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131.
金刚石生长阶段所捕虏的不纯净组分,能够提供大量地幔流体的信息。本文从金刚石的成因研究,表征地幔流体的固体包裹体、流体包裹体及流体的制药因素等方面讨论了金刚石不纯净组分与地幔流体的关系。 相似文献
132.
相山铀矿田成矿作用的地球化学模拟 总被引:4,自引:0,他引:4
相山铀矿田是我国最大的火山岩型热液铀矿田,在地质地球化学和高温高压实研究的基础上,利用地球化学模式程序EQ3/6模拟了成矿热水溶液的形成过程和减压排泄区铀成矿作用。计算机模拟结果表明,通过大气降水与碎斑熔岩相互作用,可以形成富含F和SiO2等矿化剂的含铀热水溶液;由于铀以UO2F^3和UO2(CO3(^2-3等配合形式存在,非常稳定,即使在深部强还原环境中仍能能够迁移;酸性和碱性环境,尤其是强酸性 相似文献
133.
Meihua Lu Albrecht W. Hofmann Maurizio Mazzucchelli Giorgio Rivalenti 《Chemical Geology》1997,140(3-4):207-222
Geochemical data are presented for the meta-igneous, mafic-ultramafic complex near Finero. This complex is in contact with a phlogopite-bearing mantle peridotite and is subdivided into the Internal Gabbro unit, the Amphibole Peridotite unit, and the External Gabbro unit. The Internal Gabbro and the Amphibole Peridotite units consist of coarse-grained, chemically heterogeneous cumulates, whereas the External Gabbro unit is generally massive, chemically more uniform and approximately representative of the residual melt with MgO contents between 6.6 and 9.1% and Mg numbers between 38 and 58. Both whole-rock and mineral contents of Ni and Cr are significantly higher (at similar Mg numbers) in the Amphibole Peridotite unit than in the Internal Gabbro unit. The most straightforward interpretation of this is that the Amphibole Peridotite unit accumulated after the influx of fresh mafic (or ultramafic) magma into the magma chamber. Major-element chemical trends are continuous from the Amphibole Peridotite unit to the External Gabbro unit and are consistent with closed-system fractionation with no further addition of magma or contamination by wall or roof rock assimilation. In the External Gabbro unit, total FeO and TiO2 contents are strongly correlated with each other (and with P2O5 and Zr) and reach values as high as 19 and 4%, respectively, indicating an advanced degree of crystal fractionation along a tholeftic trend. The External Gabbro samples have generally smooth normalized trace element patterns, which are consistent with being representative of a liquid composition. The residual nature of the External Gabbro magma is also indicated by negative Eu and Sr anomalies, clear evidence for prior feldspar fractionation. REE patterns are otherwise indistinguishable from N-type MORB, but Th and U are significantly more depleted than in MORB. This Th and U depletion is similar to that found in olivine basalts and picrites on Iceland and Hawaii; its origin is not well understood. No evidence is seen for any assimilation of crystal material, in sharp contrast with the situation of the igneous complex in Val Sesia near Balmuccia, where the magma composition is dominated by assimilation of crust. We suggest that the heat provided by at most two injections of magma near Finero was insufficient to induce crystal anatexis, in contrast with the excess heat supplied by multiple magma injections at Balmuccia. 相似文献
134.
重庆市滑坡、崩塌的发育规律及区域危险性程度区划 总被引:5,自引:0,他引:5
采用航空象片、遥感图像处理与野外实地考察相结合的综合研究,并根据前人的研究资料,详细解译了分布于重庆地区的各类滑坡、崩塌,总结了这些地质灾害的空间分布特征及发育规律,并对区域危险性程度进行了划分. 相似文献
135.
钛基柱撑累托石矿物材料的研究 总被引:17,自引:0,他引:17
在氮气环境中用TiCI4和HCI制成钛基柱撑液,采用离子交换法,用[Ti20O32(OH)12(OH2)18]^4 Dawson型Ti多核阳离子,交换累托石蒙皂石质晶层中的Na等阳离子,制成钛基柱撑累托石。通过电子探针定量分析、X射线衍射、红外光谱、热分析及魔角旋转核磁共振等方法,对钛基柱撑累托石的成分、结构和热稳定性进行了表征。钛基柱撑累托石具1.6nm的层孔隙,是一种很有应用前途的柱撑粘土矿物材料,有望在催化剂载体及环保材料领域中得到广泛的使用。 相似文献
136.
Parameter estimation for a karst aquifer with unknown thickness using the genetic algorithm method 总被引:3,自引:2,他引:3
The combination of ecological fragility and agricultural activity in the loess hilly–gully regions of western China has received
broad environmental concerns. In this region, rainfall and soil moisture can fatally influence crop production under dry land
farming. In this study, field experiments were conducted, from March 2001 to September 2005, to demonstrate the variation
of soil moisture and fertilizer contents at different depths in slope and terraced lands, and to evaluate the ecological impacts
and economic benefits in the terraced land of Loess Plateau. The results of both field test and Grey model (GM) calculation
show that the terraced land, as compared to the sloping land, in the agricultural area of the Loess Plateau tends to store
and retain much water, promoting more favorable interactions between water and fertilizer. During the months from March to
June of the year with less rainfall, the water supply for crop growth is mainly derived from the deep storage of soil moisture
accumulated from July to September of the previous year. The field experiments indicate that the crop yield of the 3-year-old
terraced lands was 27% higher than that of the sloping lands with slopes greater than 10°, and that the crop yield can increase
by 27.07 to 52.78% in the following cultivation years. In particular, potato was found to be more drought-resistant than winter
wheat, thus it is more suitable for the arid and semi-arid Loess Plateau regions. 相似文献
137.
柴达木地块北缘全吉地块钾长石浅粒岩碎屑
锆石LA-ICP-MS U-Pb定年
——对达肯大坂岩群时代的约束 总被引:2,自引:1,他引:2
为查明全吉地块基底中达肯大坂岩群的最大沉积年龄,用LA-ICP-MS技术测定了钾长石浅粒岩中的锆石U-Pb年龄。CL图像和Th/U比值指示这些锆石均为岩浆成因的锆石。36个测点207Pb/206Pb年龄变化范围为2094~2280Ma,其中年龄谐和度高于90%的30个测点的207Pb/206Pb年龄相对概率密度曲线呈单峰分布特征,峰值年龄为2190Ma左右。结合全吉地块最早一期变质事件的年龄,钾长石浅粒岩原岩碎屑和所在的达肯大坂岩群的沉积年龄范围被约束在1.95~2.19Ga之间。本研究表明,前人在侵入于达肯大坂岩群的伟晶岩脉中获得的约2.42Ga年龄的锆石应捕获于围岩,属于继承性岩浆碎屑成因,该类锆石年龄不能用来约束达肯大坂岩群原岩的最小沉积年龄。 相似文献
138.
Xiandong Liu Xiancai Lu Evert Jan Meijer for the Collab 《Geochimica et cosmochimica acta》2011,75(17):4978-4986
The acid chemistry of confined waters in smectite interlayers have been investigated with first principles molecular dynamics (FPMD) simulations. Aiming at a systematic picture, we establish the model systems to take account of the three possible controlling factors: layer charge densities (0 e, 0.5 e and 1.0 e per cell), layer charge locations (tetrahedral and octahedral) and interlayer counterions (Na+ and Mg2+). For all models, the interlayer structures are characterized in detail. Na+ and Mg2+ show significantly different hydration characteristics: Mg2+ forms a rigid octahedral hydration shell and resides around the midplane, whereas Na+ binds to a basal oxygen atom and forms a very flexible hydration shell, which consists of five waters on average and shows very fast water exchanges. The method of constraint is employed to enforce the water dissociation reactions and the thermodynamic integration approach is used to derive the free-energy values and the acidity constants. Based on the simulations, the following points have been gained. (1) The layer charge is found to be the direct origin of water acidity enhancement in smectites because the neutral pore almost does not have influences on water dissociations but all charged pores do. (2) With a moderate charge density of 0.5 e per cell, the interlayer water shows a pKa value around 11.5. While increasing layer charge density to 1.0 e, no obvious difference is found for the free water molecules. Since 1.0 e is at the upper limit of smectites’ layer charge, it is proposed that the calculated acidity of free water in octahedrally substituted Mg2+-smectite, 11.3, can be taken as the lower limit of acidities of free waters. (3) In octahedrally and tetrahedrally substituted models, the bound waters of Mg2+ show very low pKa values: 10.1 vs 10.4. This evidences that smectites can also promote the dissociations of the coordinated waters of metal cations. The comparison between the two Mg2+-smectites reveals that different layer charge locations do not lead to obvious differences for bound and free water acidities. 相似文献
139.
本文导出了固液两相流体中球空泡的振荡方程,并用数值方法讨论了固体颗粒对它泡运动及泡壁压强的影响,得到了固相浓度、颗粒尺寸等因素与空泡运动之间的定性关系。在分析过程中,考虑了液体与颗粒之间力的双向耦合作用。 相似文献
140.