Three-dimensional finite strain analysis in the high-grade part of the Sanbagawa Belt using deformed meta-conglomerate

Abstract   Regional ductile deformation of the Sanbagawa belt is generally thought to be characterized by constrictional strain, based on strain analysis using deformed radiolarians in the low-grade regions. Similar strain analysis could not be carried out in the medium- to high-grade zones, because it is very difficult to identify individual radiolarians after strong recrystallization. However, discovery of the first known meta-conglomerate in the high-grade region of the Sanbagawa Belt allows quantitative 3-D strain to be estimated in this region. Using a development of the Rf-φ method, an evaluation of appropriate errors for this estimate can be determined. The principal strain ratios and estimated errors are X/Y = 5.4–6.6 and Y/Z = 3.8–3.9 implying deformation in the flattening field and refuting the idea of uniform constrictional strain. Semi-quantitative markers of the shape of the strain ellipse throughout the high-grade regions suggest that the deformation of the Sanbagawa Belt is dominantly in the flattening field. The difference with the earlier results may be due to late-stage overprinting by upright folding of the main ductile fabric in the low-grade region of western Shikoku.     

Laboratory Experiment of Plasma Flow Around Magnetic Sail

To propel a spacecraft in the direction leaving the Sun, a magnetic sail (MagSail) blocks the hypersonic solar wind plasma flow by an artificial magnetic field. In order to simulate the interaction between the solar wind and the artificially deployed magnetic field produced around a magnetic sail spacecraft, a laboratory simulator was designed and constructed inside a space chamber. As a solar wind simulator, a high-power magnetoplasmadynamic arcjet is operated in a quasisteady mode of 0.8 ms duration. It can generate a simulated solar wind that is a high-speed (above 20 km/s), high-density (10¹⁸ m⁻³) hydrogen plasma plume of ∼0.7 m in diameter. A small coil (2 cm in diameter), which is to simulate a magnetic sail spacecraft and can obtain 1.9-T magnetic field strength at its center, was immersed inside the simulated solar wind. Using these devices, the formation of a magnetic cavity (∼8 cm in radius) was observed around the coil, which indicates successful simulation of the plasma flow of a MagSail in the laboratory.     

Simultaneous Analysis of Natural Free Estrogens and Their Conjugates in Wastewater by GC‐MS

A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L^–1, respectively. However, only E1 was detected at a high concentration of 44 ng L^–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent.     

Simultaneous Analysis of Natural Free Estrogens and Their Sulfate Conjugates in Wastewater

Natural estrogens from humans increasingly attract attention because of their strong endocrine disrupting potency. The discharge of sewage water is considered as the most important source of these endocrine disrupting chemicals (EDCs) in the environment. Therefore, a GC‐MS method was developed for the simultaneous analysis of six natural free estrogens and their sulfate conjugates in municipal wastewater, in which natural free estrogens and sulfate conjugates were successfully separated from an Oasis HLB solid phase extraction (SPE) cartridge with two different eluents, and the sulfate conjugates were then transformed to their corresponding free estrogens by acid solvolysis. Before the analysis with GC‐MS, samples were derivatized by N,O‐bis (trimethylsilyl) trifluoroacetamide (BSTFA) plus 1% trimethylchlorosilane (TMCS) at 80°C for 40 min. Satisfactory recoveries ranging from 64 to 112.3% were obtained by spiking ultra‐purified water, raw, and treated municipal wastewater with the six estrogens at 50, 100, and 50 ng/L, respectively. The method was successfully applied to wastewater samples from one WWTP, which suggested that E1 was the dominant natural estrogens in effluent and E3‐3S was one of the conjugates possibly occurring in the effluent.     

Response of a summertime anticyclonic eddy to wind forcing in Funka Bay,Hokkaido, Japan

Flow fluctuations inside an anticyclonic eddy in summertime Funka Bay were examined using three moorings and hydrographic data. The flow pattern above a sharp pycnocline with a concave isopycnal structure during the mooring period was characterized by high mean kinetic energy and relatively low eddy kinetic energy. The ratios of eddy to mean kinetic energy were equal to or less than one, and the mean flow field and isopycnal structure indicated the existence of a stable anticyclonic eddy above the sharp pycnocline under approximate geostrophic balance. Larger flow fluctuations with periods longer than 7 days were dominant inside the eddy. The low-frequency flow fluctuations are accompanied by north to northeastward movement of the eddy with deepening of the pycnocline and spin-up of the anticyclonic circulation. The wind field over Funka Bay is characterized by bay-scale wind fluctuations. The bay-scale winds are greatly influenced by the land topography around Funka Bay, resulting in non-uniform structure with significant wind stress curl. The bay-scale wind fluctuations are termed “locally modified wind” in the present study. The locally modified wind has a negative (positive) wind stress curl in the central–northeastern (southwestern) region of Funka Bay. The north to northeastward movement of the eddy is caused by horizontal non-uniform supply of vorticity from the locally modified wind forcing by the Ekman pumping process. Through this process, the anticyclonic circulation is enhanced (weakened) in the central–northeastern (southwestern) part of the eddy, resulting in the eddy moving north to northeastward with the pycnocline deepening and spin-up of the anticyclonic circulation. The locally modified wind forcing induces low-frequency flow fluctuations through the movement of the eddy in summertime Funka Bay.     

Petrological characteristics and volatile content of magma from the 2000 eruption of Miyakejima Volcano, Japan

Among the series of eruptions at Miyakejima volcano in 2000, the largest summit explosion occurred on 18 August 2000. During this explosion, vesiculated bombs and lapilli having cauliflower-like shapes were ejected as essential products. Petrological observation and chemical analyses of the essential ejecta and melt inclusions were carried out in order to investigate magma ascent and eruption processes. SEM images indicate that the essential bombs and lapilli have similar textures, which have many tiny bubbles, crystal-rich and glass-poor groundmass and microphenocrysts of plagioclase, augite and olivine. Black ash particles, which compose 40% of the air-fall ash from the explosion, also have similar textures to the essential bombs. Whole-rock analyses show that the chemical composition of all essential ejecta is basaltic (SiO₂=51–52 wt%). Chemical analyses of melt inclusions in plagioclase and olivine phenocrysts indicate that melt in the magma had 0.9–1.9 wt% H₂O, <0.011 wt% CO₂, 0.04–0.17 wt% S and 0.06–0.1 wt% Cl. The variation in volatile content suggests degassing of the magma during ascent up to a depth of about 1 km. The ratio of H₂O and S content of melt inclusions is similar to that of volcanic gas, which has been intensely and continuously emitted from the summit since the end of August 2000, indicating that the 18 August magma is the source of the gas emission. Based on the volatile content of the melt inclusions and the volcanic gas composition, the initial bulk volatile content of the magma was estimated to be 1.6–1.9 wt% H₂O, 0.08–0.1 wt% CO₂, 0.11–0.17 wt% S and 0.06–0.07 wt% Cl. The basaltic magma ascended from a deeper chamber (10 km) due to decrease in magma density caused by volatile exsolution with pressure decrease. The highly vesiculated magma, which had at least 30 vol% bubbles, may have come into contact with ground water at sea level causing the large explosion of 18 August 2000.Editorial responsibility: S. Nakada, T. DuittAn erratum to this article can be found at     

Soil Water Content on Mars as Estimated from Neutron Measurements by the HEND Instrument Onboard the 2001 Mars Odyssey Spacecraft

We present the results of 20 months of observations of Mars by the Russian HEND instrument onboard the NASA 2001 Mars Odyssey spacecraft. We show that there are two extended subpolar regions with a soil water content of several tens of percent in the northern and southern hemispheres of Mars. The southern subpolar region is well described by a two-layer model, according to which a soil with a water content of up to 55% by mass lies under a relatively dry soil with a water mass fraction of 2% and a thickness of 15–20 g/cm². The distribution of water in Martian regolith northern subpolar region is in good agreement with the homogeneous model and does not require invoking the more complex two-layer soil model. The water-ice content in the subsurface layer of the northern subpolar region reaches 53 % by mass. We show that there are two regions with a relatively high water content near the Martian equator. These are Arabia Terra and the Medusae Fossae formation region southwest of Olympus Mons. In these regions, a lower layer with 9–10% of water by mass may underlie the upper layer of relatively dry material 30 g/cm² in thickness. The moistest spot near the equator is at about 30° E and 10° N. Its lower-layer soil may contain more than 16% of water by mass.     

Weakening of the solar extreme-ultraviolet line emission by lyman continuum absorption as derived from line ratios

The intensity ratios of Niii, Oiii, Oiv, and Ov lines observed by the HCO experiment on Skylab are compared with the results of recent multilevel calculations. It is found that solar transition-region spectra require Lyman continuum absorption. The equivalent optical thickness of the absorbers causing the weakening is found to be 1.6–1.7 for a quiet area, 1.4–1.9 for a coronal hole, and 2.4–2.5 for active regions. These values are consistent with previous estimates from different methods.