Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

基于微电子系统（MEMS）加速度地震勘探三分量数字检波器简介

基于微电子机械系统（MEMS）制成的微加速度三分量数字地震检波器。集数据采集、处理及传输功能干一体，在结构模型、工作原理、性能指标控制等方面不同于常规检波器，其信号幅值在低于自然频率范围内没有衰减。因其独特的制造技术，MEMS检波器具有超低噪声，大动态范围和极高的向量保真度性能。     

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…     

地震地质灾害空间预警评估定量化方法研究初探

建立“发育度”、“潜势度”、“危险度”、“危害度”等概念来描述地震地质灾害各影响因子、要素及可能的灾害危害程度,进而建立构成地震地质灾害层次分析的概念体系及地震地质灾害空间预警评估模型,将定性评估转化为定量评估进行初步研究。     

用CC的方法分析和解决一个常见的网络安全问题

CC导出PP的过程是一种安全评估通用语言到某类产品的具体应用过程,需要经过需求分析、得出安全目的、提出安全功能要求与安全保证要求等几个阶段。本文利用这些过程的基本方法和思想全面分析一个常见的网络安全问题,并按照保护轮廓的模式给出该网络的安全要求。     

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。     

长江下游一次大暴雨的中尺度模拟分析

运用中尺度数值模式（MM5V3.6）对2004年6月25日长江下游地区一次大暴雨天气过程进行了数值模拟,结合天气形势和卫星云图对此次过程进行了分析.结果表明：在东北冷涡和西太平洋副热带高压两大天气尺度系统的作用下,西南低空急流的再次加强和中低层切变线共同作用是此次大暴雨过程的主要原因.螺旋度分析表明,在不均匀的强上升气流的作用下,涡旋的水平分量向垂直分量转化是此次强降水的可能机制之一.     

东亚冬季风异常与广东前汛期旱涝关系的初步分析

利用500hPa北半球格点资料,参照历史平均东亚大槽位置,定义了东亚冬季风强度指数(I₅₀₀)。分析发现,近50年东亚冬季风强度有减弱趋势,特别是1987年以来冬季风明显减弱。根据广东48个站1954～2004年前汛期(4～6月)降水资料,用区域旱涝指数W对广东前汛期旱涝等级进行划分。51年内广东有9年前汛期出现大涝(或特涝),11年出现大旱(或特旱),旱涝发生频繁。冬季风异常对广东前汛期降水的影响比较大,强冬季风年后广东前汛期出现大旱的可能性较大,而出现大涝的可能性很小。