Air-sea CO<Subscript>2</Subscript> flux by eddy covariance technique in the equatorial Indian Ocean

Direct measurements of the air-sea CO₂ flux by the eddy covariance technique were carried out in the equatorial Indian Ocean. The turbulent flux observation system was installed at the top of the foremast of the R/V MIRAI, thus minimizing dynamical and thermal effects of the ship body. During the turbulent flux runs around the two stations, the vessel was steered into the wind at constant speed. The power spectra of the temperature or water vapor density fluctuations followed the Kolmogorov −5/3 power law, although that of the CO₂ density fluctuation showed white noise in the high frequency range. However, the cospectrum of the vertical wind velocity and CO₂ density was well matched with those of the vertical velocity and temperature or water vapor density in this frequency range, and the CO₂ white noise did not influence the CO₂ flux. The raw CO₂ fluxes due to the turbulent transport showed a sink from the air to the ocean, and had almost the same value as the source CO₂ fluxes due to the mean vertical flow, corrected by the sensible and latent heat fluxes (called the Webb correction). The total CO₂ fluxes including the Webb correction terms showed a source from the ocean to the air, and were larger than the bulk CO₂ fluxes estimated using the gas transfer velocity by mass balance techniques.     

Residual deformation characteristics of partially saturated sandy soils subjected to seismic excitation

Multiple series of triaxial tests were carried out on unsaturated sandy soils subjected to irregular seismic excitation. To observe the volume changes of unsaturated soil specimens during undrained loading and subsequent process of drainage, the inner cell was newly installed inside the large triaxial cell. The soil samples tested were recovered from the construction site of a liquefied natural gas storage facility located in Tokyo Bay area. In the tests, the initial conditions of soil specimens were specified with the degrees of saturation S_r of 50, 75 and 100%. The soil specimens were anisotropically consolidated, and subjected to undrained irregular seismic excitation. The time history of irregular seismic excitation was the one obtained from one of the recent earthquakes in Japan. The drainage line was then opened to let the excess pore water drain out of soil specimens. The volume changes and residual shear strains of unsaturated soil specimens thus obtained are presented in the present paper.     

A preliminary report of development of high resolution phase shift interferometry for the assessment of nuclear waster disposal

A newly designed phase-shift interferometer and a reaction cell have been developed to investigate the alteration process and the safety assessment of an artificial barrier and the surrounding rocks during interaction with high pH solutions in repository sites.We advanced a conventional interferometer with a laser to a phase-shift interferometer with a white-light. Developments and evaluations were also made on the reaction cells at high temperature, high pressure and high pH conditions. Potentials of our established system, involving a newly equipped image-processing, were practically tested by dissolution experiments on calcite in various aqueous solutions. It was successfully confirmed that the developed phase-shift interferometer system can detect very slow retreat in short-periods with high enough precision to evaluate the dissolution kinetics.     

An international turbulence comparison experiment (ITCE 1976)

Turbulence data for the International Turbulence Comparison Experiment (ITCE) held at Conargo, N.S.W. (35° 18′ S., 145° 10′ E.) during October, 1976 are analysed. The standard deviation % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaiikaiqado% hagaqbamaaCaaaleqabaGaaGOmaaaakiaacMcadaahaaWcbeqaaiaa% igdacaGGVaGaaGOmaaaaaaa!3B93!\[(s'^2 )^{1/2} \] and covariance % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaWaa0aaaeaace% WG3bGbauaaceWGZbGbauaaaaaaaa!3809!\[\overline {w's'} \] measured by a number of instruments and instrument arrays have been compared to assess their field performance and calibration accuracy. Satisfactory agreement, i.e. typically 5% for % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaiikamaana% aabaGabm4CayaafaWaaWbaaSqabeaacaaIYaaaaaaakiaacMcadaah% aaWcbeqaaiaaigdacaGGVaGaaGOmaaaaaaa!3BA4!\[(\overline {s'^2 } )^{1/2} \] (except in humidity) and of the order of 20% for % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaiikaiqado% hagaqbamaaCaaaleqabaGaaGOmaaaakiaacMcadaahaaWcbeqaaiaa% igdacaGGVaGaaGOmaaaaaaa!3B93!\[(s'^2 )^{1/2} \], was achieved, but only after consideration of:

1. Instrumental response at high frequencies.
2. Flow distortion induced by instruments and supporting structures.
3. Spatial separation of instruments used for covariance measurements.
4. Statistical errors associated with single point measurements over a finite averaging time, and with lateral separation of two sensor arrays being compared.

     

New Data on Geochronology of the Upper Quaternary Loess–Soil Series in the Terek–Kuma Lowland

Lithology and Mineral Resources - Drilling recovered the upper part (23 m) of the upland loess–paleosol series (LPS) on the right bank of the Kuma River near the Otkaznoe Settlement....     

Feldspar dissolution rates measured using phase-shift interferometry: Implications to CO2 underground sequestration

To assess CO₂ underground sequestration from a geochemical viewpoint, the anorthite dissolution rate, which is an important parameter of risk analysis, was measured in a CO₂–water system. The authors sought to obtain precise dissolution rate data in a short time observing a crystal surface on a nanoscale. For this purpose, phase-shift interferometry was applied. Using this method, uncertainty of the reactive surface area that is imparted on calculation of the dissolution rate constant can also be avoided. The time-course profile of vertical retreat of the surface revealed that the anorthite dissolution process changes from the initial transient state to a later steady state, which is consistent with results of numerous precedent studies. The transient dissolution rate depends strongly on local features (e.g., density of defects, variation of chemical compositions) of the crystal surface, rather than on temperature. Therefore, it is very important to determine the original properties of the anorthite surface for the examination of subsequent dissolution process. Contrary to general expectations, the anorthite dissolution can alter the physical properties of reservoir rock immediately after CO₂ injection. The simple estimation using the anorthite dissolution rate obtained in this study, which was done as a test case for the CO₂ underground sequestration project conducted by RITE, revealed that porosity of reservoir rock increased about 2% (23–23.4%) of initial values during 60 a. That change in physical property in such a short time might enhance the diffusion of injected CO₂ and formation water, and therefore accelerate further geochemical reactions. Results of this study demonstrate that the geochemical water–rock interaction, which is generally regarded as a longer-term phenomenon than various physical processes, can also affect the reservoir system from the initial stage.     

Luminescence chronology of the upper part of the Stari Slankamen loess sequence (Vojvodina,Serbia)

A thick Middle and Late Pleistocene loess-palaeosol sequence is exposed at the Stari Slankamen section in the Vojvodina region situated in the south-eastern part of the Pannonian basin, Serbia. The profile exposes an about 45 m thick series of loess intercalated by at least eight pedocomplexes. Ten samples were dated by luminescence methods using a modified single aliquot regenerative dose (SAR) protocol for polymineral fine grains and for quartz extracts from the upper part of the Stari Slankamen loess sequence. The infrared stimulated luminescence (IRSL) and post-IR optically stimulated luminescence (OSL) signals from all polymineral samples showed anomalous fading, suggesting that the post-IR OSL signal is still dominated by feldspar OSL. The ages ranging from 4.6 to 193 ka were obtained after fading correction. These ages indicate that the loess unit V-L1L1, the weakly developed soil complex V-L1S1 and the loess unit V-L1L2 were deposited during marine isotope stage (MIS) 2, 3, and 4, respectively, and also indicate that the loess unit V-L2 is of the penultimate glacial age.     

Infrared stimulated luminescence and radiofluorescence dating of aeolian sediments from Hungary

Anomalous fading of the infrared stimulated luminescence (IRSL) signal from the polymineral fine-grain and K-feldspar fractions of aeolian sediments from Hungary has been studied. The samples in this study have previously been dated using the multiple aliquot additive dose (MAAD) protocol to measure the IRSL signal. The IRSL measurements using MAAD were conducted ～4 weeks after the irradiation, making it difficult to assess to what extent these age estimates were affected by anomalous fading. In this study, equivalent doses were obtained using the single aliquot regenerative dose (SAR) protocol. The fading rate for each sample was calculated using the different IRSL components and different parts of the decay curve. For each sample, the middle part of the decay curve always showed a lower fading rate than the initial part of the decay curve. The difference between the fading rates for different parts of the decay curve was greater for the K-feldspars than for the polymineral fine grains. Fading corrected ages were calculated by integrating both the initial and the middle part of the decay curve. These ages were compared with optically stimulated luminescence (OSL) ages from quartz, infrared radiofluorescence (IR-RF) ages obtained from K-feldspars and also with independent ages, provided by radiocarbon dating of shells and charcoal, and uranium-series dating of travertine.