Contamination by organochlorine compounds in sturgeons from Caspian Sea during 2001 and 2002

Organochlorine compounds (OCs) were determined in the five species of sturgeons collected from coastal waters of Caspian Sea in Kazakhstan, Azerbaijan, Turkmenistan and Iran during 2001 and 2002 to understand their status of contamination and accumulation features. Among OCs examined, concentrations of DDTs (DDT and its metabolites) were predominant in all the sturgeon samples with concentrations ranging from 73 to 31,000 ng/g on lipid weight basis, followed by PCBs, CHLs, HCHs, HCB, dieldrin, TCPMOH, and heptachlor epoxide in order. The concentrations of OCs in beluga (Huso huso) were the highest among all the five species. When comparing residue levels among same species, OC residues were highest in sturgeons from Azerbaijan and Kazakhstan and lowest in Turkmenistan. However, the concentrations of HCHs, dieldrin, and heptachlor epoxide in sturgeons showed less geographical variability.     

Specific accumulation of persistent organochlorines in bluefin tuna collected from Japanese coastal waters

Concentrations of persistent organochlorines (OCs) such as PCBs, DDTs, chlordanes (CHLs), HCHs and HCB were determined in the liver of bluefin tuna (Thunnus thynnus) collected from Japanese coastal waters in order to elucidate accumulation profiles and to evaluate the suitability of this species as a biomonitor for pollution in the open sea ecosystem. Concentrations of PCBs, DDTs and CHLs in bluefin tuna increased significantly with body length (30–190 cm). HCHs and HCB residues were comparable among all the sampling regions, and the levels of these chemicals did not show correlation with body length. These results suggest significance of dietary uptake of PCBs, DDTs and CHLs compared to the intake via the gill. On the other hand, equilibrium partitioning with ambient water is a major determinant of the levels of HCHs and HCB in tuna. Body-length normalized values (BLNV) of PCBs, DDTs and CHLs concentrations in bluefin tuna were calculated using the linear regression equation obtained from the plot of concentrations and body length. BLNV of these chemicals on a lipid wt basis, which was adjusted for 100 cm body length, were indicative of the present state water pollution by PCBs, DDTs and CHLs. These results suggest that bluefin tuna is a suitable bioindicator for monitoring OCs contamination in the open sea ecosystem.     

The first three orders of scattering in vertically inhomogeneous scattering-absorbing media

In order to facilitate the computations of the intensities of radiation reflected and/or transmitted by plane-parallel, vertically inhomogenous, scattering-absorbing media, we carry out the optical thickness integrations of the Cauchy systems (normally referred to as Invariant Imbedding Equations) for reflection and transmission functions originating from the first three orders of scattering: the medium in question is represented by a stack of a certain number of homogeneous slabs, each of which is characterized by a constant single scattering albedo and a constant phase function together with the optical thickness.The results are a set of recurrence formulae involving only the angular intergrations, a convenient feature for numerical computations, and should prove useful particularly for finding approximate values of the high frequency Fourier coefficients of reflection and transmission functions of inhomogeneous media or efficiently initializing the solution for a thin layer to perform rigorous multiple scattering computations by means of other techniques such as the Doubling-Adding method.     

Order-of-scattering of partially polarized radiation in inhomogeneous,anisotropically scattering atmospheres

A complete set of transfer equations required for the order-of-scattering analysis of partially polarized radiation in inhomogeneous, anisotropically scattering atmospheres is provided. The equations have been derived for both a local study using the radiative transfer equation and its associated auxiliary equation for the source-matrix, and a global study in terms of the scattering and transmission matrices; they account for the polarity of the scattering medium. Their derivations for the finite order scattering and the finitely cumulative scattering, in particular, have yielded important new equations expressing the invariance principles and the integro-differential recurrences for the scattering and transmission matrices. These novel expressions contain as a special case Bellmanet al's (1972) equations for the simpler case of isotropic scattering of unpolarized light in homogeneous atmospheres.     

A Study On Surges: I. Automatic Detection Of Dynamic Hα Dark Features From High-Cadence Full-Disk Observations

We present a new method for the automatic identification and classification of dynamic Hα dark features found in time series of full-disk solar images at three Hα wavelengths (center, and ± 0.8 Å). The simultaneous Hα observations are obtained by the multi-channel Flare Monitoring Telescope (FMT) at Hida Observatory. The program was developed in order to replace the present visual detection and classification of the phenomena. Usually, an obvious dark feature found in the Hα ?0.8 Å observations probably corresponds to some phenomenon such as a surge or chromospheric network enhancement, or filament activity. Thus, one of our aims in this program is to distinguish each phenomenon by its own properties and key parameters. We optimized the threshold values of the key parameters such as the area and darkness of the transiently darkening features in Hα ?0.8 Å so that the computer can reasonably identify surges and filament activations. In comparison, for a 7-day observation period, the number of dark events detected by the program contains 89% of the events recognized visually. However, 10 times more events are detected automatically. The missing events are mainly caused by the deletion of data with poor visibility. It is found that the dark events can be identified with more precise starting and ending times by a machine than by a human. Some statistical studies of surges or other activities can be carried out based on the computer-produced database. With some modifications the program can be applied to monitor real-time dynamic features on disk, including flare ribbons.     

Underground storage of carbon dioxide in depleted natural gas reservoirs and in useless aquifers

Depleted reservoirs of natural gas and petroleum can provide excellent traps for carbon dioxide. Deep aquifers, which are not used due to high salinity, can host larger amount of the carbon dioxide under their high formation pressure than natural gas and oir reservoirs. Small fraction of aquifers in sedimentary basins in the world are enough to host about 87 gigaton-C of carbon dioxide.

A preliminary technical and economical survey on the carbon dioxide injection system suggests that the energy requirement for carbon dioxide injection into subterranean aquifers is about 269 kWh/ton-C and that the investment and operation costs for system are 79 $/ton-C. By our preliminary cost estimation in Japan, the CO₂-emission-free electricity generation may become possible with a cost increase of 35% for natural-gas-fired power station, and of 60% for coal-fired-power station.     

Carbon isotope chemostratigraphy of a Precambrian/Cambrian boundary section in the Three Gorge area, South China: Prominent global-scale isotope excursions just before the Cambrian Explosion

Carbon isotope chemostratigraphy has been used for worldwide correlation of Precambrian/Cambrian (Pc/C) boundary sections, and has elucidated significant change of the carbon cycle during the rapid diversification of skeletal metazoa (i.e. the Cambrian Explosion). Nevertheless, the standard δ¹³C curve of the Early Cambrian has been poorly established mainly due to the lack of a continuous stratigraphic record. Here we report high-resolution δ¹³C chemostratigraphy of a drill core sample across the Pc/C boundary in the Three Gorge area, South China. This section extends from an uppermost Ediacaran dolostone (Dengying Fm.), through a lowermost Early Cambrian muddy limestone (Yanjiahe Fm.) to a middle Early Cambrian calcareous black shale (Shuijingtuo Fm.). As a result, we have identified two positive and two negative isotope excursions within this interval. Near the Pc/C boundary, the δ¹³C_carb increases moderately from 0 to + 2‰ (positive excursion 1: P1), and then drops dramatically down to − 7‰ (negative excursion 1: N1). Subsequently, the δ¹³C_carb increases continuously up to about + 5‰ at the upper part of the Nemakit–Daldynian stage. After this positive excursion, δ¹³C_carb sharply decreases down to about − 9‰ (N2) just below the basal Tommotian unconformity. These continuous patterns of the δ¹³C shift are irrespective of lithotype, suggesting a primary origin of the record. Moreover, the obtained δ¹³C profile, except for the sharp excursion N2, is comparable to records of other sections within and outside of the Yangtze Platform. Hence, we conclude that the general feature of our δ¹³C profile best represents the global change in seawater chemistry. The minimum δ¹³C of the N1 (− 7‰) is slightly lower than carbon input from the mantle, thus implying an enhanced flux of ¹³C-depleted carbon just across the Pc/C boundary. Hence, the ocean at that time probably became anoxic, which may have affected the survival of sessile or benthic Ediacaran biota. The subsequent δ¹³C rise up to + 5‰ (P2) indicates an increase of primary productivity or an enhanced rate of organic carbon burial, which should have resulted in lowering pCO₂ and following global cooling. This scenario accounts for the cause of the global-scale sea-level fall at the base of the Tommotian stage. The subsequent, very short-term, and exceptionally low δ¹³C (− 9‰) in N2 could have been associated with the release of methane from gas hydrates due to the sea-level fall. The inferred dramatic environmental changes (i.e., ocean anoxia, increasing productivity, global cooling and subsequent sea-level fall with methane release) appear to coincide with or occur just before the Cambrian Explosion. This may indicate synchronism between the environmental changes and rapid diversification of skeletal metazoa.     

Biological organic carbon export estimated from the annual carbon budget observed in the surface waters of the western subarctic and subtropical North Pacific Ocean from 2004 to 2013

The annual flux of biologically produced organic carbon from surface waters is equivalent to annual net community production (NCP) at a steady state and equals the export of particulate and dissolved organic carbon (POC and DOC, respectively) to the ocean interior. NCP was estimated from carbon budgets of salinity-normalized dissolved inorganic carbon (nDIC) inventories at two time-series stations in the western subarctic (K2) and subtropical (S1) North Pacific Ocean. By using quasi-monthly biogeochemical observations from 2004 to 2013, monthly mean nDIC inventories were integrated from the surface to the annual maximum mixed layer depth and corrected for changes due to net air–sea CO₂ exchange, net CaCO₃ production, vertical diffusion from the upper thermocline, and horizontal advection. The annual organic carbon flux at K2 (1.49 ± 0.42 mol m^?2 year^?1) was lower than S1 (2.81 ± 0.53 mol m^?2 year^?1) (p < 0.001 based on t test). These fluxes consist of three components: vertically exported POC fluxes (K2: 1.43 mol m^?2 year^?1; S1: 2.49 mol m^?2 year^?1), vertical diffusive DOC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.25 mol m^?2 year^?1), and suspended POC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.07 mol m^?2 year^?1). The estimated POC export flux at K2 was comparable to the sum of the POC flux observed with drifting sediment traps and active carbon flux exported by migrating zooplankton. The export fluxes at both stations were higher than those reported at other time-series sites (ALOHA, the Bermuda Atlantic Time-series Study, and Ocean Station Papa).     

The X-ray spectrum and variability of the Seyfert 2 galaxy NGC 7172

We present evidence of flux variability, on both short (hours) and long (months) time-scales, of the Seyfert 2 galaxy NGC 7172. These results are based on the ASCA observation of NGC 7172 performed in 1996 May. The source was detected at a rather low flux level, about 3 times fainter than its usual state (including 1 yr before, when it was also observed by ASCA ).   The source also varied by about 30 per cent during the observation, confirming the presence of a type 1 nucleus in its centre. However, its spectrum appears to be flatter than the typical Seyfert 1 spectrum (in agreement with findings on other Seyfert 2s), posing problems for the unification model unless complex absorption is invoked.     

A direct numerical approach to the Chandrasekhar'sH-functions for arbitrary characteristic functions

The purpose of this paper is to present a numerical technique to directly compute the Chandrasekhar'sH ()-function for anisotropic scattering in terms of the roots of the characteristic equations as well as the quadrature points of a certain degreen employed to approximate the definite integral involved in the basic equation. The principal feature of the algorithm proposed here is a compact computer code to enumerate _n C _m combinations ofn distinct integers {1,...,n} takenm at a time. With these quantities available, the coefficients of the polynomial equation of the characteristics equation can be readily computed for any given characteristic function, so that a standard technique such as the Laguerre method can be applied to find all the roots.It is shown that the results obtained for some representativeH()-functions using the present technique with relatively low-order formula (e.g.,n=7) are sufficiently accurate for all practical purposes.