准噶尔盆地滴西地区石炭系火山岩储集性能分布规律研究

火山岩储集性能分布的非均质性非常强,探索其分布规律成为火山岩油气勘探的难点和重要任务。本文以实际岩心及其分析化验等资料为基础,从滴西地区取心最佳储集性能段、最差储集性能段、风化壳储集性能分布模式、薄层熔岩储集性能分布模式、厚层熔岩储集性能分布模式等方面总结了石炭系火山岩储集性能的垂向分布规律,同时分析了储集性能的平面分布情况。火山熔岩储集性能在垂向上的分布差异,成岩阶段主要受岩相的影响,后期主要受构造作用及风化溶蚀作用等的影响。受成岩阶段岩相的影响,溢流相上部亚相和下部亚相均有可能形成较好的储集性能。与碎屑岩互层的薄层熔岩常具有较好的储集性能。与碎屑岩互层的厚层熔岩段的底部储集性能可能较好,其次是顶部,而中部常沦落为储集性能相对较差的位置。风化壳的风化粘土层、强风化带、中等风化带、弱风化带、未风化带5个垂向分带结构中,中等风化带往往具备相对最佳的储集条件。应用W风化指数新型工具对火山岩进行风化程度评估显示,准噶尔盆地火山岩具有多期风化的特征,并残留有大量未风化、轻微风化及中等风化的火山岩,这其中不乏储集性能优良的岩性段。从平面分布来看,研究区域火山岩储集性能具有强烈的各向异性特征,常表现为局部富集,快速变迁,随机分布。     

An optimized sequential extraction scheme for molybdenum association in environmental samples

By comparing three sequential extraction procedures, a new optimized extraction scheme for the molybdenum association in environmental samples was proposed. Five operational steps were described as exchangeable (KH₂PO₄ + K₂HPO₄: including water-soluble), associated with organic matter (NaOH), Fe–Mn oxides and/or carbonates (HCl), sulfides (H₂O₂) and residue (HNO₃ + HF + H₂O₂). An optimized extraction scheme was compared with Tessier’s procedure and the Commission of European Communities Bureau of Reference (BCR) was applied to black shales. Results showed Tessier’s procedure gave the lowest concentration values for exchangeable molybdenum and the highest values for the residual molybdenum, which could not present the efficiency of the extraction reagents. BCR’s procedure showed the highest values in oxidizable molybdenum and presented four fractions of molybdenum, which did not demonstrate the fractions of molybdenum in the black shales in detail. The optimized extraction scheme demonstrated a certain improvement on extraction efficiency over Tessier’s procedure for the lowest residual molybdenum, and revealed more featured fraction information of molybdenum in black shales than BCR’s. Therefore, after a comparison with other two extraction procedures, the optimized extraction scheme proved suitable for the molybdenum in black shales and it also showed an accurate determination of the molybdenum in the fractions and source of bioavailable Mo.     

An Overview of Paleo-AO/NAO Studies

The discovery of decadal variability of North Atlantic Oscillation (NAO) and the introduction of Arctic oscillation (AO) concept have initiated a series of paleo-AO/NAO related studies since the mid-to-late 1990s. The progress and new findings of paleo-AO/NAO works after that time were comprehensively reviewed. The new results from the observations and modelings at four key timescales were summarized in detail: ①the reconstructions of the AO/NAO annual index over the past millennium; ②the debate on AO/NAO’s trend since early Holocene; ③the weakening of AO/NAO’s amplitude during the Last Glacial Maximum; and ④the anomalous positive phase of AO/NAO during the Last Interglacial. In addition, the possible mechanism for different timescales of AO/NAO is also summarized. Furthermore, the distinction between AO/NAO’ was mean state and amplitude, which were not explicitly separated in previous studies, were comprehensively discussed. Considering the current uncertainties related to paleo-AO/NAO studies, we encourage the community to search for more proxies having longer-than-10,000-year length with annual resolution around AO/NAO highly correlated regions. Another, we encourage long-term transient modeling on AO/NAO can be performed in order to improve our understanding of the dynamics and interaction between AO/NAO’s high-frequency variability and the climatological background, so as to further improve AO/NAO’s predictability on global warming context.     

东昆北成矿带冰沟南铜镍矿辉长岩地球化学特征

通过对东昆北成矿带冰沟南铜镍矿辉长岩的全岩地球化学进行分析,以确定该岩体的岩石成因及其形成的构造环境。冰沟南辉长岩SiO_2的含量为49.72%~51.58%,岩石系列为钙碱性。稀土元素球粒陨石分配模式为轻稀土略富集型,δEu为1.26~1.54,轻微正Eu异常。岩石富集大离子亲石元素(LILE)Rb、Ba、K,相对亏损P。岩体中的La/Sm、Th/La和Nb/U比值显示在就位过程中经历了一定程度的地壳混染。研究认为,岩体的岩浆源区为亏损地幔。结合区域演化,认为岩体形成于碰撞后伸展的背景。     

钟姑地区典型矿床的重磁找矿模式

钟姑地区位于宁芜中生代火山岩盆地南段,已发现有白象山铁矿等多个大型铁矿,是长江中下游成矿带以玢岩型铁矿为主的矿集区。本文以钟姑地区实测岩石物性参数为桥梁,以实测重磁数据为基础,分析了该区白象山铁矿、钟九铁矿和云楼铁矿的重磁场分布特征,并根据典型矿区已知地质条件,运用成熟的2.5D重磁联合反演技术进行计算,从定量角度认识铁矿体深部发育形态、位置与重磁异常之间对应关系,建立钟姑地区白象山铁矿等典型矿床的重磁找矿模式,为该区进一步找矿突破提供地球物理场信息。     

昌宁-孟连结合带牛井山早古生代埃达克岩锆石U-Pb年龄、岩石成因及其地质意义

昌宁-孟连结合带是西南三江地区重要的古特提斯结合带,本文报道该带牛井山蛇绿混杂岩带内的早古生代英云闪长岩的锆石U-Pb年龄和Hf同位素、全岩地球化学特征,探讨其岩石成因,揭示早古生代(原)特提斯演化过程和恢复古地理格局。利用LA-ICP-MS对英云闪长岩进行锆石U-Pb定年,获得~(206)Pb/~(238)U加权平均年龄为468±2Ma(MSWD=1.4,n=22),代表岩浆岩结晶时代。对锆石进行原位微区Hf同位素分析获得锆石ε_(Hf)(t)=+1.6~+2.8。牛井山英云闪长岩具有高的SiO_2(61.6%~67.16%),Al_2O_3(15.4%~17.64%),Na_2O(2.93%~3.25%)含量,高的Na_2O/K_2O(3.9~5.4)比值。微量元素具有高Sr(469×10~(-6)~533×10~(-6)),低Yb(0.66×10~(-6)~1.22×10~(-6))和Y(8.5×10~(-6)~16.3×10~(-6)),Eu正异常(1.01~1.37)的特征。此外,在同等SiO 2条件下,还具有相对高的Mg~#和MgO(Mg~#=50~51,MgO=2.84%~3.58%)。这些特征表明英云闪长岩具有高镁埃达克岩的性质。岩石成因研究表明牛井山高镁埃达克岩很可能是俯冲洋壳加上部分大洋沉积物部分熔融并与上覆地幔橄榄岩反应的产物。早古生代洋壳俯冲成因的埃达克岩的发现证明昌宁-孟连特提斯洋演化历史可追溯至约468Ma。昌宁-孟连结合带早古生代岩浆作用与龙木错-双湖结合带早古生代洋壳残片的时代一致、构造属性相似,我们认为昌宁-孟连结合带与木错-双湖结合带可对比,它们代表了一个统一的古生代特提斯大洋残余。     

基于小波分析的抚松县降水量变化对矿泉水资源量的响应研究

大气降水是抚松县矿泉水资源的重要补给来源,探究其变化规律及极值概率对泉流量是否能够得到持续补给具有重要意义。为此,首先利用1960~2013年的降水资料和1981~2008年部分泉流量观测数据,对抚松县降水量的年内分配、年际变化和不同年代降水量均值变化进行降水特征分析;之后,运用皮尔逊Ⅲ型模型分析最大年降水量的概率分布;接着,利用1981年7月~2008年11月期间降水量和部分泉的泉流量监测数据,采用连续小波分析法对二者周期进行分析;最后,运用交叉小波变换法对同一时段内降水量和泉流量多时间尺度变化的相关性进行分析。结果表明:1960~2013年的54间,研究区内年降水量呈现周期性变化,变差系数为1.017×10-17,降水稳定,未发生异常变化。降水量和泉流量均存在约11个月的主震荡周期,二者属于同相位(即泉流量对降水量的变化产生即刻反应),降水量作为本区矿泉水补给的重要影响因素,可为矿泉水资源得到有效补给提供保证。     

汶川地震断裂带多次地震活动新证据

虹口乡八角庙出露完整的映秀—北川断裂带剖面断层岩,高分辨率磁化率测试揭示出多个具有高磁化率特征的断层岩带。系统的岩石磁学分析证明一层褐色断层岩相对围岩具有最大的磁化率值,存在新生成的磁铁矿和拥有相似的天然剩磁(NRM)和非磁滞剩磁(ARM)强度衰减过程。高磁化率特征是含铁顺磁性矿物受到断层滑移过程产生摩擦生热作用生成磁铁矿所致。同时断层岩还获得了热剩磁,记录了地震活动磁学信息。结合汶川地震科学钻探项目1号孔(WFSD-1)磁化率和岩石磁学研究结果,说明映秀—北川断裂带包含多层具有高磁化率特征的断层岩,暗示了多次强震的发生。具有高磁化率特征的断层岩可以作为判定地震活动的标志之一。     

北方某经济开发区地下水污染调查评价

本文应用污染指数法,对北方某经济开发区及周边地下水水质进行了污染评价,结果表明研究区地下水水质以轻污染和中污染为主,局部地区出现较重污染,主要指标为硝酸盐氮、三氯甲烷和三氯乙烯。通过对工业废水、再生水、河水水质的检测,发现研究区地表水水质与污水处理厂再生水排放密切相关,地下水污染很可能与开发区企业排污有关。由于开发区所处位置的环境敏感性和脆弱性,建议今后在开发区及附近继续开展相关研究,进一步查明地下水的硝酸盐氮及有机污染物来源、污染途径,建立完善的监测体系,以便及时切断污染源,保障城市及当地供水安全。     

Detachment folding in a Lower Cambrian–Upper Permian karst reservoir: 3D model of the Yubei 3D area (eastern Markit Slope,Tarim Basin,Northwest China)

A three-dimensional (3D) structural modeling of the Lower Cambrian–Upper Permian Yubei 3D area was performed to understand its structural evolution. This model reproduces the present-day structure of the basin and comprises 11 horizons within Lower Cambrian to Upper Permian rocks. The analysis is based on 3D depth views and faults. The results image salt movements due to tectonics and/or burial. From these observations, this paper deduces that salt structures are correlated to the main faults and tectonic events. From the model analysis, we interpret the timing and geometry of Tarim Basin tectonics. The fault geometry can be resolved based on the strike of the fault, the morphology of hanging wall strata, and the stratigraphic distribution. Emphasis is placed on gypsum rock detachment, considering its movements during the Middle Caledonian event and decoupling effects during tectonic evolution. Moreover, we point to the structural control of the Paleozoic basement and the crustal architecture (Yubei 3D Zone) on the geometry of the Tarim Basin.