene expression profiling showed 97 down-regulated and 379 up-regulated genes in the brain of medaka exposed to PCB126. KC-400 exposure suppressed 15 genes and induced 266 genes in medaka brain. Among these genes, the expression levels of 7 and 188 genes were commonly down- or up-regulated, respectively in both treatment groups. On the other hand, 31 gene expressions were significantly different between PCB126 and KC-400 treatment groups, and three out of 31 genes were received opposite effects. In addition, the microarray data showed that thyroid hormone-responsive genes were up-regulated by PCB-exposure, which may imply that PCBs or their metabolites mimic thyroid hormone effects in the brain of PCB-exposed medaka.