Stress Concentration at the Bottom of a Borehole and its Effect on Borehole Breakout Formation

Summary Stress concentration at the bottom of a borehole due to the corners with small radius of curvature in an axial section and its effect on the azimuth of breakout was studied. To this end, a 3-D finite element analysis was conducted and the stress around the borehole was examined for boreholes arbitrarily oriented to three principal axes of remote stress. Results show that, in the case of high strength rock, compressive failure resulting in spalling of a borehole may occur only at the bottom of the borehole. The spalling can occur continuously with drilling, and results in continuous spalling with depth, i.e., a breakout. This type of breakout tends to form on one side of the borehole and its orientation is approximately perpendicular to the orientation of standard breakouts, inferred from the stress concentration due to the cylindrical shape of the borehole.     

Authigenic calcium carbonate flux in groundwater-controlled lakes: Implications for lacustrine paleoclimate records

Groundwater dominated lakes are an important feature of many landscapes. Their sediments are a particularly valuable source of paleoenvironmental information in semiarid regions where perennial lakes may otherwise be scarce. Where groundwater and lake composition are favorable, carbonate mineral precipitation, evaporative concentration of lake water, and microbial processes can combine to strongly deplete dissolved Ca relative to influent groundwaters. The authigenic carbonate flux (ACF) can then become limited by water column cation availability and thereby be coupled to groundwater inflow rates and aquifer recharge. Here we analyze sedimentary records from two marl-producing, groundwater-controlled lakes and demonstrate a link between one-dimensional ACF and the Palmer Drought Severity Index (PDSI), a measure of land surface wetness. In a restricted outflow lake with high-carbonate alkalinity, ACF is enhanced during historically wet climatic periods in response to increased aquifer recharge rates. ACF in this lake declines during droughts. A neighboring dilute lake with a high rate of groundwater outflow shows comparatively weak coupling between ACF and PDSI history. Ionic chemistry, carbonate mineral equilibria, and δ¹³C patterns of dissolved inorganic carbon show that the sensitivity of the ACF signal depends on the degree of evaporative evolution of lake water and the mineral saturation state of the water column under conditions of stratification and ice cover.     

准噶尔板块东北缘富铌玄武岩的发现及其地质意义

富铌玄武岩是硅过饱和,富Ｎａ2Ｏ,ＴｉＯ2,Ｐ2Ｏ5,同时富集高场强元素的一类岛弧玄武岩,这类玄武岩的ｗ(Ｎｂ)>7×10-6,(ｗ(Ｌａ)/ｗ(Ｎｂ))ＭＮ<2。它是由来源于70100ｋｍ深处、受ａｄａｋｉｔｅ熔体交代过的地幔楔橄榄岩部分熔融形成的,是大洋板块俯冲作用的产物。目前发现的富铌玄武岩大多分布在环太平洋新生代岛弧环境,与洋壳俯冲作用密切相关[1 5]。本研究在准噶尔板块东北缘富蕴县的索尔库都克附近首次发现了富铌玄武岩。它产于下泥盆统托让格库都克组中、上部。该地层自下而上的岩石组合为:玄武岩 火山凝灰角砾岩 火山集块岩 含…     

Holocene Climate in the Northern Great Plains Inferred from Sediment Stratigraphy, Stable Isotopes, Carbonate Geochemistry, Diatoms, and Pollen at Moon Lake, North Dakota

Seismic stratigraphy, sedimentary facies, pollen stratigraphy, diatom-inferred salinity, stable isotope (δ¹⁸O and δ¹³C), and chemical composition (Sr/Ca and Mg/Ca) of authigenic carbonates from Moon Lake cores provide a congruent Holocene record of effective moisture for the eastern Northern Great Plains. Between 11,700 and 9500¹⁴C yr B.P., the climate was cool and moist. A gradual decrease in effective moisture occurred between 9500 and 7100¹⁴C yr B.P. A change at about 7100¹⁴C yr B.P. inaugurated the most arid period during the Holocene. Between 7100 and 4000¹⁴C yr B.P., three arid phases occurred at 6600–6200¹⁴C yr B.P., 5400–5200¹⁴C yr B.P., and 4800–4600¹⁴C yr B.P. Effective moisture generally increased after 4000¹⁴C yr B.P., but periods of low effective moisture occurred between 2900–2800¹⁴C yr B.P. and 1200–800¹⁴C yr B.P. The data also suggest high climatic variability during the last few centuries. Despite the overall congruence, the biological (diatom), sedimentological, isotopic, and chemical proxies were occassionally out of phase. At these times the evaporative process was not the only control of lake-water chemical and isotopic composition.     

Elasticity of MgSiO3 in the ilmenite phase

The single-crystal elastic moduli of the ilmenite phase of MgSiO₃ have been determined from Brillouin spectroscopy. They are: C₁₁ = 472, C₁₂ = 168, C₃₃ = 382, C₁₃ = 70, C₄₄ = 106, C₁₄ = ?27, C₆₆ = 152 and C₂₅ = ?24 in GPa. These elastic properties are consistent with a structural mechanical model where the silicon octahedra are very stiff under compression and shear. This latter property yields an unexpectedly high shear modulus for the magnesium silicate ilmenite as compared with analogue compounds. The further transformation to perovskite will probably be associated with a significant increase in elastic properties since the strong silicon polyhedra form a structural network in this phase. The transformation of spinel and stishovite to ilmenite is associated with a slight density increase and a slight decrease in acoustic velocities. This transformation will probably not produce a seismic discontinuity even if it does occur in the Earth's mantle.     

Analytical and numerical solutions on the response of pore pressure to cyclic atmospheric loading: with application to Horonobe underground research laboratory,Japan

During the long-term stability assessment of underground disposal repositories buried in sedimentary formations, one of crucial scientific problems is to determine parameters of site formations. The analysis of response of the pore pressure due to atmospheric loading provides a possible way of accurate estimation of formation parameters. In this paper, an analytical solution of response of the pore pressure to atmospheric loading was derived starting from the Biot’s poroelasticity, and its corresponding numerical solutions were developed by finite element methods for 1D and 2D situations. With comparison to the analytical solution, the experimental results show that the numerical schemes sound reasonable to implement the assessment of response of the pore pressure in horizontal multilayer sedimentary formations. In particular, it is effective for a 2D model over large area with consideration of background horizontal groundwater flow. A highlight of this work is to construct a reasonable approach to capture responses of the pore pressure to atmospheric loading, and at the same time to provide the feasibility of integrated analysis of well monitoring data of pore pressure variance in Horonobe Underground Research Laboratory (URL), Hokkaido, Japan.     

Diffusion in single crystal of melilite: interdiffusion of Al + Al vs. Mg + Si

Interdiffusion coefficients of Al + Al vs. Mg + Si in the gehlenite–åkermanite system of melilite were determined by coupled annealing of synthesized end-member single crystals. The observed diffusion coefficients for a couple-annealed sample vary for about 2 orders of magnitude, showing strong dependence on the gehlenite–åkermanite composition: diffusion coefficient observed at 1350 °C, for example, is 3 × 10^?13 cm² s^?1 at 5 mol% åkermanite composition (Ak₅), increases to 2 × 10^?11 cm² s^?1 at Ak₈₀, and then decreases to 1 × 10^?12 cm² s^?1 at Ak₉₅. The diffusion coefficient–temperature relation indicates high activation energy of diffusion of about 420 kJ mol^?1 for gehlenite-rich melilite. The observed diffusion coefficient–composition relation may be explained by a combination of (1) the diffusion coefficient–melting temperature relation (Flynn's rule) and (2) the feasibility of local charge compensation, which can possibly be maintained more easily in the intermediate chemical composition. The high activation energy value for gehlenitic melilite appears to correspond to the complex diffusion mechanism. The observed highly variable diffusion coefficients suggest that gehlenite–åkermanite zoning in the melilite crystals in Ca, Al-rich inclusions in the carbonaceous meteorites may provide a sensitive indicator for the thermal history of the inclusions.     

High temperature solvent growth of anorthite on the join CaAl2Si2O8-SiO2

Stoichiometric anorthite, CaAl₂Si₂O₈, Pˉ1, with sharp a, b, c, and d diffractions was grown, using a CaV₂O₆ solvent, by cooling at 2 ° C per hour from 1450 to 750 ° C in air. Euhedral crystals up to 5 × 3× 0.5 mm, with prominent {010} and well-developed {110} and {001}, were obtained by spontaneous nucleation. Nonstoichiometric anorthite with excess SiO₂ (CaAl₂Si₂O₈+Si₂Si₂O₈) was grown on the join CaAl₂Si₂O₈-SiO₂. Chemical analysis of the synthetic anorthite, having the highest SiO₂ content, with maximum vacancies on M-site gave □_0.110 Na_0.006Ca_0.884Al_1.80Si_2.20O₈, and X-ray diffraction showed a trend from stoichiometric Pˉ1 through diffuse Pˉ1 to body-centered Iˉ1 probably reflecting increasing disorder caused by a higher Si/Al ratio in the T-sites and the positional disorder accompanied by M-site vancancies. Annealing of the nonstoichiometric diffuse Iˉ1 anorthite in air at 1050 ° C for 14 days resulted in exsolution of minute SiO₂ inclusions due to probable ordering in the T-sites and filling of M-sites by Ca. Stoichiometric Pˉ1 anorthite was not obtained by annealing at 1050 ° due to appreciable solubility of SiO₂ in CaAl₂Si₂O₈. Metastable hexagonal CaAl₂Si₂O₈ was found to be a twinned monoclinic crystal with cell dimensions: a = 10.24 (2), b = 17.74 (3), c= 14.99 (5) ?, β = 92.05 (5) °, space group C2.