Mudstone lithogeochemistry and formation conditions of Vendian deposits in the Shkapovo-Shikhan Basin

Variation of geochemical modules and indices in mudstones from the Upper Vendian Kairovo and Shkapovo groups of the Shkapovo-Shikhan Basin provides the comprehensive information on changes in maturity of the fine aluminosiliciclastic material delivered in the basin, characterizes the redox environment in bottom water, and makes it possible to reconstruct the rock composition in provenance and its evolution through time. The generally moderate maturity of the fine terrigenous clastic material suggests that a nearly semiarid-semihumid climate dominated in paleodrainage area throughout the Late Vendian. It has been established that reducing environment did not exist in bottom water of the central Shkapovo-Shikhan Basin throughout the Late Vendian. Intermediate rocks prevailed in the paleodrainage area. More silicic rocks could occur only in the early Staropetrovo and late Salikhovo times. Data points of mudstones from the Kairovo and Shkapovo Groups plotted on the Cr-Ni, Co-V, Co/Hf-Ce/Cr, La-Th, and La/Sm-Sc/Th diagrams indicate that both Archean and more mature Paleoproterozoic crustal blocks existed in different proportions in the Late Vendian within source areas.     

Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.     

Ballooning instability and oscillations of coronal loops

The excitation of the ballooning instability by the eigenoscillations of coronal loops is analyzed using the energy method. The second variation of the potential energy for the case of a plasma—plasma boundary is obtained via the linearized ideal MHD equations. It is shown that the eigenmodes of a magnetic tube and of a toroidal coronal loop coincide in a first approximation. The bending oscillations of the loops are able to excite the ballooning instability when β ? 1. The effects of the instability in solar coronal loops are discussed.     

Morphotectonics and incision of the Kaoping submarine canyon, SW Taiwan orogenic wedge

The Kaoping submarine canyon developed on the frontal orogenic wedge off SW Taiwan and is the largest one among others. The canyon begins at the mouth of the Kaoping River, crosses the narrow shelf and broad slope region, and finally merges into the northern Manila Trench for a distance of about 260 km. Using reflection seismic sections and bathymetric mapping this paper reveals the geomorphic characteristics of the Kaoping Canyon strongly related to structural and sedimentary processes. The combined morphometry statistics analysis, seismic interpretations of structures and examinations of detailed bathymetric charts indicate that regional canyon morphology is strongly linked to intrusions of mud diapirs in the upper reach of the canyon and thrust faulting in the middle and lower reaches which produce two prominent morphological breaks of the course of the Kaoping Canyon with two sharp bends. Although excavation of floor and enlargement of the Kaoping Canyon are mainly attributed to downslope erosion of seabed, incision of this canyon is also strongly complicated by mud diapiric intrusions (upper reach), westward thrust faults (middle reach), and regional base level tilting (lower reach). The resultant cross-sectional morphology along the Kaoping Canyon changes considerably, ranging from U-shaped, broad V-shaped, to irregular troughs. The Kaoping Canyon may be served as a variant of canyon model of active margins with a distinct morphology of two sharp bends along the canyon course associated with structure deformation.     

Optical variability of the NLS1 galaxy Ark 564 in 1987–2004

We present the results of our U BV R _c I _c photoelectric and CCD photometry of the NLS1 galaxy Ark 564 in 1987–2004. Between late 1997 and 2002, a slight increase in brightness was observed followed by a small but systematic decline until 2004. Ark 564 has a low variability amplitude, within 0.2^m in the U BV R _c I _c bands. The galaxy’s spectral energy distribution at 3600–9000 Å is unlike those for Seyfert 1 (Syl) galaxies. A delay of the Ic flux relative to the B flux of about three days was found, which is in agreement with the standard disk model. This delay probably reflects the geometric size of the region that emits the observed continuum.     

Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.