Determination of indium in natural waters by flow injection inductively coupled plasma mass spectrometry

Two methods have been developed to measure indium (In) in natural waters by flow injection inductively coupled plasma mass spectrometry (ICPMS). One is the isotope dilution technique using an¹¹³In enriched spike and the other utilizes natural yttrium present in the sample as an internal standard. In the former, optimization of the¹¹³In spike to minimize error is often difficult for samples in which In concentrations are variable, whereas in the latter method, a separate determination of Y in the sample is necessary and hence more sample is required. Using about 1 liter of a water sample, 200 fold preconcentration of In was performed by solvent extraction and back extraction technique and then introduced into the ICPMS to measure the¹¹³In/¹¹⁵In or¹¹⁵In/⁸⁹Y ratios. The detection limits were 0.01–0.02 pmol kg⁻¹ for both methods. Application of the methods to seawater samples yielded the concentrations of 0.06–0.15 pmol kg⁻¹ for the Pacific and 0.6–1.5 pmol kg⁻¹ for the Atlantic. The large inter-oceanic variation of In best resembles that of Al amongst the 3B group of elements in the periodic table. River and estuarine samples gave a more variable range of concentrations of 0.01–15 pmol kg⁻¹. Most of the In supplied by rivers is removed by scavenging in the estuarine mixing zone, suggesting that the fluvial input of In to the ocean is small.     

K–Ar geochronology of a Quaternary monogenetic volcano group in Ojika Jima District, Southwest Japan

 An unspiked K–Ar dating method using a mass-fractionation correction procedure was applied to a Quaternary independent group of monogenetic volcanoes, Ojikajima Volcano Group, located in northwestern Kyushu in Southwest Japan, in order to clarify in detail secular variations in eruptive volume, locations of eruptive vents, and magma compositions in a single monogenetic volcano group. The major results were as follows: (a) K–Ar ages of monogenetic volcanoes distribute from 1.08 to 0.30 Ma, with voluminous peaks at approximately 1.0 and 0.6 Ma. (b) The volcanic activity commenced in the central part of the field, expanded to the whole field at approximately 0.6 Ma, and then shrank to the central area. (3) Concentrations of incompatible elements, such as Ba, K, and Nb, increase with decreasing age, whereas P, Y, and Zr concentrations remain constant. These concentrations suggest gradual decrease in the degree of partial melting from an identical mantle source with residual garnet. Received: 15 December 1997 / Accepted: 23 May 1998     

Lead-210 in the Japan Sea

This is the first detailed study on the distribution of lead-210 in the Japan Sea water. The content of lead-210 ranged from 9.3±2.1 dph/l in the surface water to 3.4+-0.8 dph/l in the deep water—a quite low content as compared to that in the deep water of the North Pacific. Vertical profiles show that the content of lead-210 abruptly decreases below the seasonal thermocline (10–20 m in depth) and nearly uniform in the deep water. It is suggested that a significant amount of air-borne lead-210 deposited over the Japan Sea is transported along with the Tsushima Current to the open ocean. The budget of lead-210 is calculated by using a simple box-model and the mean residence time of lead-210 in the Japan Sea is estimated to be 15 yr.     

Contribution of different functional groups to the diet of major predatory fishes at a seagrass meadow in northeastern Japan

We examined the variation in habitat use and diet of three dominant fish species (Myoxocephalus brandti, Pholidapus dybowskii, and Pholis crassispina) in a seagrass meadow in the Akkeshi-ko estuary in northeastern Japan, where broad and dense Zostera marina beds exist, using a semi-quantitative census of the fishes and analyses of their stomach contents. Differences among the three fish species in the temporal variation in abundance of each age class (mainly 1- and 2-year age classes) indicated that the temporal pattern of utilization of the seagrass meadow were different among them. In the semi-quantitative dietary analysis, two prey categories, i.e., taxonomic group (order and suborder) and functional group, were used to explain the variation in prey composition with size-dependent changes. The six prey functional groups were classified based on the ecological traits of the prey, i.e., trophic level, size, and life type (habitat and behavior). Ontogenetic shifts in prey of the three fish species could be fully explained by a combination of the two prey categories, and not by the use of only one category (taxonomic or functional group). The pattern of ontogenetic shifts in prey differed among the fish species and size (age) classes. These results indicate that segregation of habitat (seagrass meadow) and prey group (taxonomic and functional group) is performed among the three species, which may contribute to their coexistence in this estuary.     

Stream temperature,specific conductance and runoff process in mountain watersheds

Stream temperature ranged from 3 to 4°C at an experimental site during snowmelt on Hokkaido Island, Japan, which provided direct evidence of major contributions of subsurface water to stream water. In contrast, stream temperatures during rainstorms in summer decreased gradually after stream flow peaked, attaining a nearly constant temperature ranging from 9 to 11°C. During storm flow recession, stream temperatures during summer or snowmelt were similar to the soil temperature at 1·8 m below the land surface, suggesting that subsurface water contributions to stream flow are derived from this depth. The hygrographs during two rainstorms, August 1987 and September 1989, were separated using temperature. The stream temperature was assumed to depend on the mixing of surface flow, having a temperature ranging from that of rainfall to that of shallow (50 cm deep) soil water, and subsurface flow, having the temperature of the soil at 1·8 m below the land surface. Subsurface flow was estimated to contribute 85–90% of the total stream flow during each rainstorm. A two‐component hydrograph separation was also evaluated using specific conductance. Runoff contributions from the two sources for the temperature and specific conductance analysis were similar. Analysis of the temperature and conductance–discharge hysteresis loop, and of individual flow components for storm hygrographs, provide a general picture of the runoff process in the experimental basin. Copyright © 1999 John Wiley & Sons, Ltd.     

Element transport by dehydration of subducted sediments: Implication for arc and ocean island magmatism

High-pressure experiments on a natural pelite have been conducted at 2–11-GPa pressures in order to evaluate contributions of subducted sediments to arc and ocean island magmatism. Obtained phase relations suggest that, at least in modern subduction zones, subsolidus dehydration of chlorite and phengitic muscovite in the subducted sediments, rather than partial melting, is a predominant process in overprinting sediment components onto the magma source region. Trace element compositions of sediment-derived fluids are estimated based on dehydration experiments at 5.5 GPa and 900/1300°C. Pb is effectively transported by fluids relative to other elements. This results in the Pb enrichment for arc basalts by fluids, generated by the dehydration of subducted sediments, together with altered mid-ocean ridge basalt (MORB), and complementary depletion of Pb in subducted sediments. Inferred arc magma compositions obtained by model calculations based on the present experimental results agree well with a natural primitive arc basalt composition. A large increase in the U/Pb ratio in the subducted sediments at deeper levels than major dehydration depths results in a high Pb isotopic ratio through radioactive decay after long periods of isolation. Combined with other isotopic ratios such as Sr and Nd, it is possible to produce the EM II source, one of the enriched geochemical reservoirs for ocean island basalt magmas, by mixing of a small amount of subducted sediments with depleted or primitive mantle.     

Crust-mantle interaction during the tectono-thermal reactivation of the North China Craton: constraints from SHRIMP zircon U–Pb chronology and geochemistry of Mesozoic plutons from western Shandong

Chronological, geochemical and Sr–Nd–Pb isotopic analyses have been carried out on the Mesozoic plutons in western Shandong with the aim of characterizing crustal–mantle evolution during the tectono-thermal reactivation of the craton. Detailed SHRIMP zircon U–Pb dating reveals two main periods of Mesozoic activity with contrasting compositions. The older magmatic pulse is manifested by monzonites and monzodiorites from Tongshi for which zircon rims yield a concordant age of 177±4 Ma and the cores have a discordant age of ca. 2.5 Ga. Low MgO and Cr, high Na₂O contents and especially their isotopic compositions (⁸⁷Sr/⁸⁶Sr < 0.7042, ²⁰⁶Pb/²⁰⁴Pb < 16.8 and _Nd ~ –12) are consistent with derivation from late Archean–Paleoproterozoic lower crust. Relatively high HREE contents in these Jurassic plutons indicate a garnet-free source (<32 km), in contrast to the garnet-bearing source (>40 km) of the late Mesozoic high Sr and low Y granitoids from the same region. Distinctively different depths of crustal melting suggest dynamic thickening of the crust by magmatic underplating during the Jurassic and Cretaceous. The younger dioritic plutons from Laiwu and Yinan were emplaced at 132–126 Ma and show relatively high MgO and Cr contents and large isotopic variability. They were likely derived from enriched lithospheric mantle source and were subjected to crustal contamination during magma evolution. Early Cretaceous mantle melting is coeval with the widespread late Yanshanian granitic magmatism in North China. Early Cretaceous time may correspond to a critical period when a temperature increase due to lithospheric thinning allowed the intersection of the local geotherm and the wet peridotite solidus. While some mantle-derived magmas were erupted, most were trapped at variable crustal depths, triggering large-scale concomitant melting of the crust. Lithospheric thinning must have continued until the late Cretaceous because of the change in the source of mafic magmas from lithospheric to asthenospheric at that time. It is proposed that removal of the lithospheric keel beneath the North China craton may have been initiated as early as the Jurassic, but with the most intense period in the Cretaceous between 130–75 Ma. Such a relatively long timescale (~100 Ma) emphasizes the role of thermomechanical erosion by convective mantle in lithospheric thinning beneath this region.     

Fragility curves for expressway embankments based on damage datasets after recent earthquakes in Japan

The seismometer network of the Japanese expressway system was enhanced following the 1995 Kobe earthquake. Based on earthquake information from the instruments of the seismometer network, a traffic control is performed directly after the event because of the potential for damage to expressway structures. Expressways serve as vital trunk lines of transportation and are important for the restoration of damage-stricken areas. Therefore, earthquake-induced damage to expressway structures should be estimated as soon as possible. Expressway embankments were seriously damaged during recent earthquakes, such as the 2004 Niigata Chuetsu earthquake. The present study constructs the fragility curves of expressway embankments in Japan in order to estimate the damage distribution immediately after an earthquake. Damage datasets for expressways are compiled for the 2003 Northern-Miyagi earthquake, the 2003 Tokachi-oki earthquake, the 2004 Niigata Chuetsu earthquake, and the 2007 Niigata Chuetsu-oki earthquake. The spatial distributions of the peak ground velocity (PGV) are estimated for these four earthquakes in order to evaluate the relationship between the damage ratio of expressway embankments and the PGV. Statistical analysis is then conducted in order to draw the fragility curves for expressway embankments. Based on the fragility curves, major damage that disrupts ordinary expressway traffic may occur when the peak ground velocity exceeds approximately 35.0 cm/s. The fragility curves constructed in the present study are helpful for predicting the damage distribution on expressways soon after an earthquake, which enables efficient traffic control and rapid disaster response.     

Teshima pyroclastics: Onset of characteristic Setouchi magmatism induced by slab melting at 14.8 Ma

Ar-Ar ages, and petrographical and geochemical characteristics of pyroclastics and an overlying lava from Teshima Island, southwest Japan are presented. Although previous geological and age data suggested Teshima pyroclastics were products of magmatism > 3 my prior to lava flows of Setouchi volcanic rocks generated in association with southward migration of the southwest Japan arc sliver during opening of the Sea of Japan backarc basin at ~ 15 Ma, the present results led to the conclusion that a sequence of Setouchi volcanism, induced by slab melting and subsequent melt-mantle reactions, produced both pyroclastics and lava at 14.6–14.8 Ma. This age is oldest among those reported so far and may represent the timing of onset of characteristic Setouchi magmatism immediately posterior to and hence as a result of the mega-tectonic event including rotation of the southwest Japan arc sliver.     

Lead-210 in the North Pacific and the transport of terrestrial material through the atmosphere

²¹⁰Pb in the surface water of the North Pacific was extensively determined. The results showed that the highest concentrations of²¹⁰Pb of 19 ± 3dpm/100kg were found in the northern mid-latitudes around 30°N, but longitudinal variation across the North Pacific was not observed. The mean residence time of²¹⁰Pb in the surface water up to 100 m in depth is calculated to be 230 days. In the mid-latitudes of the northern hemisphere,²¹⁰Pb may be transported by the prevailing westerly wind of a higher speed than 15 m/sec, likely the jet stream.