Magmatic unmixing in spinel from late Precambrian concentrically-zoned mafic–ultramafic intrusions, Eastern Desert, Egypt

Spinel is widespread in the ultramafic core rocks of zoned late Precambrian mafic–ultramafic complexes from the Eastern Desert of Egypt. These complexes; Gabbro Akarem, Genina Gharbia and Abu Hamamid are Precambrian analogues of Alaskan-type complexes, they are not metamorphosed although weakly altered. Each intrusion is composed of a predotite core enveloped by pyroxenites and gabbros at the margin. Silicate mineralogy and chemistry suggest formation by crystal fractionation from a hydrous magma. Relatively high Cr₂O₃ contents are recorded in pyroxenes (up to 1.1 wt.%) and amphiboles (up to 1.4 wt.%) from the three plutons. The chrome spinel crystallized at different stages of melt evolution; as early cumulus inclusions in olivine, inclusions in pyroxenes and amphiboles and late-magmatic intercumulus phase. The intercumulus chrome spinel is homogenous with narrow-range of chemical composition, mainly Fe³⁺-rich spinel. Spinel inclusions in clinopyroxene and amphibole reveal a wide range of Al (27–44 wt.% Al₂O₃) and Mg (6–13 wt.% MgO) contents and are commonly zoned. The different chemistries of those spinels reflect various stages of melt evolution and re-equilibration with the host minerals. The early cumulus chrome spinel reveals a complex unmixing structures and compositions. Three types of unmixed spinels are recognized; crystallographically oriented, irregular and complete separation. Unmixing products are Al-rich (Type I) and Fe³⁺-rich (Type II) spinels with an extensive solid solution between the two end members. The compositions of the unmixed spinels define a miscibility gap with respect to Cr–Al–Fe³⁺, extending from the Fe³⁺–Al join towards the Cr corner. Spinel unmixing occurs in response to cooling and the increase in oxidation state. The chemistry and grain size of the initial spinel and the cooling rate control the type of unmixing and the chemistry of the final products. Causes of spinel unmixing during late-magmatic stage are analogous to those in metamorphosed complexes. The chemistry of the unmixed spinels is completely different from the initial spinel composition and is not useful in petrogenetic interpretations. Spinels from oxidized magmas are likely to re-equilibrate during cooling and are not good tools for genetic considerations.     

Seismic behaviour of pile groups by hybrid experiments

Non-linear seismic soil-pile interaction was studied with a hybrid procedure that used a pseudo-dynamic testing (PDT) method modified to account for frequency dependence and developed for foundation-soil systems. The numerical scheme used in the conventional PDT was improved by the introduction of a time-dependent pseudo-forcing function derived from the frequency-dependent dynamic characteristics of the system by Hilbert transformation in the frequency domain. Single, 2-, 3- and 9-pile group foundation models were used, their mechanical characteristics later being determined from static and forced vibration dynamic tests. Amplitude scaling was used for three recorded accelerograms. Data recorded during an earthquake at the site of the experiments revealed that the proposed methodology predicts well seismic nonlinear interaction and accounts for frequency dependence and non-linearity in the time domain.     

Hybrid experiments on non-linear earthquake-induced soil-structure interaction

Non-linear seismic soil-structure interaction is studied through a hybrid procedure using the pseudo-dynamic testing (PDT) method which is modified to take into account frequency dependence and developed for foundation-soil systems. The numerical scheme used in conventional PDT is improved by introduction of a time-dependent pseudo-forcing function which is derived from frequency-dependent dynamic characteristics of the system by means of Hilbert transformation in the frequency domain. Surface, shallow and caisson foundation models that differed in size and depth of embedment were used. The mechanical characteristics of the systems were determined from static and forced vibration dynamic tests. An amplitude scaling technique was used for three recorded accelerograms.     

Asteroids approaching the Earth from directions around the Sun

We have estimated close asteroid encounters with the Earth by numerical integrations of a system with the Sun, 9 planets, and 188 near-earth-asteroids during the period 1994–4600. Asteroids approach the Earth from directions within 30 around the Sun in more than 20% of encounters with the closest distance less than 0.01 AU. Since ground-based observations cannot detect these objects, we should develop space-borne and/or lunar observatories in a short time to allow enough warning time before a catastrophic collision.     

Generation mechanisms of tidal residual circulation

Two new types of mechanism for the generation of tidal residual flow are revealed with the use of a hydraulic model experiment. A remarkable anticlockwise tidal residual circulation is formed in a model bay due to the presence of a tidal current, the Coriolis force and a horizontal boundary. A similar circulation is also formed due to the presence of a bottom slope, a horizontal boundary and a tidal current which flows normal to the inclination of the bottom slope. The residual circulation in the Sea of Iyo in the Seto Inland Sea is considered to be due to a combination of the effects of the Coriolis force, a bottom slope, a horizontal boundary and the tidal current. We classified some of the generation mechanisms of tidal residual flow which have been described to date into seven types on the basis of vorticity considerations.     

Pingos on Earth and Mars

Pingos are massive ice-cored mounds that develop through pressurized groundwater flow mechanisms. Pingos and their collapsed forms are found in periglacial and paleoperiglacial terrains on Earth, and have been hypothesized for a wide variety of locations on Mars. This literature review of pingos on Earth and Mars first summarizes the morphology of terrestrial pingos and their geologic contexts. That information is then used to asses hypothesized pingos on Mars. Pingo-like forms (PLFs) in Utopia Planitia are the most viable candidates for pingos or collapsed pingos. Other PLFs hypothesized in the literature to be pingos may be better explained with other mechanisms than those associated with terrestrial-style pingos.     

Variation in lunar sodium exosphere measured from lunar orbiter SELENE (Kaguya)

Resonant scattering of the lunar sodium exosphere was measured from the lunar orbiter SELENE (Kaguya) from December 2008 to June 2009. Variations in line-of-sight integrated intensity measured on the night-side hemisphere of the Moon could be described as a spherical symmetric distribution of the sodium exosphere with a temperature of 2400-6000 K. Average surface density of sodium atoms in February is well above that in the other months by about 30%. A clear variation in surface density related to the Moon’s passage across the Earth’s magnetotail could not be seen, although sodium density gradually decreased (by 20±8%) during periods from the first through the last quarter of two lunar cycles. These results suggest that the supra-thermal components of the sodium exosphere are not mainly produced by classical sputtering of solar wind. The variation in sodium density (which depends on lunar-phase angle) is possibly explained by the presence of an inhomogeneous source distribution of photon-stimulated desorption (PSD) on the surface.     

Nikubuchi peridotite body in the sanbagawa metamorphic belt; thermal history of the ‘Al-pyroxene-rich suite’ peridotite body in high pressure metamorphic terrain

Oceanic tholeiite glass has been reacted with natural seawater at 25°–500° C, 1 kbar, with both low (5) and high (50) water/rock mass ratios. Initial experiments were conducted at constant temperatures between 100° C and 500° C (100° intervals) in order to characterize the mineralogy and chemical exchange trends for both water/rock ratios. However, the primary purpose of this investigation was to study the chemical and mineralogical changes that may take place as reacted seawater cools as it traverses a temperature gradient before exiting onto the seafloor, as may happen in some submarine hydrothermal systems. Consequently, a series of cooling or temperature gradient experiments were performed in which seawater that had reacted with basalt at 500° C was cooled to 25° C in a step-wise fashion; mineralogy and fluid chemistry were determined at 100 degree intervals during cooling.For all of the experiments, the elemental exchange trends were the same. With respect to the initial sea-water, Fe, Mn, Ca, Si and H⁺ increased while Na and Mg decreased. However, the extent of the exchange depended heavily on the temperature and water/rock ratio. During cooling, fluid compositions in the temperature gradient runs generally approached those of the constant temperature experiments. Even though fluid compositions were very similar at 500° C for both water/rock ratios, the high water/rock ratio systems were more efficient in leaching transition metals from the rock and maintained substantial concentrations in solution during cooling, even to temperatures as low as 25° C. The Fe/Mn ratio in the fluid, however, was quite different for the two water/rock ratios; consequently, the effective water/rock ratio appears to be one parameter that can control the Fe/Mn ratio in exiting hydrothermal fluids and may influence the Fe/Mn ratio in metal-rich sediments.Alteration minerals produced in these seawater/ basalt experiments are very similar to those found at submarine springs on the East Pacific Rise, 21° N. Iron sulfides, pyrite and pyrrhotite, precipitated during cooling for both water/rock ratios, demonstrating the ore-forming potential of submarine hydrothermal systems.     

SHRIMP and electron microprobe chronology of UHT metamorphism in the Napier Complex,East Antarctica: implications for zircon growth at >1,000 °C

Zircons in ultra-high-temperature (UHT) metamorphosed paragneisses from Mt. Riiser-Larsen in the Napier Complex, East Antarctica, were dated by using ion microprobe (SHRIMP) and electron microprobe (EMP). Both SHRIMP and EMP analyses yield consistent 2520–2460 Ma age populations for garnet–orthopyroxene-bearing paragneiss and leucosomes enclosed within. The peak UHT event was dated at 2480 Ma by SHRIMP analyses on metamorphic zircons from the garnet–orthopyroxene paragneiss and those on magmatic zircons from the leucosomes which are interpreted to be formed at syn-UHT. As obtained by SHRIMP, the UHT metamorphic event was terminated no later than 2460 Ma. Minor 2520-Ma SHRIMP age suggests either the onset of prograde metamorphism or another high-grade metamorphic event unrelated to the UHT. EMP analyses on metamorphic zircons from sapphirine–quartz and osumilite-bearing magnesian paragneisses give c. 2500–2450 Ma ages. Inherited igneous zircon cores of the magnesian paragneisses yield relatively scattered EMP ages ranging over c. 3000–2650 Ma, suggesting that igneous materials of these ages sourced the protoliths of the paragneisses and that they were deposited during the interval c. 2650–2520 Ma.