Adsorption of anionic dye on magnesium hydroxide-coated pyrolytic bio-char and reuse by microwave irradiation

Magnesium hydroxide-coated pyrolytic bio-char composite was prepared by chemical precipitation, and the adsorption behavior of anionic dye (directly frozen yellow) onto magnesium hydroxide-coated pyrolytic bio-char was investigated in the batch mode. The Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy and X-ray fluorescence spectroscopy of adsorbents were characterized. Adsorption studies were performed at different pH, salt concentration, contacting time and dye concentration. The pH value of the solution influenced the adsorption capacity significantly, and adsorption is favored of pH 6–8. Salt coexisted in solution increased slightly directly frozen yellow adsorption capacity. The isotherm data were analyzed by Langmuir and Freundlich isotherm model, and Langmuir model was better to predict the equilibrium data. Thermodynamic calculations showed that the adsorption was a spontaneous and endothermic process. Exhausted magnesium hydroxide-coated pyrolytic bio-char was treated by microwave irradiation, and yield of regeneration was 98 % in the case of microwave irradiated time 5 min at 320 W. The magnesium hydroxide-coated pyrolytic bio-char can be reused.     

锰矿石脱硫产物处理含铜废水动态实验研究

氧化型锰矿石脱硫产物含大量硫化锰,利用这种材料装填固定床进行净化水中铜离子的动态试验.在材料粒径0.45～0.9mm、进水pH=5.8、进水滤速4.58 m/h条件下,1 t锰矿石脱硫产物可以处理923 tρ(Cu~(2+))=50 mg/L的含铜废水,出水ρ(Cu~(2+))<0.5 mg/L,低于国家一级排放标准.控制进水pH在4～9之间、降低进水滤速、采用较小粒径的材料有利于提高锰矿石脱硫产物处理含铜废水的容量.利用X射线粉末衍射(XRD)和扫描电镜-能谱分析(SEM-EDS)对材料和产物进行表征,证明锰矿石脱硫产物去除水中铜离子是基于离子交换反应的原理.     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

基于BGM的暴雨集合预报初始扰动发展分析

基于增长模繁殖法（BGM）思想,采用AREM（新一代区域η坐标模式）,研究了暴雨过程中,初始随机扰动在繁殖循环中随时间的演变特征和发展机理。结果表明,初始扰动的演变决定于环流背景场的结构和大气中的湿物理过程。背景场不仅影响扰动的演变规律,而且决定了扰动发展的敏感区域。初始扰动随时间演变存在两个敏感区,一是背景场的大风速区,二是降水区附近。对流层高层,大风速区附近扰动得到最优发展;对流层中低层,扰动不仅沿大风速区发展,且与降水区配合较好。初始扰动发展的机理也有两种,一是大气湿物理过程引起的位势不稳定或第二类条件不稳定（CISK）;二是由风切变引起的大气动力不稳定。高层扰动的增长,以干大气的动力不稳定占优,中低层扰动的发展主要是湿物理过程的贡献,初始扰动在模式中的发展与降水的发展是同“源”的,有利于降水发展的环境也有利于初始扰动的发展,从而影响了降水的可预报性。所以利用暴雨预报模式制作集合预报时,BGM仍是可用的方法。     

去除EOS/MODIS 1B数据中"弯弓"效应的方法

分析了中分辨率成像光谱仪EOS／MODIS的扫描方式,在此基础上研究了EOS／MODIS1B数据集“弯弓”效应的成因。对EOS／MODIS1B数据02级产品HDF文件的格式进行了探讨,并以250m分辨率资料为例,在2002年7月13日10时的MODIS资料中选取鄱阳湖以北部分地区,读取其数据进行插值、Lambert投影、重采样等处理,从而消除了影响资料使用的“弯弓”效应,同时也完成了对EOS／MODIS数据的几何校正,取得了一定的效果,为EOS／MODIS遥感资料在今后得以广泛应用作了有益的尝试。     

高精度温度采集系统设计

针对高精度温度采集的需求,设计了一个以低功耗单片机MSP430F149作为核心处理器,以PT100铂电阻为传感器的温度采集系统。为了提高系统的复用性,采用精密电阻法,从硬件设计上消除了恒流源电流漂移以及A/D转换电路参考电压精度对温度测量数据的影响。重点描述了系统设计方案,详细说明了恒流源选择的原则、电流偏差的消除以及AD7792转换器的操作步骤。实验结果表明,温度测量精度优于0.1 ℃。对比试验表明,系统稳定性良好,已应用于业务产品中。     

杞麓湖泄水暗河淤塞的不良环境效应分析

杞麓湖岩溶盆地为一封闭的汇水径流型断陷湖盆,汇水面积内的地表地下水流入杞麓湖后,从岳家营落水洞灌入式补给高寨暗河系统,通过地下暗河岩溶管道径流至东部的华宁盆地后以暗河形式排泄。由于泥砂堵塞暗河岩溶管道,导致落水洞最大泄流量不断减小,削弱了杞麓湖的水资源调节功能,引发洪涝灾害;淤塞物及径流迟缓引起污染、污染水置换缓慢又加剧了暗河污染;为解决淹蓄矛盾修建的调蓄水隧道施工以来,岩溶渗漏使得隧道沿线地下水位下降,疏干了山区农村水源,导致地面沉降变形,间接引出一系列新的环境地质问题。     

北方某废弃矿区地下水污染帷幕注浆应急处置研究

随着我国煤炭资源的枯竭,大量矿山关闭,遗留了广大的地下采空区场地。不少化工企业向废弃矿井内倾倒化学废液等导致了矿区地下水污染事故,威胁地下水水源地的水源安全。针对此类复杂场地条件下污染事故的应急处置案例和经验都非常少,本文以北方某废弃矿区地下水污染注浆帷幕应急处置为例,通过对矿区地质条件的分析、地下空间结构和地下水流场的刻画,构建三维地质模型,以模型为基础设计帷幕注浆工程并实施,研究复杂场地条件下开展帷幕注浆应急处置的重要内容和决定因素,并利用场地地下水样品监测结果,分析研究帷幕内外污染物浓度分布特征及差异,找出地下水运移规律,评价注浆帷幕效果。研究表明：在事故井周边100 m范围实施的帷幕注浆工程,对污染物运移的封堵效果显著,帷幕注浆内外污染物含量差距明显。一期检测结果显示帷幕注浆范围内地下水中二氯甲烷浓度最高1390 μg/L,帷幕范围外最高浓度仅为8. 07 μg/L;二期检测结果为污染物检出浓度大于5 μg/L的区域全部位于帷幕范围内,帷幕范围外均未检出。同时污染物的分布特征指示着地下水沿巷道运移成为最主要的形式,对地下空间结构的精准刻画是决定帷幕注浆工程成效的重要因素。     

吉林夹皮沟金矿带黄铁矿热电性及热爆裂特征

通过对夹皮沟金矿带主要载金矿物黄铁矿的热电性和热爆裂特征分析,确定了主成矿世代及各世代矿化类型,预测了深部探矿的可能性。黄铁矿以电子型(N型)为主,极少有空穴型(P型),N型热电系数分布于-347.3～-6.2 μV·℃-1,P型热电系数介于17.4～193.5 μV·℃-1, 成矿温度集中于258.8～319.2 ℃, 剥蚀率为50.260%～50.485%。爆裂曲线反映中低温(＜280 ℃)矿化没有高温(＞290 ℃)矿化好。综合分析认为,夹皮沟金矿带矿化分早期高温世代(热电系数峰值为-120 μV·℃-1,成矿温度峰值为320 ℃)和晚期中低温世代(热电系数值峰值为-210 μV·℃-1,成矿温度峰值为270 ℃)。前者包括石英脉型与蚀变岩型,在矿体走向与夹皮沟主断裂一致及相交的矿区中均有发育;后者属石英脉型,主要在矿体走向与夹皮沟主断裂相交的矿区发育,叠加于高温世代热液矿化之上。高温热液矿化世代是主成矿世代,但有叠加的部位矿化增强。     

MODIS遥感监测滇池蓝藻水华分布

以中分辨率的MODIS数据作为遥感影像源,运用蓝藻水华在蓝波段、红波段和近红外波段的光谱特征,使用假彩色合成法（RGB：6-2-1）和归一化植被指数法对滇池的蓝藻水华进行遥感监测。通过星地同步试验,证明了该两种方法的正确性。其中假彩色合成法通过色彩差异表现蓝藻水华,具有视觉效果较好的优点,归一化植被指数法则以数值大小的方式区别水华浓度,该方法建立反演模型后可用于定量研究。